[1]边广岭,姜 艳,王云翔,等.一种新的C2 对称手性多齿配体的合成[J].常州大学学报(自然科学版),2007,(02):1-3.
 BIAN Guang -ling,JIANG Yan,WANG Yun -xiang,et al.Synthesis of a Novel C2 -Symmetric Chiral Polydentate Ligand[J].Journal of Changzhou University(Natural Science Edition),2007,(02):1-3.
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一种新的C2 对称手性多齿配体的合成()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2007年02期
页码:
1-3
栏目:
出版日期:
2007-06-25

文章信息/Info

Title:
Synthesis of a Novel C2 -Symmetric Chiral Polydentate Ligand
作者:
边广岭1 姜 艳1 王云翔2 孟 启1 孙小强1
1.江苏工业学院江苏省精细石油化工重点实验室, 江苏 常州 213164 ;2.苏州科技学院化学化工系, 江苏 苏州215009
Author(s):
BIAN Guang -ling1 JIANG Yan1 WANG Yun -xiang2 MENG Qi1 SUN Xiao -qiang1
1 .Jiang su Key Laboratory of Fine Petrochemical Engineering , Jiangsu Poly technic University , Changzhou 213164 , China ;2 .Department of Chemistry , Suzhou Institute of Technology , Suzhou 215009 , China
关键词:
反-1 2 -二苯乙烯手性多齿配体C2 对称
Keywords:
trans -1 2 -stilbene chi ral poly dentate ligand C2 -symmetry
分类号:
O 625.21  
文献标志码:
A
摘要:
以反-1 , 2 -二苯乙烯、二甘醇单甲醚为原料, 经Sharpless 不对称双羟基化和Williamson 反应合成了一种新的具有C2 对称轴的手性多齿配体(R, R) -7 , 8 -二苯基-1 , 14 -二甲氧基-3 , 6 , 9 , 12 -四氧杂十四烷, 并通过质谱、核磁共振、 红外光谱等手段进行了结构表征
Abstract:
Abstract:A novel C2 -symmetric chiral polydentate ligand , (R, R) -7,8 -dipheny l -1 ,14 -dimethoxy -3 ,6,9 ,12 -tetraoxatet radecane , has been synthesized from trans -1,2 -stilbene and diethy lene -glycol -monomethyl ether by Sharpless syndihy droxylation and Williamson method .The target product was characterized by MS , NMR , FT -IR .

参考文献/References:

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[7] Dario Pini , An toaella Pet ri , Pi ero Salvadori.Het erogeneous catalyt ic asymmetric dihydroxylation of olefins :a new polymeric support and a process improvement [J] .Tet rahedron , 1994 , 50 (38):11 321 -11 328 .
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[9] 孙小强, 孟启, 何明阳, 等.光学纯1 , 2 -二苯基乙二醇的 不对称催化合成[J] .化学试剂, 1997 , 19 (3):145 -146 .

备注/Memo

备注/Memo:
基金项目:江苏省精细石油化工重点实验室开放课题(KF 0503) 作者简介:边广岭(1980 -), 男, 山东兖州人, 硕士研究生;联系人:孙小强。
更新日期/Last Update: 2007-06-25