[1]吴敏娴,汤荣军,夏 寒,等.氯乙酸水溶液中低电压沉积碳膜研究[J].常州大学学报(自然科学版),2019,31(05):31-35.[doi:10.3969/j.issn.2095-0411.2019.05.005]
　WU Minxian,TANG Rongjun,XIA Han,et al.Low Voltage Electrodeposition of Carbon Films from Aqueous Solutions[J].Journal of Changzhou University(Natural Science Edition),2019,31(05):31-35.[doi:10.3969/j.issn.2095-0411.2019.05.005]
点击复制

氯乙酸水溶液中低电压沉积碳膜研究()
分享到：

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第31卷
期数:
2019年05期
页码:
31-35
栏目:
材料科学与工程
出版日期:
2019-09-28

文章信息/Info

Title:
Low Voltage Electrodeposition of Carbon Films from Aqueous Solutions
文章编号:
2095-0411(2019)05-0031-05
作者:
吴敏娴; 汤荣军; 夏 寒; 王文昌; 陈智栋
(常州大学 石油化工学院,江苏 常州 213164)
Author(s):
WU Minxian;  TANG Rongjun;  XIA Han;  WANG Wenchang;  CHEN Zhidong
(School of Petroleum Engineering,Changzhou University,Changzhou 213164,China)
关键词:
电沉积;  碳膜;  氯乙酸;  低电压;  不锈钢
Keywords:
electrodeposition;  carbon films;  chloroacetic acid;  low voltage;  stainless steel
分类号:
TG 174.44
DOI:
10.3969/j.issn.2095-0411.2019.05.005
文献标志码:
A
摘要:
采用电化学沉积技术,在较低的电压(8～11 V)下,以氯乙酸为碳源、甲酸钠为支持电解质,在304不锈钢基体上电沉积制备碳膜,研究了沉积电压、沉积时间及氯乙酸质量浓度对碳膜形貌和性质的影响。通过扫描电镜(SEM)观察薄膜微观形貌及生长规律,发现薄膜由纳米颗粒和片层结构组成,并随着电压增加,片层结构更为致密。拉曼光谱显示碳膜由sp2碳和sp3碳组成,sp3碳成分随沉积电压及沉积时间的增加而增加。
Abstract:
Carbon films were electrodeposited from aqueous solutions containing chloroacetic acid and sodium formate with low applied voltage(8～11 V)on 304 stainless steel. The effects of applied voltage, plating time and the concentration of chloroacetic acid on film morphology and structure have been investigated. The carbon films were composed of nanoparticles and nanosheets. With the increase in deposition voltage, the carbon nanosheets became smaller and denser. Raman spectra illustrated that the carbon films contained both sp2 and sp3 bonded carbon. The content of sp2 bonded carbon increased with the deposition time.

参考文献/References:

[1]ROBERTSON J F R. Diamond-like amorphous carbon[J]. Materials Science and Engineering R Reports, 2002, 37(4/5/6): 129-281.
[2]YAN X B, XU T, YANG S R, et al. Characterization of hydrogenated diamond-like carbon films electrochemically deposited on a silicon substrate[J]. Journal of Physics D: Applied Physics, 2004, 37(17): 2416-2424.
[3]杜开瑛, 石瑞英, 谢茂浓, 等. 直接光CVD类金刚石碳膜的初期成膜结构[J]. 半导体光电, 1999, 20(6): 405-408.
[4]阳硕.直流辉光放电CVD法制备纳米金刚石薄膜的研究[D].武汉:武汉工程大学, 2017.
[5]李晓红, 郭晚土, 陈学康, 等. 微波化学气相沉积中气压对金刚石薄膜生长速率和质量的影响[J]. 物理学报, 2007, 56(12): 7183-7187.
[6]PANDIYARAJ K N, SELVARAJAN V, HEEG J, et al. Influence of bias voltage on diamond like carbon(DLC)film deposited on polyethylene terephthalate(PET)film surfaces using PECVD and its blood compatibility[J]. Diamond and Related Materials, 2010, 19(7/8/9): 1085-1092.
[7]IJIJE H V, LAWRENCE R C, CHEN G Z. Carbon electrodeposition in molten salts: Electrode reactions and applications[J]. RSC Advances, 2014, 4(67): 35808-35817.
[8]DENG B W, MAO X H, XIAO W, et al. Microbubble effect-assisted electrolytic synthesis of hollow carbon spheres from CO2[J]. Journal of Materials Chemistry A, 2017, 5(25): 12822-12827.
[9]NAMBA Y. Attempt to grow diamond phase carbon films from an organic solution[J]. Journal of Vacuum Science & Technology A, 1992, 10(5): 3368-3370.
[10]PANG H, WANG X Q, ZHANG G L, et al. Characterization of diamond-like carbon films by SEM, XRD and Raman spectroscopy[J]. Applied Surface Science, 2010, 256(21): 6403-6407.
[11]GUPTA S, PAL C M, PAL A K. Synthesis of DLC films by electrodeposition technique using formic acid as electrolyte[J]. Diamond and Related Materials, 2004, 13(9): 1680-1689.
[12]GUPTA S, ROY R K, DEB B, et al. Low voltage electrodeposition of diamond-like carbon films[J]. Materials Letters, 2003, 57(22/23): 3479-3485.
[13]HASSANNEJAD H, BOGANI F, BONIARDI M, et al. Electrodeposition of DLC films on carbon steel from acetic acid solutions[J]. Transactions of the IMF, 2014, 92(4): 183-188.
[14]ZHANG Q, WANG Y R, WANG W C, et al. Low voltage and ambient temperature electrodeposition of uniform carbon films[J]. Electrochemistry Communications, 2016, 63: 22-25.
[15]DRESSELHAUS M S, DRESSELHAUS G, SAITO R, et al. Raman spectroscopy of carbon nanotubes[J]. Physics Reports, 2005, 409(2): 47-99.
[16]SCHWAN J, ULRICH S, BATORI V, et al. Raman spectroscopy on amorphous carbon films[J]. Journal of Applied Physics, 1996, 80(1): 440-447.

相似文献/References:

[1]许娟,薛宇,王国鑫,等.柔性氢氧化镍/石墨烯膜的制备及超电容性能研究[J].常州大学学报(自然科学版),2015,(03):7.[doi:10.3969/j.issn.2095-0411.2015.03.002]
　XU Juan,XUE Yufei,WANG Guoxin,et al.Preparation of Flexible Nickel Hydroxide-Graphene Film and Its Supercapacitor Performances[J].Journal of Changzhou University(Natural Science Edition),2015,(05):7.[doi:10.3969/j.issn.2095-0411.2015.03.002]

备注/Memo

备注/Memo:
收稿日期:2018-07-26。
基金项目:国家自然科学基金资助项目(51574047)。
作者简介:吴敏娴(1986—),女,江苏常州人,博士,讲师。通信联系人:陈智栋(1964—), E-mail: zdchen@cczu.edu.cn
更新日期/Last Update: 2019-09-30