[1]陈圣春,史 娟,何明阳,等.邻菲罗啉铋配合物的制备、结构及催化性能[J].常州大学学报(自然科学版),2018,30(06):1-8.[doi:10.3969/j.issn.2095-0411.2018.06.001]
 CHEN Shengchun,SHI Juan,HE Mingyang,et al.Syntheses, Structures and Catalytic Activity of Bismuth Complexes Based on Phenanthroline Derivatives[J].Journal of Changzhou University(Natural Science Edition),2018,30(06):1-8.[doi:10.3969/j.issn.2095-0411.2018.06.001]
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邻菲罗啉铋配合物的制备、结构及催化性能()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
30
期数:
2018年06期
页码:
1-8
栏目:
化学化工
出版日期:
2018-11-28

文章信息/Info

Title:
Syntheses, Structures and Catalytic Activity of Bismuth Complexes Based on Phenanthroline Derivatives
作者:
陈圣春史 娟何明阳陈 群
(常州大学 石油化工学院,江苏 常州 213164)
Author(s):
CHEN Shengchun SHI Juan HE Mingyang CHEN Qun
(School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China)
关键词:
开环聚合 聚己内酯 铋配合物 晶体结构
Keywords:
ring-opening polymerization poly(ε-caprolactone) Bi(III)complex crystal structure
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2018.06.001
文献标志码:
A
摘要:
以4,7-二甲基-1,10-邻菲罗啉(dmphen)和4,7-二苯基-1,10-邻菲罗啉(dpphen)为配体分别与三氯化铋反应,经常温挥发合成了2个新的配合物Bi2(dmphen)2Cl6(DMSO)2(1)和[Bi(dpphen)Cl4]·Hdpphen·DMF(2)。晶体结构分析表明,双核结构的配合物1中Bi(Ⅲ)离子配位数为7,显示为五角双锥构型,而单核的配合物2中Bi(Ⅲ)离子配位数为6,呈现为八面体构型。考察了所得配合物对催化ε-己内酯本体开环聚合的催化性能,结果表明,配合物1对该反应显示出较高的单体转化率、所得聚酯分子质量较高、分子质量分布较窄以及不同位次取代的己内酯底物都能适用于该催化体系。
Abstract:
Reaction of BiCl3 with 4,7-dimethyl-1,10-phenanthroline(dmphen)or 4,7-diphenyl-1,10-phenanthroline(dpphen)synthesized two new complexes Bi2(dmphen)2Cl6(DMSO)2(1)and [Bi(dpphen)Cl4]·Hdpphen·DMF(2), respectively. Complexes 1 and 2 displays dinuclear and mononuclear molecular structure types, where each Bi(Ⅲ)ion in 1 is seven-coordinated with a pentagonal bipyramidal geometry, while each Bi(III)ion in 2 shows a six-coordinated octahedral geometry. The results of catalytic experiments showed that 1 is more active than 2 towards bulk ring-opening polymerization of ε-caprolactones with high monomer conversion, giving polyesters with high molecular weights and narrow molecular weight distributions. Furthermore, the Bi(Ⅲ)complexes also exhibited catalytic activity for substituted ε-caprolactones in different positions.

参考文献/References:


[1] HABIBI Y, GOFFIN A L, SCHILTZ N, et al. Bionanocomposites based on poly(ε-caprolactone)-grafted cellulose nanocrystals by ring-opening polymerization [J]. J Mater Chem, 2008, 18(41): 5002-5010.
[2]BOUYAHYI M, PEPELS M P F, HEISE A, et al. 䥺SymbolwA@ -Pentandecalactone polymerization and 䥺SymbolwA@ -pentandecalactone/ε-caprolactone copolymerization reactions using organic catalysts [J]. Macromolecules, 2012, 45(8): 3356-3366.
[3]CHENH Y, HUANG B H, LIN C C. A highly efficient initiator for the ring-opening polymerization of lactides and ε-caprolactone: a kinetic study [J]. Macromolecules, 2005, 38(13): 5400-5405.
[4]CHAGNEUX N, TRIMAILLE T, ROLLET M, et al. Synthesis of poly(n-butyl acrylate)-b-poly(ε-caprolactone)through combination of SG1 nitroxide-mediated polymerization and Sn(Oct)2-catalyzed ring-opening polymerization: study of sequential and one-step approaches from a dual initiator [J]. Macromolecules, 2009, 42(24): 9435-9442.
[5]YANG N, SUN H. Biocoordination chemistry of bismuth: recent advances [J]. Coord Chem Rev, 2007, 251(17): 2354-2366.
[6]PARK Y, MCDONALD K J, CHOI K-S. Progress in bismuth vanadate photoanodes for use in solar water oxidation [J]. Chem Soc Rev, 2013, 42(6): 2321-2337.
[7]GUAN M, XIAO C, ZHANG J, et al.Vacancy associates promoting solar-driven photocataytic activity of ultrathin bismuth oxychloride nanosheets [J]. J Am Chem Soc, 2013, 135(28): 10411-10417.
[8]邬纯晶, 杨超, 曹剑瑜, 等. 水热法合成NCQD/BiOCl复合物及其光催化分解水性能 [J]. 常州大学学报(自然科学版), 2018, 30(3): 41-49.
[9]LU Y, SCHMIDT C, BEUERMANN S. Fast synthesis of high-molecular-weight polyglycolide using diphenyl bismuth bromide as catalyst [J]. Macromol Chem Phys, 2015, 216(4): 395-399.
[10]DUVAL C, NOUVEL C, SIX J L. Is bismuth subsalicylate an effective nontoxic catalyst for PLGA synthesis [J]. J Polym Sci Pol Chem, 2014, 52(8): 1130-1138.
[11]VUORINEN S, LAHCINI M, HATANPAEAE T, et al. Bismuth(Ⅲ)alkoxide catalyst for ring-opening polymerization of lactides andε-caprolactone [J]. Macromol Chem Phys, 2013, 214(6): 707-715.
[12]GAO J, YUAN Y, CUI A J, et al. Bismuth(Ⅲ)complexes based on bis(triazol)ligands: effect of fluorine substitution on the structure and catalysis for the polymerization of glycolide [J]. Z Anorg Allg Chem, 2016, 642(11): 698-703.
[13]BRUKER A X S. SAINT software reference manual V. 6.23 [M]. Madison: WI, 2002.
[14]SHELDRICK G M. A short history of SHELX [J]. Acta Crystallogr, 2008, A64: 112-122.
[15]DECHY-CABARET O, MARTIN-VACA B, BOURISSOU D. Controlled ring-opening polymerization of lactide and glycolide [J]. Chem REV, 2004, 104(12): 6147-6176.

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备注/Memo

备注/Memo:
基金项目:国家自然科学基金资助项目(21676030)。
作者简介:陈圣春(1976—),男,江苏盐城人,博士,副研究员。通信联系人:陈群(1963-),E-mail: 13906123032@cczu.edu.cn
更新日期/Last Update: 2018-10-28