[1]陈晔,马丹,王悦,等.介孔石墨相氮化碳催化CO2环加成合成碳酸丙烯酯[J].常州大学学报(自然科学版),2017,(03):18-24.[doi:10.3969/j.issn.2095-0411.2017.03.004]
　CHEN Ye,MA Dan,WANG Yue,et al.Propylene Carbonate from the Cycloaddition of CO2 Catalyzed by Mesoporous Graphitic Carbon Nitride[J].Journal of Changzhou University(Natural Science Edition),2017,(03):18-24.[doi:10.3969/j.issn.2095-0411.2017.03.004]
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介孔石墨相氮化碳催化CO2环加成合成碳酸丙烯酯()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2017年03期
页码:
18-24
栏目:
化学化工
出版日期:
2017-05-28

文章信息/Info

Title:
Propylene Carbonate from the Cycloaddition of CO2 Catalyzed by Mesoporous Graphitic Carbon Nitride
作者:
陈晔; 马丹; 王悦; 许杰; 李永昕
常州大学 石油化工学院,江苏 常州 213164
Author(s):
CHEN Ye;  MA Dan; WANG Yue;  XU Jie;  LI Yongxin
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
关键词:
石墨相氮化碳;  CO2转化;  环加成反应
Keywords:
g-C3N4;  CO2 conversion;  cycloaddition reaction
分类号:
O 643
DOI:
10.3969/j.issn.2095-0411.2017.03.004
文献标志码:
A
摘要:
以盐酸胍为前驱体,纳米氧化硅小球为模板剂,通过调节纳米氧化硅小球与盐酸胍的质量比,合成了一系列比表面(146～194 m2·g-1)和孔体积(0.57～0.75 cm3·g-1)可调的介孔石墨相氮化碳(mp-C3N4)。通过N2吸-脱附、透射电镜、X射线衍射、傅里叶红外光谱、X射线光电子能谱等手段对材料的孔结构、微观形貌和化学组成等理化性质进行表征。在CO2环加成反应合成碳酸丙烯酯的催化反应中,mp-C3N4材料表现出良好的催化性能。在反应温度120 ℃条件下,碳酸丙烯酯的选择性和收率分别高达98%和76%。根据理化表征提出了一种可能的催化机理。
Abstract:
A series of mesoporous g-C3N4 materials(mp-C3N4)with tunable surface areas(146-194 m2·g-1)and pore volumes(0.57-0.75 cm3·g-1)have been synthesized using guanidinium chloride as a precursor, and colloid silica nanoparticles as hard templates through a nanocasting method. The physicochemical properties of mp-C3N4 materials(including porosity, micrograph, and chemical compositions)were characterized by N2 adsorption-desorption, XRD, TEM, FT-IR, and XPS spectroscopy. In the cycloaddition reactions of CO2 with propylene oxide to propylene carbonate(PC), the mp-C3N4 materials showed high catalytic performances. The maximum selectivity and yield of PC were up to 98% and 76%, respectively at 120 ℃. On the basis of the characterization results, a possible catalytic mechanism has been proposed.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期:2016-08-23。
基金项目:国家自然科学基金资助项目(21203014); 江苏省先进催化与绿色制造协同创新中心资助项目(ACGM2016-06-28)。
作者简介:陈晔(1992—),女,安徽淮南人,硕士生。通讯联系人:许杰(1982-),E-mail:shine6832@163.com
更新日期/Last Update: 2017-06-05