[1]徐淑玲,马江权,郭 楠,等.渗透汽化从重石脑油中脱除微量水[J].常州大学学报(自然科学版),2009,(04):42-45.
 XU Shu -ling,MA Jiang -quan,GUO N an,et al.Study of Pervaporation Separation of Heavy Naphtha in the Removal of Micro Water[J].Journal of Changzhou University(Natural Science Edition),2009,(04):42-45.
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渗透汽化从重石脑油中脱除微量水()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2009年04期
页码:
42-45
栏目:
出版日期:
2009-12-25

文章信息/Info

Title:
Study of Pervaporation Separation of Heavy Naphtha in the Removal of Micro Water
作者:
徐淑玲 马江权 郭 楠 侯永涛 许守勇
江苏工业学院江苏省精细石油化工重点实验室, 江苏 常州 213164
Author(s):
XU Shu -ling MA Jiang -quan GUO N an HO U Yong -tao XU Shou -y ong
Jiang su Key Labo rato ry o f Fine Pet rochemical Engineering , Jiangsu Poly technic Unive rsity , Chang zhou 213164 , China
关键词:
渗透汽化脱水渗透通量重石脑油
Keywords:
pervaporation dehydratio n permeation f lux heavy naphtha
分类号:
TQ 028  
文献标志码:
A
摘要:
重石脑油作为芳烃重整装置的原料, 要求油品中水分含量低于20 μg/ g , 以保证脱硫剂的使用寿命, 进一步避免装置催 化剂铂的中毒。建立了年处理量为8 000 kg 的渗透汽化装置对重石脑油的深度脱水进行研究, 通过考察操作温度θ、进料质量 分数ρw 、操作流量qv 和透过侧压力p 来确定合适的工艺条件。实验表明80 ℃、500 L/ h 、1.5 kPa 下采用恒温加热的方式, 达 到了渗透通量J w =0.34 g/ (m2 · h) 的最好分离效果。通过数据拟合确定了J w 和ρw 、θ、p 关系的经验公式, 并且推出了J w 计算的总公式, 实验结果为106 kg 级渗透汽化重石脑油脱水的中试设计提供了基础数据。
Abstract:
Heavy naphtha is the raw material o f the aromatic gy drocarbon Refining Device , w hile the w ater co ntent in heavy naphtha requi red to be less than 20 μg/g , in order to guarantee the life span o f desulfurizatio n agent , to avoid further poisoning the platinum cataly st .Pervapo ratio n separation of heavy naphtha in the remov al of micro w ater w as conducted by the establishment o f the 8 -ton small pilo t plant .The ef fect s o f operat ion temperature (θ), w ater consistence (ρw ), feed f low rate (qv), and pressure (p)on the dehydratio n proper ties w ere investigated .The ex perimental resul ts indicated that the membrane had J w of 0.34 g/ (m2 /h), at 80 ℃, 500 L/h of flow rate , 1.5 kPa pressure o f dow nst ream and the co nstant temperature o f the heating mode for dehydratio n o f heav y naphtha system , w hich is the best separation ef fect .Fi tt ing data to determine the empirical fo rmula of J w with θ, ρw , p , the paper introduced the calculation of the total fo rmula J w .The result s provide the basic data for the further design of the kiloton pervaporation dehydration naphtha

参考文献/References:

[1] Els ayed A , Fouad , Xiansh e Feng .Use of pervaporat ion t o separat e b ut an ol f rom di lut e aqueou s soluti ons :Ef fect s of operat ing condit ions and concent ration polarizati on [J] .Journal of Membrane Sci ence, 2008 , 323 :428 -435 .
[2] 曾盔, 李继定, 陈翠仙.改性复合膜对微水异丙醇的的渗透汽 化脱水[J] .化学工程, 2006 , 34 (5):37 -40 .
[3] Sw ayampaku la Kalyani , Bidu ru Smi tha , S underg opal S ridhar , et al.Pervaporati on separat ion of ethanol - w at er mi xtu res through sodium alginat e memb ranes [J] .Desalination , 2008 , 229 :68 -81 .
[4] 王金厢, 蔡邦肖.渗透汽化在酯水体系分离中的应用[J] . 化工进展, 2006 , 25 (6):608 -612 .
[5] Garcia Vi llaluenga J P , Tabe -M oham madi A .A review on the separat ion of b enzene/ cycloh exane mi xtures by pervaporati on processes [J] .Journal of Mem brane Science , 1999 , 169 (2 000):159 -174 .
[6] Kh ayet M , Cojocaru C , Zak rzew s ka -T rz nadel G .Response su rf ace modelling and opt imiz at ion in pervaporati on [J] .Jou rnal of M emb rane S cience , 2008 , 321 :272 -283 .
[7] 彭勇, 陈翠仙, 李继定.渗透汽化苯脱水的实验室和工业试验 研究(1) 实验室放大试验[J] . 膜科学与技术, 2000 , 20 (6):1 -7 .

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备注/Memo

备注/Memo:
基金项目:中国石油化工扬子石油化工股份有限公司资助项目(07GKJ026);欧盟国际合作项目资助(EC Project BD Asia Pro Eco/ 07/ 96638) 作者简介:徐淑玲(1970 -), 女, 山东汶上人, 硕士, 助理研究员。
更新日期/Last Update: 2009-12-25