[1]刘长海,张 进,陈智栋,等.硼添加剂对背钝化太阳能电池的性能影响及机理研究[J].常州大学学报(自然科学版),2018,30(05):9-16.[doi:10.3969/j.issn.2095-0411.2018.05.002]
 LIU Changhai,ZHANG Jin,CHEN Zhidong,et al.Study on Effects and Mechanism of Boron Additive for PERC Solar Cell[J].Journal of Changzhou University(Natural Science Edition),2018,30(05):9-16.[doi:10.3969/j.issn.2095-0411.2018.05.002]
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硼添加剂对背钝化太阳能电池的性能影响及机理研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
30
期数:
2018年05期
页码:
9-16
栏目:
材料科学与工程
出版日期:
2018-09-28

文章信息/Info

Title:
Study on Effects and Mechanism of Boron Additive for PERC Solar Cell
作者:
刘长海1张 进1陈智栋2 VITYUK Sergey3
1.常州大学 材料科学与工程学院,江苏 常州 213164; 2. 常州大学 石油化工学院,江苏 常州 213164; 3.摩诺克里斯光伏科技(常州)有限公司,江苏 常州 213164
Author(s):
LIU Changhai1 ZHANG Jin1 CHEN Zhidong2 VITYUK Sergey3
1. School of Materials Science and Engineering, Changzhou University, Changzhou 213614, China; 2. School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China; 3. Monocrystal PV Technology(Changzhou)Co., Ltd., Changzhou 213164, China
关键词:
背钝化太阳能电池 硼添加剂 背表面层
Keywords:
PERC solar cell boron additives local back surface field
分类号:
TM 914.41
DOI:
10.3969/j.issn.2095-0411.2018.05.002
文献标志码:
A
摘要:
以3种含硼化合物作为添加剂,对背钝化(PERC)太阳能电池铝浆进行了系统地性能研究。其中,Na2B4O7·10H2O的添加质量分数为1.0%时,填充因子最大可达到78.5%,太阳能电池光电转换效率可达到20.2%。通过SEM和EDS对PERC电池片的横截面进行微观形貌表征和元素分析,发现硼添加剂对于PERC电池的局部背表面层(LBSF)的厚度产生一定的影响,从而会进一步影响背钝化太阳能电池的电性能; 另外,EDS结果表明靠近LBSF层及界面铝浆中的硅含量都有增加。因此可以推断,局部背表面层厚度的增加与硼添加剂可以增加铝硅在烧结时的互扩散有关。
Abstract:
Three different boron compounds were used and systematically studied as aluminum paste additives for passivated emitter rear contact(PERC)solar cells. The fill factor(FF)can increase to 78.5% and the photo-electric conversion of the PERC solar cells can reach an appreciable value of 20.2%, when 1.0% of Na2B4O7·10H2O boron additive is added into aluminum paste. The microstructures and elemental analysis of the cross-section of the PERC solar cell were carried out by SEM and EDS. The SEM results show that the boron additive can increase the inter-diffusion between aluminum and silicon atoms during sintering, and meanwhile the the thickness of local back surface field(LBSF)layer can also be controlled, which will affect the electrical properties of the solar cells. In addition, the EDS results indicate that the increased thickness of LBSF layer is related to the increased inter-diffusion. And according to analysis of above results, the possible mechanism of boron-based additives in PERC solar cells was also explored.

参考文献/References:


[1]BLAKERS A W, WANG A, MILNE A M, et al. 22.8% efficient silicon solar cell[J].Appl Phys Lett, 1989, 55(13): 1363-1365.
[2]WANG A, ZHAO J, GREEN M A. 24% efficient silicon solarcells[J]. Appl Phys Lett, 1990, 57(6): 602-604.
[3]FISCHER G, MULLER M, STECKEMETZ S, et al. Model based continuous improvement of industrial p-type PERC technology beyond 21% efficiency[J]. Energy Procedia, 2015, 77: 515-519.
[4]SAGA T. Advances in crystalline silicon solar cell technology for industrial massproduction[J]. NPG Asia Mater, 2010, 2(3): 96-102.
[5]DRESSLER K, KRATT M, VOSS P A, et al. Influence of Al particle size and firing profile on void formation in rear local contacts of silicon solarcells[J]. IEEE Journal of Photovoltaics, 2016, 6(1): 68-73.
[6]HORBELT R, EBERT S, ULBIKAITE V, et al. Al-density variation as one driving force for void formation in PERC solar cells[J]. Physica Status Solidi(RRL)-Rapid Research Lett, 2016, 10(7): 515-519.
[7]CHIU Y S, CHENG C L, WHANG T J, et al. Effects of silicate glasses in aluminum pastes on physical and electrical characteristics of screen-printed multi-crystalline silicon solarcells[J]. Mater Lett, 2014, 126: 143-146.
[8]RAUER M, SCHMIGA C, GLATTHAAR M, et al. Alloying from screen-printed aluminum pastes containing boronadditives[J]. IEEE Journal of Photovoltaics, 2013, 3(1):206-211.
[9]IKEDA Y, TOMIZWA Y, ITOH H, et al. Investigation ofrear localized back surface field formed from boron laser doping and screen-printed aluminum paste in high-efficiency solar cells[J]. Energy Procedia, 2016, 92: 404-411.
[10]LIN C H, TSAI S Y, HSU S P, et al. Structural properties of the solidified-Al/regrown-Si structures of printed Al contacts on crystalline Si solarcells[J]. Solar Energy Mater and Solar Cells, 2008, 92(8): 986-991.
[11]FANG H C, CHANG CC, LIU C P, et al. Effects of back surface textures on contact formation and solar cell performance[J]. J Electrochem Soc, 2010, 157(3): 246-249.
[12]吕伟,房香,董旭,等.CH3NH3PbI3多晶薄膜的铁电光伏性能研究[J].常州大学学报(自然科学版), 2016,28(2): 20-23.

[13]GREEN M A. The passivated emitter and rear cell(PERC): from conception to mass production[J]. Solar Energy Mater and Solar Cells,2015,143:190-197.

备注/Memo

备注/Memo:
收稿日期:2018-04-15。
基金项目:国家自然科学基金资助项目(51702025); 江苏省自然科学基金资助项目(BK20160277)。
作者简介:刘长海(1986-),男,山东淄博人,博士,讲师。 通信联系人:陈智栋(1964—),E-mail:zdchen@cczu.edu.cn
更新日期/Last Update: 2018-09-28