[1]陈　勇,杨　光,张新兵,等.二茂铁衍生物的合成和表征[J].常州大学学报(自然科学版),2002,(02):14-16.
　CHENG Yong,YANG Guang,ZHANG Xin -bing,et al.Synthesi s and Characterization of Ferrocene Der ivatives[J].Journal of Changzhou University(Natural Science Edition),2002,(02):14-16.
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二茂铁衍生物的合成和表征()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2002年02期
页码:
14-16
栏目:
出版日期:
2002-06-25

文章信息/Info

Title:
Synthesi s and Characterization of Ferrocene Der ivatives
作者:
陈　勇1 ;  杨　光1 ;  张新兵1 ;  刘惠英2
1.江苏石油化工学院化学工程系, 江苏 常州 213016;2.武汉大学化学系, 湖北武汉430072
Author(s):
CHENG Yong1 ;  YANG Guang1 ;  ZHANG Xin -bing1 ;  LIU Hui -ying2
1 .Department of Chemical Engineering , Jiangsu Institute of Pet rochemical Technology , Changzhou 213016 , China ;2 .Department of Chemist ry , Wuhan University , Wuhan 430072 , China
关键词:
二茂铁衍生物; 合成; 表征
Keywords:
ferrocene derivative ; synthesis; characterization
分类号:
O 627.8
文献标志码:
A
摘要:
由二茂铁和芳胺作为原料通过芳基化作用合成了3 个新二茂铁衍生物。通过元素分析、IR、1HNMR 和MS 确证了化合物 结构。这些化合物的其它性质和用途还有待研究。
Abstract:
In the investigatio n , three new ferrocene derivatives w ere sy nthesized by arylatio n , using ferrocene and ary lamines as the starting materials .The st ructures of these new derivatives were confi rmed by elementary analy sis , IR , 1HNMR and MS .The o ther properties and uses of these compounds are yet to be studied .The y ields of three products w ere 17.3 %, 10.2 % and 20.3 %, respect ively .The test s found that the key step is the preparation of diazotization of arylamine .The result showed that the appropriate reaction condi tions should be :sulfuric acid as reaction medium ;at room temperature .

参考文献/References:

[1] 刘惠英, 付莎莉, 陈勇.二茂铁羧酸四乙酰葡萄糖酯的合成 [J] .化学试剂, 1996 , 18 (5):270 -272 .
[2] 袁耀锋, 叶素明, 张蕴文, 等.具有生物(理) 活性的二茂铁 衍生物[J] .化学通报, 1995 , 5 :24 -31 .
[3] Bouchet M , Bauer D .Comparison of Elect roact ivi ty Range [J] . J Elect roanal Chem Int erf acial Electrochem , 1975 , 63 (2):171 -186 .
[4] Weinm agr V.The Condensation of Dicyclopent adienyliron w ith Aromatic Diazonium S alt s [J] .J Am C hem S oc, 1955 , 77 :3 012 -3 014 .
[5] Rosenblum M .The St ructure and Chemi stry of Ferrocene IV Intraannular Resonance Effect s [J] .J Am Chem Soc, 1959 , 81 : 4 530 -4 536 .

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备注/Memo

备注/Memo:
基金项目:江苏石油化工学院科研基金资助 作者简介:陈勇(1971 -), 男, 江苏武进人, 硕士, 讲师, 从事二茂铁衍生物、糖苷(酯) 化合物合成研究。
更新日期/Last Update: 2002-06-25