[1]吴王平,江鹏,苏少航,等.贵金属催化剂在甲烷干重整中的研究[J].常州大学学报(自然科学版),2015,(04):31-37.[doi:10.3969/j.issn.2095-0411.2015.04.006]
 WU Wangping,JIANG Peng,SU Shaohang,et al.Review on Noble Metal Catalysts for Dry Reforming of Methane[J].Journal of Changzhou University(Natural Science Edition),2015,(04):31-37.[doi:10.3969/j.issn.2095-0411.2015.04.006]
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贵金属催化剂在甲烷干重整中的研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2015年04期
页码:
31-37
栏目:
化学化工
出版日期:
2015-11-15

文章信息/Info

Title:
Review on Noble Metal Catalysts for Dry Reforming of Methane
作者:
吴王平江鹏苏少航华同曙
常州大学 机械工程学院,江苏 常州 213164
Author(s):
WU Wangping JIANG Peng SU Shaohang HUA Tongshu
School of Mechanical Engineering, Changzhou University, Changzhou 213164, China
关键词:
贵金属 催化剂 甲烷重整 二氧化碳
Keywords:
noble metal catalyst methane reforming carbon dioxide
分类号:
TQ 032.41
DOI:
10.3969/j.issn.2095-0411.2015.04.006
文献标志码:
A
摘要:
甲烷和二氧化碳是两种重要温室气体,可通过重整反应制合成气,所制合成气可通过费-托合成转化成高附加值产品,对缓解能源危机具有重大意义。常用的负载型镍催化剂由于在反应过程中产生积炭,导致活性下降。贵金属具有优异的催化性能和稳定性,比镍催化剂具有更好的抗积炭性能。为设计出较好稳定性的催化剂,主要综述贵金属催化剂对甲烷干重整的动力学和催化反应机理,同时结合催化剂、载体及制备方法等进行阐述。
Abstract:
Both methane and carbon dioxide are two major greenhouse gases, which can be used to produce syngas by reforming reaction. The syngas can be used to manufacture high value-added products using Ficher-Tropsch synthesis, which has an important significance for alleviating the energy crisis. The carbon deposition is formed using the commonly supported nickel catalyst, which results in the decrease of catalytic activity. Noble metals have an excellent catalytic performance and good stability. The carbon deposition resistance of supported noble metals is better than that of supported nickel catalyst in dry reforming of methane. In order to design well stable catalysts, the kinetic reaction models and catalytic reaction mechanism of noble metal catalysts in dry reforming of methane are reviewed, at the same time combining with catalysts, supports, preparation methods and so on.

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备注/Memo

备注/Memo:
收稿日期:2015-05-09。基金项目:江苏省自然科学基金(BK20150260); 常州大学科研启动基金资助项目(ZMF15020070)。作者简介:吴王平(1985—),男,安徽安庆人,博士,讲师,主要从事贵金属及其合金涂层材料研究。
更新日期/Last Update: 2015-10-20