[1]何小波,丁露,银凤翔,等.高熵合金在电催化氧还原反应中的应用及发展[J].常州大学学报(自然科学版),2024,36(01):27-38.[doi:10.3969/j.issn.2095-0411.2024.01.004]
　HE Xiaobo,DING Lu,YIN Fengxiang,et al.Applications and developments of high-entropy alloys toward electrocatalytic oxygen reduction reaction[J].Journal of Changzhou University(Natural Science Edition),2024,36(01):27-38.[doi:10.3969/j.issn.2095-0411.2024.01.004]
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高熵合金在电催化氧还原反应中的应用及发展()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第36卷
期数:
2024年01期
页码:
27-38
栏目:
化学化工
出版日期:
2024-01-28

文章信息/Info

Title:
Applications and developments of high-entropy alloys toward electrocatalytic oxygen reduction reaction
文章编号:
2095-0411(2024)01-0027-12
作者:
何小波1; 2; 丁露2; 银凤翔1; 2; 李国儒1; 2
1.江苏省绿色催化材料与技术重点实验室常州大学, 江苏 常州 213164; 2.常州大学 石油化工学院, 江苏 常州 213164
Author(s):
HE Xiaobo1; 2;  DING Lu2;  YIN Fengxiang1; 2;  LI Guoru1; 2
1.Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology,Changzhou University,Changzhou 213164,China; 2.School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
关键词:
催化剂;  电催化;  高熵合金;  氧还原反应
Keywords:
catalyst;  electrocatalysis;  high-entropy alloy;  oxygen reduction reaction
分类号:
TQ 15
DOI:
10.3969/j.issn.2095-0411.2024.01.004
文献标志码:
A
摘要:
开发用于氧气还原反应(ORR)的高效催化剂是提高燃料电池和金属-空气电池性能的关键。然而,ORR是动力学缓慢反应,存在着很高的过电势,从而降低了燃料电池和金属-空气电池的能量转换效率。高熵合金是由5种或5种以上金属元素等(近)物质的量比形成的一种新型合金材料。凭借其独特的组分与结构优势,高熵合金能够高效加速ORR、降低ORR过电势,表现出对ORR的显著催化作用。文章主要综述了高熵合金的结构、性能特点、制备方法以及在催化ORR方面的应用,并提出了挑战和发展展望。
Abstract:
The development of highly efficient catalysts for oxygen reduction reaction(ORR)is the key to improve the performance of fuel cells and metal-air batteries. However, ORR is a kinetic slow reaction with high overpotential, which limits the energy conversion efficiency of fuel cells and metal-air batteries. High-entropy alloy is a new kind of alloy, which is consisted of five or more metal elements with(nearly)equimolar ratios. With unique composition and structural advantages, high-entropy alloy can effectively accelerate ORR kinetics and lower overpotential, showing remarkable catalytic performance toward ORR. In this paper, the structures, properties, preparation methods and applications of high entropy alloys in catalytic ORR were reviewed, and the challenges and development perspectives were proposed.

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备注/Memo

备注/Memo:
收稿日期: 2023-03-29。
基金项目: 国家自然科学基金资助项目(22078027); 常州市科技计划应用基础研究计划资助项目(CJ20220253)。
作者简介: 何小波(1983—), 男, 江苏常州人, 博士, 副研究员。 通信联系人: 银凤翔(1975—), E-mail: yinfx@cczu.edu.cn
更新日期/Last Update: 1900-01-01