[1]田 俐,王会锋,李 岩,等.PPy@In-BDC复合材料的制备与表征[J].常州大学学报(自然科学版),2018,30(03):28-33.[doi:10.3969/j.issn.2095-0411.2018.03.003]
 TIAN Li,WANG Huifeng,LI Yan,et al.Preparation and Characterization of the PPy@In-BDC Composite Material[J].Journal of Changzhou University(Natural Science Edition),2018,30(03):28-33.[doi:10.3969/j.issn.2095-0411.2018.03.003]
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PPy@In-BDC复合材料的制备与表征()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
30
期数:
2018年03期
页码:
28-33
栏目:
材料科学与工程
出版日期:
2018-05-28

文章信息/Info

Title:
Preparation and Characterization of the PPy@In-BDC Composite Material
作者:
田 俐1王会锋2李 岩2陈善民1刘 强1罗 奇1郭 珍1邬发发1李英杰1林彬彬1
1. 湖南科技大学 材料科学与工程学院,湖南 湘潭 411201; 2. 湖南科技大学 化学化工学院,湖南 湘潭 411201
Author(s):
TIAN Li1 WANG Huifeng2 LI Yan2 CHEN Shanmin1 LIU Qiang1 LUO Qi1 GUO Zhen1 WU Fafa1 LI Yingjie1 LIN Binbin1
1. School of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China; 2. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
关键词:
聚吡咯 In-BDC 复合材料 电导率
Keywords:
polypyrrole In-BDC composite material conductivity
分类号:
TB 33
DOI:
10.3969/j.issn.2095-0411.2018.03.003
文献标志码:
A
摘要:
通过碘氧化法,在金属有机框架材料In-BDC(BDC2- 为对苯二甲酸酸酐)的一维孔道内实现吡咯的化学氧化聚合,得到了PPy@In-BDC复合材料。利用X射线粉末衍射、扫面电子显微镜、热失重、红外光谱、N2吸附以及四探针法表征了制备过程中所得材料的结构、组成及性能。压片成型后,PPy@In-BDC复合材料的电导率达10-5S/cm,和无模板法合成的块状聚吡咯(~10-8S/cm)及模板In-BDC相比,至少有3个数量级的提高。
Abstract:
In the 1D channels of the In-BDC, polypyrrole could be synthesised by iodine oxidation, and then the PPy@In-BDC composite material was achieved. The structure, composition and properties of the obtained materials were characterized by PXRD, SEM, TG, IR, N2 adsorption and four-probe method. The electronic conductivity of PPy@In-BDC composite material after molded was 10-5 S/cm, which had an increment of at least three orders of magnitude, compared with the bulk PPy(—10-8 S/cm)and In-BDC template.

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备注/Memo

备注/Memo:
收稿日期:2018-03-20。
基金项目:国家自然科学基金(51202066,21333005); 教育部新世纪优秀人才支持计划项目(NCET-13-0784); 湖南省研究生科研创新项目(CX2016B540); 湖南科技大学大学生科研创新计划项目( SYZ2016050,YZ2017068)。
作者简介:田俐(1973—),女,湖南株洲人,博士,教授,主要从事材料化学研究。E-mail:849050031@qq.com
更新日期/Last Update: 2018-05-20