[1]王亚飞,朱梦冰,杨春诚,等.基于亚氨基芪共轭分子的合成及其性能[J].常州大学学报(自然科学版),2017,(05):28-34.[doi:10.3969/j.issn.2095-0411.2017.05.005]
　WANG Yafei,ZHU Mengbing,YANG Chuncheng,et al.Synthesis and Property Studies of D-π-A-π-A Conjugated Molecules Based on 10-Methoxy-5H-Dibenzo[b,f]azepine Unit[J].Journal of Changzhou University(Natural Science Edition),2017,(05):28-34.[doi:10.3969/j.issn.2095-0411.2017.05.005]
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基于亚氨基芪共轭分子的合成及其性能()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2017年05期
页码:
28-34
栏目:
材料科学与工程
出版日期:
2017-09-30

文章信息/Info

Title:
Synthesis and Property Studies of D-π-A-π-A Conjugated Molecules Based on 10-Methoxy-5H-Dibenzo[b,f]azepine Unit
作者:
王亚飞; 朱梦冰; 杨春诚; 朱卫国
江苏省环境友好高分子材料重点实验室, 江苏 常州 213164; 常州大学 材料科学与工程学院,江苏 常州 213164; 常州大学 材料科学与工程国家级实验教学示范中心,江苏 常州 213164
Author(s):
WANG Yafei;  ZHU Mengbing;  YANG Chuncheng;  ZHU Weiguo
Jiangsu Key Laboratory for Environment-Friendly Polymer Materials, Changzhou 213164, China; School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China; Jiangsu Collaborative Innovation Center of Photovoltaic Science and Engineering, Changzhou 213164, China
关键词:
10-甲氧基亚氨基芪;  异靛蓝;  末端基团;  D-π-A-π-A;  合成
Keywords:
10-methoxy-5H-dibenzo[b; f]azepine;  isoindigo;  terminal group;  D-π-A-π-A;  synthesis
分类号:
O 633.4
DOI:
10.3969/j.issn.2095-0411.2017.05.005
文献标志码:
A
摘要:
设计合成了4种基于10-甲氧基亚氨基芪的D-π-A-π-A型共轭小分子,并通过核磁共振氢谱、碳谱和飞行时间质谱确证了它们的分子结构。通过热失重分析(TGA)、紫外分光光度计(UV-Vis)和循环伏安法(CV)研究了这4种D-π-A-π-A分子的光物理性能; 初步探索了分子中给体单元的大小和末端受体单元的结构对分子光物理性能的影响。该研究为设计新型的D-π-A-π-A型共轭小分子有机光电材料具有一定的意义。
Abstract:
FourD-π-A-π-A conjugated molecules based on 10-methoxy-5H-dibenzo[b,f]azepine unit were designed and prepared in this context. The molecular structures were confirmed by 1H NMR, 13C NMR and TOF-MS. Furthermore, the photophysical properties of these molecules were investigated through TGA, UV-Vis and CV measurements. The effect of donor size and terminal acceptor unit in these molecules on their photophysical property were explored. This research has certain scientific significance for design novel organic optoelectronic materials with D-π-A-π-A feature.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2017-02-28。 基金项目:国家自然科学基金面上资助项目(51773021); 国家自然科学基金石油化工联合基金重点项目(U1663229)。 作者简介:王亚飞(1983—),男,湖南攸县人,博士,教授。通讯联系人:朱卫国(1964—),E-mail:zhuwg18@126.com
更新日期/Last Update: 2017-10-20