[1]张后甫,郝晓琼,银凤翔,等.Ni/de-ZSM催化剂的制备及其氨分解制氢性能[J].常州大学学报(自然科学版),2022,34(02):8-18.[doi:10.3969/j.issn.2095-0411.2022.02.002]
　ZHANG Houfu,HAO Xiaoqiong,YIN Fengxiang,et al.Preparation of Ni/de-ZSM Catalyst and Its Performance in Hydrogen Production by Ammonia Decomposition[J].Journal of Changzhou University(Natural Science Edition),2022,34(02):8-18.[doi:10.3969/j.issn.2095-0411.2022.02.002]
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Ni/de-ZSM催化剂的制备及其氨分解制氢性能()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第34卷
期数:
2022年02期
页码:
8-18
栏目:
化学化工
出版日期:
2022-03-28

文章信息/Info

Title:
Preparation of Ni/de-ZSM Catalyst and Its Performance in Hydrogen Production by Ammonia Decomposition
文章编号:
2095-0411(2022)02-0008-11
作者:
张后甫; 郝晓琼; 银凤翔; 李国儒; 何小波
(常州大学石油化工学院,江苏常州213164;江苏省绿色催化材料与技术重点实验室(常州大学),江苏常州213164)
Author(s):
ZHANG Houfu;  HAO Xiaoqiong;  YIN Fengxiang;  LI Guoru;  HE Xiaobo
(School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China; Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China)
关键词:
镍;  氨分解;  ZSM-5分子筛;  制氢;  催化剂
Keywords:
Ni;  ammonia decomposition;  ZSM-5 zeolite;  hydrogen production;  catalyst
分类号:
TK 8
DOI:
10.3969/j.issn.2095-0411.2022.02.002
文献标志码:
A
摘要:
通过浸渍法制备了一系列Ni/de-ZSM催化剂,对合成的催化剂进行了XRD,TEM,H2-TPR,XPS,BET表征和氨分解制氢性能评价。结果表明当Ni的质量分数达到5%时,5%Ni/de-ZSM中Ni纳米颗粒高度分散且催化活性最佳。在650 ℃,空速为30 000 mL/(h·g)时,氨分解转化率高达90%,氢气生成速率达28.41 mmol/(min·g),且催化稳定性良好,可高效催化氨分解长达40 h。
Abstract:
A series of Ni/de-ZSM(the de-aluminized ZSM is named as de-ZSM)catalysts were prepared by impregnation method, the catalysts were characterized by XRD, TEM, H2-TPR, XPS, BET, and their performance of ammonia decomposition to produce hydrogen has also been investigated. The results show that when the loading amount of Ni reaches 5%, Ni nanoparticles in the 5%Ni/de-ZSM catalyst are highly dispersed and the catalytic activity is the best. When temperature rises to 650 ℃ and the space velocity is 30 000 mL/(h·g), the conversion rate of ammonia decomposition is as high as 90%, the hydrogen generation rate reaches 28.41 mmol/(min·g). The catalyst also shows excellent catalytic stability, which can effectively catalyze the ammonia decomposition up to 40 h.

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(责任编辑:谭晓荷)

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备注/Memo

备注/Memo:
收稿日期: 2021-10-27。
基金项目: 国家自然科学基金资助项目(22078027)。
作者简介: 张后甫(1997—), 男, 安徽宿州人, 硕士生。通信联系人: 银凤翔(1975—), E-mail: yinfx@cczu.edu.cn
更新日期/Last Update: 1900-01-01