[1]雷冲,毛辉麾,张忠明,等.两步水热法合成磺酸功能化碳质纳米微球及其催化性能研究[J].常州大学学报(自然科学版),2018,30(02):23-29.[doi:10.3969/j.issn.2095-0411.2018.02.004]
　LEI Chong,MAO Huihui,ZHANG Zhongming,et al.Synthesis of Sulfuric Acid Functional Carbonaceous Sphere Through Two-Steps Hydrothermal and Their Catalyst Application[J].Journal of Changzhou University(Natural Science Edition),2018,30(02):23-29.[doi:10.3969/j.issn.2095-0411.2018.02.004]
点击复制

两步水热法合成磺酸功能化碳质纳米微球及其催化性能研究()
分享到：

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第30卷
期数:
2018年02期
页码:
23-29
栏目:
化学化工
出版日期:
2018-03-31

文章信息/Info

Title:
Synthesis of Sulfuric Acid Functional Carbonaceous Sphere Through Two-Steps Hydrothermal and Their Catalyst Application
作者:
雷冲; 毛辉麾; 张忠明; 王倩倩
常州大学 石油化工学院,江苏 常州 213164
Author(s):
LEI Chong;  MAO Huihui;  ZHANG Zhongming; WANG Qianqian
School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
关键词:
水热法;  纳米碳质;  纳米微球;  酸催化
Keywords:
hydrothermal;  nano-carbonaceous;  nano sphere;  acidic catalysis
分类号:
TQ 645.6
DOI:
10.3969/j.issn.2095-0411.2018.02.004
文献标志码:
A
摘要:
在相对温和的条件下通过两步法水热合成制备了表面富含磺酸基官能团的碳质纳米微球。并对实验方法和条件进行了全面的考察,通过红外光谱(FT-IR)和表面能谱(XPS)分析在碳纳米微球表面形成的磺酸基; 用扫描电镜(SEM)和透射电镜(TEM)分别表征碳纳米微球表面形貌,颗粒大小及微观结构; 碳纳米微球的孔道结构用氮气吸附-脱附(N2 adsorption-desorption isotherms)进行表征。表征结果证明,获得的磺酸功能化碳质纳米微球具有高比表面积,大量的活性酸性位等特点。催化测试实验证明该碳纳米微球材料可作为一种高效廉价的催化剂用于果糖酸催化脱水合成羟甲糠醛(HMF)。
Abstract:
The monodispersed activated hydrothermal carbons coated with sulfonic acid groups carbonaceous composite sphere was successfully synthesized through two-step hydrothermal carbonization under mild conditions. The effect of experimental conditions on the morphology of carbonaceous spheres has been investigated systematically. The sulfonic acid groups on the surface of the materials had been characterized by XPS and FT-IR, and the morphology and particle size had been analyzed through TEM and SEM. The N2 adsorption-desorption isotherms were used to characterize the specific surface areas, pore volumes and porous structure. The carbonaceous material owned high acidity and showed the comparable activities to sulfuric acid for the traditional acid-catalyzed reactions. During catalytic activities research, the obtained carbonaceous exhibit excellent acidic catalytic activities in synthesizing 5-hydroxymethylfurfural(HMF)from dehydration using fructose as raw material.

参考文献/References:

[1]LIANG X,ZENG M,QI C,One-step synthesis of carbon functionalized with sulfonic acid groups using hydrothermal carbonization[J]. Carbon,2010(48):1844-1848.
[2]MAKOWSKI P,R. DEMIR-CAKAN,ANTONIETTI M,et al. Selective partial hydrogenation of hydroxy aromatic derivatives with palladium nanoparticles supported on hydrophilic carbon[J]. Chem Commun,2008,39(28):999-1001.
[3]HU Y S,DEMIR-CAKAN R,TITIRICI M M,et al. Superior storage performance of a Si@SiOx/C nanocomposite as anode material for lithium-ion batteries[J]. Angew Chem Int Ed,2008,47(9):1645-1649.
[4]WATANABE M,AIZAWA Y,IIDA T,et al. Glucose reactions with acid and base catalysts in hot compressed water at 473K[J]. Carbohydr Res,2005,340(12):1925-1930.
[5]SUN X, LI Y. Colloidal carbon spheres and their core/shell structures with noble-metal nanoparticles[J]. Angew Chem Int Ed,2004(116):607-611.
[6]NAKAJIMA K,OKAMURA M. KONDO J N,et al. Amorphous carbon bearing sulfonic acid groups in mesoporous silica as a selective catalyst[J]. Chem Mater,2009(21):186-193.
[7]CHEN L F,LIANG H W,LU Y,et al. Synthesis of an attapulgite clay@carbon nanocomposite adsorbent by a hydrothermal carbonization process and their application in the removal of toxic metal ions from water[J]. Langmuir,2011(27):8998-9004.
[8]LI T,SHEN J,HUANG S,et al. Hydrothermal carbonization synthesis of a novel montmorillonite supported carbon nanosphere adsorbent for removal of Cr(VI)from waste water[J]. Appl Clay Sci,2014(93/94):48-55.
[9]OKUHARA T. Water-tolerant solid acid catalysts[J]. Chem Rev,2002(102):3641-3666.
[10]NAKAJIMA K,HARA M. Amorphous carbon with SO3H groups as a solid br?nsted acid catalyst[J]. ACS Catal,2012(2):1296-1304.
[11]OKAMURA M,TAKAGAKI A,TODA M,et al. Acid-catalyzed reactions on flexible polycyclic aromatic carbon in amorphous carbon[J]. Chem Mater,2006(18):3039-3045.
[12]GUO X,CAO Q,JIANG Y,et al. Selective dehydration of fructose to 5-hydroxymethylfurfural catalyzed by mesoporous SBA-15-SO3H in ionic liquid Bmim Cl[J]. Carbohydr Res, 2012(351):35-41.
[13]ZHAO L,BACCILE N,GROSS S,et al. Sustainable nitrogen-doped carbonaceous materials from biomass derivatives[J].Carbon,2010(48):3778-3787.
[14]毛辉麾,朱孔南,张光程.羧酸功能化纳米碳包覆凹凸棒石材料的制备及其吸附应用研究〖J〗.常州大学学报(自然科学版),2016,28(4):43-47.
[15]关媛,王少莽,易广,等. 酸化凹凸棒石的制备及其对苯胺的吸附性能〖J〗. 常州大学学报(自然科学版), 2017,29(6):15-25.
[16]WANG X, GU J, TIAN L, et al. Hierarchical porous interlocked polymeric microcapsules:sulfonic acid functionalization as acid catalysts〖J〗. Sci Rep, 2017, 7:44178.
[17]NATA I F, PUTRA M D, IRAWAN, et al. Catalytic performance of sulfonated carbon-based solid acid catalyst on esterification of waste cooking oil for biodiesel production〖J〗.J Environ Chem Eng, 2017, 5(3):2171-2175.
[18]ZHANG Z,DUAN H,LI S,et al. Assembly of magnetic nanospheres into one-dimensional nanostructured carbon hybrid materials[J]. Langmuir,2010,26(9):6676-6680.
[19]ZHU K,JIA H,WANG F,et al. Efficient removal of Pb(II)from aqueous solution by modified montmorillonite/carbon composite: equilibrium, kinetics, and thermodynamics[J]. J Chem Eng Data,2017,62(1):333-341.
[20]SEVILLA M,FUERTES A B. Highly porous S-doped carbons[J]. Micropor Mesopor Mater,2012(158):318-323.
[21]SEVILLA M,FUERTES A B. Chemical and structural properties of carbonaceous products obtained by hydrothermal carbonization of saccharides[J]. Chem Eur J,2009(15):4195-4203.
[22]HU L, ZHAO G, HAO W, et al. Catalytic conversion of biomass-derived carbohydrates into fuels and chemicals via furanic aldehydes[J]. RSC Advances,2012(2):11184-11206.

相似文献/References:

[1]陈若愚,李　坤.水热法制备锆钛酸铅纳米粉体[J].常州大学学报(自然科学版),2000,(03):20.
　CHEN Ruo -yu,LI Kun.Syntheses of Lead Zirconate Titanate Powder Under Hydrothermal Conditions[J].Journal of Changzhou University(Natural Science Edition),2000,(02):20.
[2]杨辉龙,段家骥,张福长,等.ZnO/石墨烯复合材料的制备及其光催化性能[J].常州大学学报(自然科学版),2017,(03):13.[doi:10.3969/j.issn.2095-0411.2017.03.003]
　YANG Huilong,DUAN Jiaji,ZHANG Fuchang,et al.Preparation and Study of Photocatalytic Properties of the Composite Materials of Zinc Oxide/Graphene[J].Journal of Changzhou University(Natural Science Edition),2017,(02):13.[doi:10.3969/j.issn.2095-0411.2017.03.003]
[3]宋 艳,宗 旭,张 鑫,等.水热法制备羟甲基化木质素工艺研究[J].常州大学学报(自然科学版),2021,33(02):8.[doi:10.3969/j.issn.2095-0411.2021.02.002]
　SONG Yan,ZONG Xu,ZHANG Xin,et al.Methylolation of Lignin by Hydrothermal Method[J].Journal of Changzhou University(Natural Science Edition),2021,33(02):8.[doi:10.3969/j.issn.2095-0411.2021.02.002]

备注/Memo

备注/Memo:
收稿日期:2017-09-30。
基金项目:国家自然科学基金资助项目(21401014); 江苏省自然科学基金资助项目(BK20140255)。
作者简介:雷冲(1994—),男,山东枣庄人,硕士生。通信联系人:毛辉麾(1981—),E-mail: maohuihui_beijing@126.com
更新日期/Last Update: 2018-03-20