[1]张秋亚,徐凯琳,许筠,等.g-C3N4可见光-臭氧催化氧化降解二苯甲酮-4[J].常州大学学报(自然科学版),2022,34(03):54-63.[doi:10.3969/j.issn.2095-0411.2022.03.008]
　ZHANG Qiuya,XU Kailin,XU Jun,et al.Visible-Light-Driven Photocatalytic Ozonation for Degradation of Organic Sunscreen BP-4[J].Journal of Changzhou University(Natural Science Edition),2022,34(03):54-63.[doi:10.3969/j.issn.2095-0411.2022.03.008]
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g-C3N4可见光-臭氧催化氧化降解二苯甲酮-4()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第34卷
期数:
2022年03期
页码:
54-63
栏目:
环境科学与工程
出版日期:
2022-05-28

文章信息/Info

Title:
Visible-Light-Driven Photocatalytic Ozonation for Degradation of Organic Sunscreen BP-4
文章编号:
2095-0411(2022)03-0054-10
作者:
张秋亚; 徐凯琳; 许筠; 王利平; 卜一鸣
(常州大学环境与安全工程学院,江苏常州213164)
Author(s):
ZHANG Qiuya;  XU Kailin;  XU Jun;  WANG Liping;  BO Yiming
(School of Environmental & Safety Engineering, Changzhou University, Changzhou 213164, China)
关键词:
二苯甲酮(BP-4);  光催化;  臭氧氧化;  去除率;  风险评价
Keywords:
benzophenone(BP-4);  photocatalysis;  ozone oxidation;  removal rate;  risk assessment
分类号:
X 703
DOI:
10.3969/j.issn.2095-0411.2022.03.008
文献标志码:
A
摘要:
二苯甲酮-4(Benzophenone-4, BP-4)是常用的有机防晒剂,广泛存在于环境介质,对人体健康和生态安全产生严重威胁。分别考察单一g-C3N4光催化和臭氧氧化降解BP-4的最佳反应条件,探明光催化臭氧氧化耦合工艺对BP-4的去除效能,并对降解溶液生态风险进行评估。结果表明,单一g-C3N4光催化和单一臭氧氧化技术对BP-4去除率分别为53.3%和32.4%; 光催化臭氧氧化耦合技术对BP-4降解具有协同作用,去除率达79.6%,且符合准一级反应动力学。BP-4降解溶液的发光菌抑制率增强,具有潜在生态风险。
Abstract:
Benzophenone-4(BP-4), a commonly used organic sunscreen, is widely found in environmental media and poses a serious threat to human health and ecological safety. In this study, the optimal reaction conditions for degradation of BP-4 by single g-C3N4 photocatalysis and ozone oxidation were specified respectively, and the removal efficiency of BP-4 by photocatalysis and ozone oxidation coupled process was investigated, and especially, the ecological risk of degradation solution was evaluated. The results showed that the removal of BP-4 by single g-C3N4 photocatalysis and single ozonation were 53.3% and 32.4%, respectively. Photocatalytic ozonation coupling had a synergistic effect on the degradation of BP-4, and the removal was up to 79.6%, which was consistent with the pseudo-first order reaction kinetics. The inhibition rate of bioluminescent bacteria in BP-4 degradation solution was enhanced, which had potential ecological risk.

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备注/Memo

备注/Memo:
收稿日期: 2022-02-14。
基金项目: 常州大学自然科学基金资助项目(ZMF19020388)。
作者简介: 张秋亚(1988—), 女, 河南周口人, 博士, 讲师。 E-mail: qiuya@cczu.edu.cn
更新日期/Last Update: 1900-01-01