[1]杨海存,贾天飞,薛胜,等.凹凸棒土核壳杂化粒子改性聚苯乙烯的性能[J].常州大学学报(自然科学版),2017,(04):19-25.[doi:10.3969/j.issn.2095-0411.2017.04.004]
 YANG Haicun,JIA Tianfei,XUE Sheng,et al.Study on the Properties of Polystyrene Modified by Attapulgite Core-Shell Hybrid Particles[J].Journal of Changzhou University(Natural Science Edition),2017,(04):19-25.[doi:10.3969/j.issn.2095-0411.2017.04.004]
点击复制

凹凸棒土核壳杂化粒子改性聚苯乙烯的性能()
分享到:

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2017年04期
页码:
19-25
栏目:
材料科学与工程
出版日期:
2017-07-30

文章信息/Info

Title:
Study on the Properties of Polystyrene Modified by Attapulgite Core-Shell Hybrid Particles
作者:
杨海存1贾天飞1薛胜1潘霁1龚方红12刘春林1陶国良1马文中1
1.常州大学 材料科学与工程学院,江苏 常州 213164; 2.无锡职业技术学院 机械技术学院,江苏 无锡 214121
Author(s):
YANG Haicun1JIA Tianfei1 XUE Sheng1 PAN Ji1 GONG Fanghong12LIU Chunlin1TAO Guoliang1 MA Wenzhong1
1. School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China; 2. Department of Mechanical Technology, Wuxi Institute of Technology, Wuxi 214121, China
关键词:
凹凸棒土 杂化粒子 聚苯乙烯 力学性能 热稳定性 粘弹行为
Keywords:
attapulgite hybrid particles polystyrene mechanical property thermal stability viscoelastic behavior
分类号:
TQ 327.8
DOI:
10.3969/j.issn.2095-0411.2017.04.004
文献标志码:
A
摘要:
采用芳叔胺基团对凹凸棒土(ATP)进行表面修饰制备改性粒子(ATP-ATA),通过表面引发氧化-还原聚合制备凹凸棒土接枝聚苯乙烯杂化粒子(ATP@PS),利用X射线衍射(XRD)、X射线光电子能谱(XPS)、热失重(TGA)、场发射扫描电镜(FESEM)和透射电镜(TEM)对杂化粒子进行详细表征。通过熔融共混法制备PS/ATP@PS杂化材料,并研究杂化粒子含量对材料力学性能、热稳定性和粘弹行为的影响。结果表明,杂化粒子质量比为1.5%时,材料的拉伸强度、冲击强度和弯曲强度分别提高65.5%,28.5%和25.3%,随杂化粒子含量增大,材料的热稳定性提高,粘流态下具有较大的线性粘弹区和更长的松弛时间。
Abstract:
Attapulgite(ATP)was firstly modified with aromatic tertiary amine(ATA)to afford functionalized particles ATP-ATA. Subsequently, ATP grafted with polystyrene hybrid particles(ATP@PS)were prepared via surface-initiated redox polymerization. The resulted hybrid particles were characterized by X-ray diffraction(XRD), X-ray photoelectron spectroscopy(XPS), thermal gravimetric analysis(TGA), field-emission scanning electron microscopy(FESEM)and transmission electron microscopy(TEM). PS/ATP@PS hybrid material was prepared via melt blending technique, and the effects of particle contents on the mechanical property, thermal stability and viscoelastic behavior of hybrid materials were investigated in detail. Experimental results showed that as compared with pure PS, the tensile, impact and flexural strength with 1.5% content of ATP@PS increased by65.5%, 28.5% and 25.3%respectively. The thermal stability was enhanced as the increase of ATP@PS content, and broaderlinear viscoelastic region and longer relaxation time were observed in the viscous-flow state.

参考文献/References:

[1] 耿丽娜,洪钏,吴燕,等. 有机-无机杂化材料的应用研究进展[J]. 化学世界,2011,52(11):699-664.
[2]WANG S R, KANG Y F, WANG L W, et al. Organic/inorganic hybrid sensors: A review[J]. Sensors and Actuators B: Chemical, 2013, 182: 467-481.
[3]SANCHEZ C, JULIAN B, BELLEVILLE P, et al. Applications of hybrid organic-inorganic nanocomposites[J]. Journal of Materials Chemistry, 2005, 15: 3559-3592.
[4]LIU Y, KANG Y R, MU B, et al. Attapulgite/bentonite interactions for methylene blue adsorption characteristics from aqueous solution[J]. Chemical Engineering Journal, 2014, 237: 403-410.
[5]ZHU C Z, WANG X H, HUANG Q, et al.Removal of gaseous carbon bisulfide using dielectric barrier discharge plasmas combined with TiO2 coated attapulgitecatalyst[J]. Chemical Engineering Journal, 2013, 225: 567-573.
[6]LI J, YAN L, LI H Y, et al.A facile one-step spray-coating process for the fabrication of a superhydrophobicattapulgite coated mesh for use in oil/water separation[J]. RSC Advances, 2015, 5(66): 53802-53808.
[7]臧亚南,徐冬梅,刘琼琼. 凹凸棒土在工程塑料中的应用进展[J]. 工程塑料应用,2011,39(1):96-99.
[8]YANG H C, PU H T, GONG F H. Attapulgitegrafted with polystyrene via a simultaneous reverse and normal initiation atom transfer radical polymerization[J]. Journal of Polymer Science Part A: Polymer Chemistry, 2016, 54(11): 1508-1516.
[9]YANG H C, XUE S, PAN J, et al. Preparation of core-shell attapulgite particles byredox-initiated surface reversible addition-fragmentation chain transfer polymerization via a “graft from” approach[J]. RSC Advances, 2016, 6(17): 14120-14127.
[10]姚海军,杨永青,常新林,等. 聚苯乙烯改性方法及其应用研究进展[J]. 化学工程与装备,2009(7):142-145.
[11]Liu YS, Liu P, Su ZX. Thermal stabilities of attapulgite/polystyrene(ATP/PS)nanocomposites via microwave-assisted bulk polymerization[J]. Journal of Dispersion Science and Technology, 2008, 29(4): 478-481.
[12]杨利营,宋仁峰,盛京. 在位分散聚合制备聚苯乙烯/凹凸棒土复合材料[J]. 中国塑料,2002,16(7):47-52.
[13]ZHANG L, YANG H C, LIU H, et al. Preparation and characterization of polystyrene-graftedattapulgite via surface-initiated redox polymerization[J]. Polymer Engineering and Science, 2015, 55(4): 889-895.

相似文献/References:

[1]蔡 晋,董如林,何越江,等.凹凸棒土的表面改性及其在不饱和聚酯树脂中的应用[J].常州大学学报(自然科学版),2014,(02):14.[doi:10.3969/j.issn.2095-0411.2014.02.005]
 Surface Modification of Attapulgite and Its Applicationin Unsaturated Polyester Resin.Surface Modification of Attapulgite and Its Applicationin Unsaturated Polyester Resin[J].Journal of Changzhou University(Natural Science Edition),2014,(04):14.[doi:10.3969/j.issn.2095-0411.2014.02.005]
[2]姚 超,张 良,丁永红,等.导电凹凸棒土的制备[J].常州大学学报(自然科学版),2007,(04):5.
 YAO Chao,ZHAN G Liang,DIN G Yong - hong,et al.Preparation of Conductive Attapulgite[J].Journal of Changzhou University(Natural Science Edition),2007,(04):5.
[3]董良飞,郜 飞,刘会东,等.凹凸棒土/玉米秸秆生物炭制备及对四环素的吸附[J].常州大学学报(自然科学版),2023,35(02):46.[doi:10.3969/j.issn.2095-0411.2023.02.006 ]
 DONG Liangfei,GAO Fei,LIU Huidong,et al.Preparation of attapulgite/corn straw biochar and its adsorption on tetracycline[J].Journal of Changzhou University(Natural Science Edition),2023,35(04):46.[doi:10.3969/j.issn.2095-0411.2023.02.006 ]

备注/Memo

备注/Memo:
收稿日期:2016-12-27。基金项目:江苏省高校优势学科建设工程资助项目(苏学科办[2014]9); 国家自然科学基金资助项目(21406017)。作者简介:杨海存(1987—),男,江苏泰州人,博士,讲师,主要从事有机-无机杂化材料研究。通讯联系人:龚方红(1966—),E-mail:fhgong@cczu.edu.cn
更新日期/Last Update: 2017-07-20