[1]赖梨芳,陈林提,程美令,等.基于3,4-吡唑二甲酸的锌配合物的合成、晶体结构和荧光性质[J].常州大学学报(自然科学版),2017,(05):16-21.[doi:10.3969/j.issn.2095-0411.2017.05.003]
　LAI Lifang,CHEN Linti,CHENG Meiling,et al.Synthesis, Crystal Structure and Luminescent Property of Zinc Complex Based on 3,4-Pyrazoledicarboxylic Acid Ligand[J].Journal of Changzhou University(Natural Science Edition),2017,(05):16-21.[doi:10.3969/j.issn.2095-0411.2017.05.003]
点击复制

基于3,4-吡唑二甲酸的锌配合物的合成、晶体结构和荧光性质()
分享到：

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2017年05期
页码:
16-21
栏目:
化学化工
出版日期:
2017-09-30

文章信息/Info

Title:
Synthesis, Crystal Structure and Luminescent Property of Zinc Complex Based on 3,4-Pyrazoledicarboxylic Acid Ligand
作者:
赖梨芳; 陈林提; 程美令; 戎红仁; 王先梅; 刘琦
常州大学 石油化工学院,江苏 常州 213164
Author(s):
LAI Lifang;  CHEN Linti;  CHENG Meiling;  RONG Hongren;  WANG Xianmei;  LIU Qi
School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China
关键词:
Zn(II);  3; 4-吡唑二甲酸;  晶体结构;  荧光
Keywords:
Zinc(II);  3; 4-pyrazoledicarboxylic acid;  crystal structure;  luminescence
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2017.05.003
文献标志码:
A
摘要:
利用3,4-吡唑二甲酸与硝酸锌作用合成了一种新的配合物[Zn(H2pdc)2(H2O)2]·2DMF,并采用红外光谱、元素分析和单晶-X衍射结构分析等手段对其进行了表征。晶体结构表明[Zn(H2pdc)2(H2O)2]·2DMF属于三斜晶系Pī空间群,该配合物中的锌离子位于八面体的配位环境中,[Zn(H2pdc)2(H2O)2](独立单元)和DMF间通过氢键的作用而形成一个二维的超分子结构,考察了该配合物的热稳定性和荧光性能。
Abstract:
A new metal complex[Zn(H2pdc)2(H2O)2]·2DMF(H3pdc=3,4-pyrazoledicarboxylic acid)has been synthesized by the reaction of H3pdc and Zn(NO3)2, and characterized by elemental analysis, IR spectra, and single-crystal X-ray diffraction. Structure analysis reveals that complex[Zn(H2pdc)2(H2O)2]·2DMF has mononuclear structure, each Zn(II)ion is located in an octahedron geometry,and independent units[Zn(H2pdc)2(H2O)2]and DMF are linked by intermolecularhydrogen bonds to form a 2D supramolecular network. The thermal stability and luminescent property of the complex in the solid state have also been investigated.

参考文献/References:

[1] O'KEEFFE M, YAGHI O M.Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J].Chem Rev, 2012, 112(2): 675-702.
[2]ROSI N L, ECKERTT J, EDDAOUDI M, et al. Hydrogen storage in microporous metal-organic frameworks[J]. Science,2003, 300(5622): 1127-1129.
[3]CHOI H J, DINC M, LONG J R, et al. Broadly hysteretic H2adsorption in the microporous metal-organic framework Co(1,4-benzenedipyrazolate)[J].J Am Chem Soc,2008, 130(25): 7848-7850.
[4]OHARA K, KAWANO M, INOKUMA Y, et al.A porous coordination network catalyzes an olefin isomerization reaction in the pore[J]. J Am Chem Soc,2010,132(1): 30-31.
[5]YOON M, SRIRAMBALAJI R, KIM K, et al. Homochiralmmetal-organic frameworks for asymmetric heterogeneous catalysis[J]. Chem Rev,2012,112(2):1196-1231.
[6]FURUKAWA H, CORDOVA K E, O'KEEFFE M, et al. The chemistry and applications of metal-organic frameworks[J]. Science,2013, 341(6149): 1230444.
[7]FÉREY G, MILLANGE F, MORCRETTE M, et al. Mixed-valence Li/Fe-based metal-organic frameworks with both reversible redox and sorption properties[J].Angew Chem Int Ed,2007, 46(18): 3259-3263.
[8]LIU Q, YU L L, WANG Y, et al.Manganese based layered coordination polymer: synthesis, structural characterization, magnetic property and electrochemical performance in lithium ion batteries[J].Inorg Chem,2013, 52(6):2817-2822.
[9]NAGARATHINAM M, SARAVANAN K, PHUA E J H, et al. Redox-active metal-centered oxalatophosphate open framework cathode materials for lithium ion batteries[J].Angew Chem,2012, 124(24):5968-5972.
[10]SHI C, XIA Q, XUE X, et al. Synthesis of cobalt-based layered coordination polymer nanosheets and their application in lithium-ion batteries as anode materials[J]. RSC Ad,2016, 6(6): 4442-4447.
[11]LIU X, SHI C, ZHAI C, et al.A cobalt-based layered metal-organic framework as an ultrahigh capacity supercapacitor electrode material[J].ACS Appl Mater Interfaces, 2016, 8(7): 4585-4591.
[12]LIU Q, LIU X, SHI C, et al. A copper-based layered coordination polymer: synthesis, magnetic properties and electrochemical performance in supercapacitors[J].Dalton Trans, 2015, 44(44):19175-19184.
[13]KRENO L E, LEONG K, FARHA O K, et al.Metal-organic framework materials as chemical sensors[J]. Chem Rev,2012,112(2):1105-1125.
[14]YANG P, WANG M S, SHEN J J, et al.Seven novel coordination polymers constructed by rigid 4-(4-carboxyphenyl)-terpyridine ligands: synthesis, structural diversity, luminescence and magnetic properties[J]. Dalton Trans, 2014, 43(3): 1460-1470.
[15]WANG H Y,WU Y,LEONG C F,et al.Crystal structures, magnetic properties, and electrochemical properties of coordination polymers based on the tetra(4-pyridyl)-tetrathiafulvaleneligand[J].Inorg Chem,2015, 54(22): 10766-10775.
[16]ZHOU X H, DU X D, LI G N, et al.Coordination polymers assembled from 3,5-pyrazoledicarboxylic acid and bis(triazolyl)ligands: chiral and meso-structures Induced by ligand flexibility and a six-connected self-catenatednetwork[J]. Cryst Growth Des,2009, 9, 4487-4496.
[17]ZHOU X H, PENG Y H, DU X D, et al.New 3d-4f Heterometalliccoordination polymers based on pyrazole-bridged CuIILnIIIdinuclearunits and sulfate anions: syntheses, structures, and magnetic properties[J]. Cryst Growth Des, 2009, 9:1028-1035.
[18]LIU J, CHENG M L, YU L L, et al. Three metal complexes derived from 3-methyl-1Hpyrazole-4-carboxylic acid: synthesis, crystal structures, luminescence and electrocatalytic properties[J].RSC Adv, 2016, 6(57): 52040-52047.
[19]CHEN L, TAO F, WANG L, et al. Two metal complexes based on 3,4-pyrazoledicarboxylic acid ligand: synthesis, structures and luminescent properties[J].Z Anor Allg Chem, 2013, 639: 552-557.
[20]TAO F, CHEN L, CHENG M L,et al. Synthesis, crystalstructures and luminescent properties of two transition metal complexes based on 3,4-pyrazoledicarboxylic acid[J]. Chinese J Inorg Chem, 2014, 30(9): 2105-2110.
[21]WANG L, TAO F, CHENG M L, et al. Syntheses, crystal structures, and luminescence of two main-group metal complexes based on 3,4-pyrazoledicarboxylic acid[J]. J Coord Chem, 2012, 65(6): 923-933.
[22]JONESR G. The synthesis of ethyl ethoxymethyleneoxalacetate and related compounds[J].J Am Chem Soc,1951, 73(8):3684-3686.
[23]SHELDRICK G M.Metal-organic compounds[J]. Acta Cryst, 2008,A64: 112-122.
[24]LIU X, CHENG M L, REN Y, et al. Two zinc complexes based on 1-carboxymethyl-3,5-dimethyl-1H-pyrazole-4-carboxylicacid: syntheses, structures, and lu minescent properties[J]. Chinese J Inorg Chem, 2015, 31(3): 611-618.

相似文献/References:

[1]陶永新,等.侧链含2, 5- 二苯基- 1, 3, 4- 噻二唑聚乙烯的 制备及其性能[J].常州大学学报(自然科学版),2009,(04):16.
　TAO Yong- x in,YANG Xue- bo,et al.Study of Synthesis and Properties of Polystyrene Containing 2, 5- Diphenyl- 1, 3, 4- Thiadiazole in Side Chain[J].Journal of Changzhou University(Natural Science Edition),2009,(05):16.
[2]陈?? 勇,周国平,梁?? 俊,等.PT C 法合成杂环羧酸类1- O- 芳酰基- 2, 3, 4, 6- 四- O- 乙酰基- ?β- D- 吡喃己糖化合物的研究[J].常州大学学报(自然科学版),2007,(01):9.
　CHEN Yong,ZHOU Guo- ping,LIANG Jun,et al.Study of Synthesis of 1- O- Aroyl- 2, 3, 4, 6- tetra- O- acetyl- β?- D- glucopyranoses of Heterocyclic Carboxylic Acids by PTCMethod[J].Journal of Changzhou University(Natural Science Edition),2007,(05):9.

备注/Memo

备注/Memo:
收稿日期:2016-11-10。 基金项目:国家自然科学基金资助项目(20971060, 21101018 ); 江苏省高校自然科学研究重大项目(16KJA430005); 江苏省先进催化与绿色制造协同创新中心创新型人才支持项目(ACGM2016-06-10)。 作者简介:赖梨芳(1969—),女,江西广丰人,硕士,讲师,主要从事功能材料研究。通讯联系人:刘琦(1962—),E-mail: liuqi@cczu.edu.cn
更新日期/Last Update: 2017-10-20