[1]冯晋荃,张独伊,赵 鑫,等.聚乳酸/纳米银负载二氧化硅复合材料的制备及性能[J].常州大学学报(自然科学版),2015,(01):37-40.[doi:10.3969/j.issn.2095-0411.2015.01.007 ]
 FENG Jin-quan,ZHANG Du-yi,ZHAO Xin,et al.Investigation on the Preparation and Properties of Antimicrobial Poly(lactic acid)/Nanosilver-loaded Silica Nanocomposites[J].Journal of Changzhou University(Natural Science Edition),2015,(01):37-40.[doi:10.3969/j.issn.2095-0411.2015.01.007 ]
点击复制

聚乳酸/纳米银负载二氧化硅复合材料的制备及性能()
分享到:

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2015年01期
页码:
37-40
栏目:
材料科学与工程
出版日期:
2015-01-25

文章信息/Info

Title:
Investigation on the Preparation and Properties of Antimicrobial Poly(lactic acid)/Nanosilver-loaded Silica Nanocomposites
作者:
冯晋荃1张独伊1赵 鑫 2王标兵1
1.常州大学 材料科学与工程学院,江苏 常州 213164; 2.中国环境科学研究院,北京 100012
Author(s):
FENG Jin-quan1ZHANG Du-yi1ZHAO Xin2 WANG Biao-bing1
1.School of Materials Science and Engineering,Changzhou University,Changzhou 213164,China; 2.Chinese Research Academy of Environmental Science,Beijing 100012,China
关键词:
抗菌性 聚乳酸 纳米银负载二氧化硅 形态结构 动态力学性能
Keywords:
antimicrobial properties poly(lactic acid) nanosilver-loaded silica morphology dynamical mechanical properties
分类号:
O 613.72
DOI:
10.3969/j.issn.2095-0411.2015.01.007
文献标志码:
A
摘要:
采用熔融共混的方法,在密炼机上制备了聚乳酸/纳米银负载二氧化硅(PLA/Ag-SiO2)纳米复合材料,并通过透射电镜、抑菌率和动态力学分析仪表征了复合材料的微观形态结构、抗菌性能和动态力学性能。研究结果表明,Ag-SiO2颗粒均匀地分散在在聚乳酸基体中,对金黄色葡萄球菌和大肠杆菌均体现出良好的抗菌作用,而纳米复合材料的储能模量尽管随着纳米粒子含量的增加而增加,但在纳米粒子含量低于10 000 ppm时,纳米复合材料的储能模量均低于纯聚乳酸。
Abstract:
Antimicrobial poly(lactic acid)(PLA)/nanosilver-loaded silica(Ag-SiO2)nanocomposites were prepared by melt compounding on an internal mixer. Morphology, amtimicrobial property and dynamical mechanical properties of the nanocomposites were investigated in terms of transmission electron microscope(TEM), bacteria-inhibiting rate and dynamical mechanical analysis, respectively. It showed that the Ag-SiO2 nanoparticles disperse homogeneously in the PLA matrix, and display potent antibacterial action against S. aureus and E. coli. Although the storage modulus of nanocomposites increased with the increasing Ag-SiO2 particals contents, it is lower than that of the pure PLA in the case of nanoparticles loading level below 10 000 ppm.

参考文献/References:

[1] 吴伟,陶德良,贺全国.绿色包装材料和技术的应用及展望[J].包装工程,2007,28(3): 30-41.
[2]陈 烨,纪俊,李海乐,等.3-( 三甲氧基硅烷基)丙基二甲基十二烷基氯化铵的合成及其抗菌性能[J].常州大学学报(自然科学版),2010,22(2):10-14.
[3]费燕娜,傅佳佳,万玉芹,等.聚乳酸/茶多酚复合纳米纤维膜抗菌机理[J].材料科学与工程学报,2013,31(2):181-186.
[4]向红亮,郭培培.载银抗菌金属材料研究概况[J].金属世界,2012(1): 21-26.
[5] Huda M S, Drzal L T, Misra M. A study on biocomposites from recycled newspaper fiber and poly(lactic acid)[J].Ind Eng Chem Res, 2005, 44(15): 5593-5601.
[6] Wang B,Sun X S,Kenneth K.Poly(lactic acid)/multi-hydroxyl magnesium oxide nanocomposites prepared by melt compounding[J].J Biobased Mater Bioenergy,2009(3): 130-138.
[7] Brostrom J,Boss A,Chronakis I S.Biodegradable films of partly branched poly(L-lactide)-co-poly(E-caprolactone)copolymer:modulation of phase morphology, plasticization properties and thermal depolymerization[J].Biomacromolecules,2004,5(3):1124-1134.
[8] Pothan L A,Oommen Z,Thomas S.Dynamic mechanical analysis of banana fiber reinforced polyester composites[J].Compos Sci Technol,2003,63(2):283-293.
[9] Liu X,Dever M,Fair N,et al.Thermal and mechanical properties of poly(lactic acid)and poly(ethylene/butylene succinate)blends[J]. J Environ Polym Degrad,1997(5):225-235.
[10] Bleach N C,Nazhat S N,Tanner K E,et al.Effect of filler content on mechanical and dynamic mechanical properties of particulate biphasic calcium phosphatepolylactide composites[J].Biomaterials,2002,23(7):1579- 1585.

备注/Memo

备注/Memo:
作者简介:冯晋荃(1991-),女,安徽黄山人,硕士生。通讯联系人:王标兵(1971-),E-mail:biaobing@cczu.edu.cn
更新日期/Last Update: 2015-01-25