[1]王 进,展亮亮,许 娟,等.锂离子电池负极材料SnO2-Gn-C三元复合物的制备及其电化学性能[J].常州大学学报(自然科学版),2013,(04):74-78.[doi:10.3969/j.issn.2095-0411.2013.04.016]
 WANG Jin,ZHAN Liang liang,XU Juan,et al.Preparation of SnO2-Gn-C Ternary Composite and its Electrochemical Performance as Anode Material of Lithium Ion Batteries[J].Journal of Changzhou University(Natural Science Edition),2013,(04):74-78.[doi:10.3969/j.issn.2095-0411.2013.04.016]
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锂离子电池负极材料SnO2-Gn-C三元复合物的制备及其电化学性能()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2013年04期
页码:
74-78
栏目:
材料科学与工程
出版日期:
2013-09-30

文章信息/Info

Title:
Preparation of SnO2-Gn-C Ternary Composite and its Electrochemical Performance as Anode Material of Lithium Ion Batteries
作者:
王 进1展亮亮1许 娟12陈智栋12曹剑瑜12
1.常州大学 石油化工学院,江苏 常州 213164; 2.江苏省太阳能电池与储能技术重点实验室,江苏 常州 213164
Author(s):
WANG Jin1ZHAN Liang liang1XU Juan12CHEN Zhi dong12CAO Jian yu12
1.School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China; 2.Key Laboratory for Solar Cells and Energy Storage Technology of Jiangsu Province,Changzhou 213164,China
关键词:
锂离子电池 复合物 水热法 电化学性能
Keywords:
lithium-ion batteries composite hydrothermal method electrochemical performance
分类号:
O 646
DOI:
10.3969/j.issn.2095-0411.2013.04.016
文献标志码:
A
摘要:
通过两步水热法合成了可用作锂离子电池负极材料的二氧化锡-石墨烯-炭(SnO2-Gn-C)三元复合物。采用X射线粉末衍射(XRD)、透射电镜(TEM)和电化学测试研究了SnO2-Gn-C复合物的晶型结构、形貌和电化学性能,并考察了反应温度和Sn/Gn物质的量比对复合物电化学性能的影响。实验结果显示,SnO2-Gn-C复合物在200 mA·g-1电流密度下初始放电比容量达到1 225 mA·h·g-1,50次充放电循环后比容量仍有约229 mA·h·g-1。SnO2-Gn-C良好的电化学性能主要归结于大比表面
Abstract:
SnO2-graphene-carbon(SnO2-Gn-C)ternary composite was synthesized by a two-step hydrothermal method and utilized as anodematerial in rechargeable lithium-ion batteries.The crystal structure,morphology and electrochemical performance of SnO2-Gn-C composite

参考文献/References:

[1]Brandt K.Historical development of secondary lithium batteries[J].Solid State Ionics,1994,69:173-183.
[2]王茂华,汤庆华,姚超,等.金属Ni掺杂对中间相碳微球/石墨复合材料烧结性能的影响[J].常州大学学报:自然科学版,2010,22(3):13- 16.
[3]周慧,王进,许娟,等.LiFePO4/石墨烯复合材料的电化学性能比较研究[J].常州大学学报:自然科学版,2013,25(1):76-81.
[4]Zhang B,Zheng Q B,Huang Z D,et al.SnO2-graphene-carbon nanotube mixture for anode material with improved rate capacities[J].Carbon,2011,49:4524-4534.
[5]Zhang H K,Song H H,Chen X H,et al.Preparation and electrochemical performance of SnO2@carbon nanotube core-shell structure composites as anodematerial for lithium-ion batteries[J].Electrochimica Acta,2012,59:160-167.
[6]Wang J,Zhao H L,Liu X T,et al.Electrochemical properties of SnO2/carbon composite materials as anode material for lithium-ion batteries[J].Electrochimica Acta,2011,56:6441-6447.
[7]Liu R Q,Li N,Li D Y,et al.Template-free synthesis of SnO2 hollow microspheres as anode material for lithium-ion battery[J].MaterialsLetters,2012,73:1-3.
[8]Wang F,Song X P,Yao G,et al.Carbon-coated mesoporous SnO2 nanospheres as anode material for lithium ion batteries[J].Scripta Materialia,2012,66:562-565.
[9]Liu H D,Huang J M,Li X L,et al.SnO2 nanorods grown on graphite as a high-capacity anode material for lithium ion batteries[J].CeramicsInternational,2012,38:5145-5149.
[10]Du Z J,Zhang S C,Jiang T,et al.Facile synthesis of SnO2 nanocrystalscoated conducting polymer nanowires for enhanced lithium storage[J].Journal ofPower Sources,2012,219:199-203.
[11]Li H Q,Zhou H S.Enhancing the performances of Li-ion batteries bycarbon-coating:present and future[J].Chemical Communications,2012,48(9):1201-1217.
[12]Zhang C F,Peng X,Guo Z P,et al.Carbon-coated SnO2/graphene nanosheets as highly reversible anode materials for lithium ion batteries[J].Carbon,2012,50:1897-1903.
[13]Wang G X,Shen X P,Yao J,et al.Graphene nanosheets for enhanced lithiumstorage in lithium ion batteries[J].Carbon,2009,47:2049-2053.
[14]Wang G X,Wang B,Park J,et al.Synthesis of enhanced hydrophilic and hydrophobic graphene oxide nanosheets by a solvothermal method[J].Carbon,2009,47:68-72.
[15]Wang X Y,Zhou X F,Yao K,et al.A SnO2/graphene composite as a high stability electrode for lithium ion batteries[J].Carbon,2011,49:133-139.
[16]Hummers W S,Offeman R E.Preparation of Graphitic Oxide[J].American Chemical Society,1958,80:1339.
[17]Cao J Y,Chen Z X,Xu J,et al.Mesoporous carbon synthesized from dual colloidal silica/block copolymer template approach as support of platinum nanoparticles for direct methanol fuel cells[J].Electrochimica Acta,2013,88:184-192.

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备注/Memo

备注/Memo:
基金项目:江苏省科技支撑计划基金(BE201113); 江苏省企业博士集聚计划基金(2011Z0062) 作者简介:王进(1989-),男,江苏盐城人,硕士生; 通讯联系人:曹剑瑜。
更新日期/Last Update: 2013-09-30