[1]田 俐,王会锋,李 岩,等.PPy@In-BDC复合材料的制备与表征[J].常州大学学报(自然科学版),2018,30(03):28-33.[doi:10.3969/j.issn.2095-0411.2018.03.003]
　TIAN Li,WANG Huifeng,LI Yan,et al.Preparation and Characterization of the PPy@In-BDC Composite Material[J].Journal of Changzhou University(Natural Science Edition),2018,30(03):28-33.[doi:10.3969/j.issn.2095-0411.2018.03.003]
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PPy@In-BDC复合材料的制备与表征()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第30卷
期数:
2018年03期
页码:
28-33
栏目:
材料科学与工程
出版日期:
2018-05-28

文章信息/Info

Title:
Preparation and Characterization of the PPy@In-BDC Composite Material
作者:
田 俐1; 王会锋2; 李 岩2; 陈善民1; 刘 强1; 罗 奇1; 郭 珍1; 邬发发1; 李英杰1; 林彬彬1
1. 湖南科技大学 材料科学与工程学院,湖南 湘潭 411201; 2. 湖南科技大学 化学化工学院,湖南 湘潭 411201
Author(s):
TIAN Li1;  WANG Huifeng2;  LI Yan2;  CHEN Shanmin1;  LIU Qiang1;  LUO Qi1;  GUO Zhen1;  WU Fafa1;  LI Yingjie1;  LIN Binbin1
1. School of Materials Science and Engineering, Hunan University of Science and Technology, Xiangtan 411201, China; 2. School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan 411201, China
关键词:
聚吡咯;  In-BDC;  复合材料;  电导率
Keywords:
polypyrrole;  In-BDC;  composite material;  conductivity
分类号:
TB 33
DOI:
10.3969/j.issn.2095-0411.2018.03.003
文献标志码:
A
摘要:
通过碘氧化法,在金属有机框架材料In-BDC(BDC2- 为对苯二甲酸酸酐)的一维孔道内实现吡咯的化学氧化聚合,得到了PPy@In-BDC复合材料。利用X射线粉末衍射、扫面电子显微镜、热失重、红外光谱、N2吸附以及四探针法表征了制备过程中所得材料的结构、组成及性能。压片成型后,PPy@In-BDC复合材料的电导率达10-5S/cm,和无模板法合成的块状聚吡咯(～10-8S/cm)及模板In-BDC相比,至少有3个数量级的提高。
Abstract:
In the 1D channels of the In-BDC, polypyrrole could be synthesised by iodine oxidation, and then the PPy@In-BDC composite material was achieved. The structure, composition and properties of the obtained materials were characterized by PXRD, SEM, TG, IR, N2 adsorption and four-probe method. The electronic conductivity of PPy@In-BDC composite material after molded was 10-5 S/cm, which had an increment of at least three orders of magnitude, compared with the bulk PPy(—10-8 S/cm)and In-BDC template.

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备注/Memo

备注/Memo:
收稿日期:2018-03-20。
基金项目:国家自然科学基金(51202066,21333005); 教育部新世纪优秀人才支持计划项目(NCET-13-0784); 湖南省研究生科研创新项目(CX2016B540); 湖南科技大学大学生科研创新计划项目( SYZ2016050,YZ2017068)。
作者简介:田俐(1973—),女,湖南株洲人,博士,教授,主要从事材料化学研究。E-mail:849050031@qq.com
更新日期/Last Update: 2018-05-20