[1]杨海涛,刘锐,缪春宝.芳基亚甲叉氰乙酸酯的环氧化反应研究[J].常州大学学报(自然科学版),2016,(04):21-24,58.[doi:10.3969/j.issn.2095-0411.2016.04.004]
 YANG Haitao,LIU Rui,MIAO Chunbao.Investigation on the Epoxidation of Arylidenecyanoacetate[J].Journal of Changzhou University(Natural Science Edition),2016,(04):21-24,58.[doi:10.3969/j.issn.2095-0411.2016.04.004]
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芳基亚甲叉氰乙酸酯的环氧化反应研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2016年04期
页码:
21-24,58
栏目:
化学化工
出版日期:
2016-07-30

文章信息/Info

Title:
Investigation on the Epoxidation of Arylidenecyanoacetate
作者:
杨海涛刘锐缪春宝
常州大学 石油化工学院,江苏 常州 213164
Author(s):
YANG Haitao LIU Rui MIAO Chunbao
School of Petroleum Engineering, Changzhou University, Changzhou 213164, China
关键词:
芳基亚甲叉氰乙酸酯 环氧化 过氧化氢 碳酸钠
Keywords:
arylidenecyanoacetate epoxidation hydrogen peroxide sodium carbonate
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2016.04.004
文献标志码:
A
摘要:
以双氧水作为氧化剂、弱碱碳酸钠作催化剂在室温下实现了芳基亚甲叉氰乙酸酯的环氧化反应。该方法绿色对环境友好、产率高、副产物仅仅是水。所得环氧产物的结构经1H NMR,13C NMR和MS表征。
Abstract:
The epoxidation of arylidenecyanoacetate has been realized by using the hydrogen peroxide as the oxidant in the presence of catalytic amount of sodium carbonate as a weak base at room temperature. This environmental-friendly method has a high yield and only water was generated as the byproduct. The structures of the generated epoxides were fully characterized by their 1H NMR, 13C NMR and MS spectra.

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备注/Memo

备注/Memo:
收稿日期:2016-01-07。基金项目:江苏省自然科学基金资助(BK20141171)。作者简介:杨海涛(1979—),男,安徽肥西人,博士,副教授。常州大学 石油化工学院,江苏 常州 213164
更新日期/Last Update: 2016-08-30