[1]王 亮,陈 群,何明阳.三氯异氰尿酸促进硫代磷酸酯的高效简便合成[J].常州大学学报(自然科学版),2015,(02):6-10.[doi:10.3969/j.issn.2095-0411.2015.02.002]
　WANG Liang,CHEN Qun,HE Ming-yang.Trichloroisocyanuric Acid-Promoting the Convenient and Efficient Synthesis of Thiophosphates[J].Journal of Changzhou University(Natural Science Edition),2015,(02):6-10.[doi:10.3969/j.issn.2095-0411.2015.02.002]
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三氯异氰尿酸促进硫代磷酸酯的高效简便合成()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2015年02期
页码:
6-10
栏目:
化学化工
出版日期:
2015-04-25

文章信息/Info

Title:
Trichloroisocyanuric Acid-Promoting the Convenient and Efficient Synthesis of Thiophosphates
作者:
王 亮; 陈 群; 何明阳
（常州大学 石油化工学院，江苏 常州 213164)
Author(s):
WANG Liang; CHEN Qun; HE Ming-yang
(School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China)
关键词:
三氯异氰尿酸; 硫代磷酸酯; 磷酸酯; 硫酚
Keywords:
trichloroisocyanuric acid;  thiophosphates;  phosphonate;  thiophenol
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2015.02.002
文献标志码:
A
摘要:
以三氯异氰尿酸（TCCA）为促进剂，硫酚和亚磷酸酯为原料合成一系列硫代磷酸酯，并用1H NMR,13C NMR和质谱对产物结构进行表征。与传统方法相比，该法快速、高效、反应条件温和且底物兼容性好，为硫代磷酸酯的合成提供新的途径。
Abstract:
A series of thiophosphates were synthesized by coupling reaction between thiophenols and phosphites promoted by trichloroisocyanuric acid(TCCA). All the compounds were characterized by 1H NMR, 13C NMR and Mass. Compared with conventional methods, this protocol shows some advantages such as fast, highly efficient, mild and good substrate compatibility. This work provides a new methodology for the synthesis of thiophosphates.

参考文献/References:


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备注/Memo

备注/Memo:
国家自然科学基金项目资助（21302014）
更新日期/Last Update: 2015-05-20