[1]杨森,胡浩,陈铭.可见光诱导6H-苯并[c]苯并吡喃及二氢菲啶衍生物的合成[J].常州大学学报(自然科学版),2024,36(04):1-7.[doi:10.3969/j.issn.2095-0411.2024.04.001]
 YANG Sen,HU Hao,CHEN Ming.Visible-light-induced synthesis of 6H-benzo[c]chromene and dihydrophenanthridine derivatives[J].Journal of Changzhou University(Natural Science Edition),2024,36(04):1-7.[doi:10.3969/j.issn.2095-0411.2024.04.001]
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可见光诱导6H-苯并[c]苯并吡喃及二氢菲啶衍生物的合成()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第36卷
期数:
2024年04期
页码:
1-7
栏目:
化学化工:有机合成专题
出版日期:
2024-07-28

文章信息/Info

Title:
Visible-light-induced synthesis of 6H-benzo[c]chromene and dihydrophenanthridine derivatives
文章编号:
2095-0411(2024)04-0001-07
作者:
杨森胡浩陈铭
(常州大学 石油化工学院, 江苏 常州 213164)
Author(s):
YANG Sen HU Hao CHEN Ming
(School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China)
关键词:
可见光诱导 C—H芳基化 6H-苯并[c]苯并吡喃 二氢菲啶 杂环化合物
Keywords:
visible-light-induced C—H arylation 6H-benzo[c]chromene dihydrophenanthridine heterocyclic compounds
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2024.04.001
文献标志码:
A
摘要:
开发出了可见光诱导的分子内C—H芳基化反应,合成了一系列6H-苯并[c]苯并吡喃及二氢菲啶衍生物。合成得到的产物用1H NMR以及13C NMR进行结构表征。与传统方法相比,该方法利用清洁可再生的光能驱动化学反应,避免了高温、高压等严格的反应条件。此外,该方法具有原料易得、底物适用范围广泛、反应条件温和、操作简单等优点。
Abstract:
An intramolecular C—H arylation reaction was established for the construction of a series of 6H-benzo[c]chromene and dihydrophenanthridine derivatives under visible light irradiation. The products were characterized by 1H NMR and 13C NMR spectra. Compared with traditional methods, this method uses clean and renewable light energy to drive reactions, avoiding strict reaction conditions such as high temperature and high pressure. In addition, this method has the advantages of easily available starting materials, broad substrate scopes, mild reaction conditions and simple operation.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期: 2023-12-11。
基金项目: 国家自然科学基金青年科学基金项目(22101034); 江苏省高等学校基础科学(自然科学)研究资助项目(21KJD150002); 江苏省绿色催化材料与技术实验室开放课题基金资助项目(BM2012110)。
作者简介: 杨森(1992—), 男, 河南信阳人, 博士, 讲师。 通信联系人: 陈铭(1988—), E-mail: chenming0228@cczu.edu.cn
更新日期/Last Update: 1900-01-01