[1]汪称意,曹世杰,陈文涛,等.一类含砜基和三氟甲基结构可溶性聚酰亚胺[J].常州大学学报(自然科学版),2018,30(04):7-12.[doi:10.3969/j.issn.2095-0411.2018.04.002]
　WANG Chenyi,CAO Shijie,CHEN Wentao,et al.A Series of Soluble Polyimides Containing Sulfone and Trifluoromethyl Gourps[J].Journal of Changzhou University(Natural Science Edition),2018,30(04):7-12.[doi:10.3969/j.issn.2095-0411.2018.04.002]
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一类含砜基和三氟甲基结构可溶性聚酰亚胺()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第30卷
期数:
2018年04期
页码:
7-12
栏目:
材料科学与工程
出版日期:
2018-07-28

文章信息/Info

Title:
A Series of Soluble Polyimides Containing Sulfone and Trifluoromethyl Gourps
作者:
汪称意; 曹世杰; 陈文涛; 赵晓燕; 李 坚; 任 强
常州大学 材料科学与工程学院,江苏 常州 213164
Author(s):
WANG Chenyi;  CAO Shijie;  CHEN Wentao;  ZHAO Xiaoyan;  LI Jian;  REN Qiang
School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China
关键词:
聚酰亚胺;  三氟甲基;  溶解性;  热性能;  介电常数
Keywords:
polyimides;  trifluoromethyl groups;  solubility;  thermal stability;  dielectric constants
分类号:
TQ 322.3
DOI:
10.3969/j.issn.2095-0411.2018.04.002
文献标志码:
A
摘要:
由活性双氟砜化合物与3-氨基苯酚经芳香亲核反应,合成了2种新型含氟芳香二胺单体:2,2’-双[3-(4-三氟甲基苯基)-4-(3-氨基苯氧基)苯基]砜(2a)与2,2’-双{3-[3,5-二(三氟甲基)苯基]-4-[3-氨基苯氧基]苯基}砜(2b); 进一步利用该二胺单体分并与3,3’,4,4’-联苯四甲酸二酐经高温溶液缩聚成功制备了2种含三氟甲苯侧基结构聚酰亚胺(3a和3b)。该类含氟聚酰亚胺具有优异的溶解成膜性,可通过其聚合物溶液浇铸得到无色高透明薄膜。所制聚酰亚胺薄膜起始透光波长在342～356 nm之间,450 nm处的透过率均超过80%。该类聚酰亚胺还具有高的热稳定性和较低的介电常数,1 MHz下的介电常数在2.89～2.98。
Abstract:
Two new fluorinated aromatic diamine monomers: 2,2’-bis[3-(4-trifluoromethyl-phenyl)-4-(3-amino-phenoxy)phenyl]sulfone(2a)and 2,2’-bis{3-[3,5-di(trifluoromethyl)-phenyl]-4-(3-amino-phenoxy)phenyl}sulfone(2b), were synthesized via the nucleophilic substitution using the reactive difluorodiphenyl sulfone and 3-aminophenol. Then they were employed to prepare fluorinated polyimides(PI 3a-3b)with 3,3’,4,4’-biphenyltetracarboxylic dianhydride via a one-step high-temperature polycondensation. It swas found that these polyimides exhibited excellent solubility and good film formation ability. Flexbile and strong films based on these fluorinated polyimides could be conveniently obtained by casting solution. The thin films displayed high optical transparency, with the cutoff wavelength at 342-356 nm and transmittance higher than 80% at 450 nm. They also possessed high thermal stability and low dielectric constants with the values in the range of 2.89-2.98 at 1 MHz.

参考文献/References:


[1]DING M X. Isomeric polyimides[J]. Prog Polym Sci,2007,32(9):623-668.
[2]杨士勇,范琳,冀棉,等.耐高温聚酰亚胺材料研究进展[J]. 高分子通报,2011(10):70-78.
[3]王龙耀,蔡梦云,赵宇培,等.联苯双醚型聚酰亚胺的合成与表征[J].常州大学学报(自然科学版),2017,29(2):13-16.
[4]ZHAI L,YANG S Y,FAN L.Preparation and characterization of highly transparent and colorless semi-aromatic polyimide films derived from alicyclic dianhydride and aromatic diamines[J]. Polymer,2012,53(16):3529-3539.
[5]BAE W J,KOVALEV M K,KALININA F,et al. Towards colorless polyimide/silica hybrids for flexible substrates[J]. Polymer,2016,105:124-132.
[6]鲁云华,王巍,肖国勇.含酚酞基团的聚酰亚胺膜材料的合成与性能[J].高分子学报,2016(6):831-836.
[7]陈云云,陈文涛,汪称意,等.一种含烷基取代刚性二胺单体及其聚酰亚胺的合成与表征[J]. 高分子材料科学与工程,2014,30(10):28-32.
[8]CHERN Y T, TSAI J Y, WANG J J.High Tg and high organosolubility of novel unsymmetric polyimides[J].Journal of Polymer Science: Part A: Chemistry,2009,47(9):2443-2452.
[9]WANG C Y,CAO S J,CHEN W T,et al.Synthesis and properties of fluorinated polyimides with multi-bulky pendant groups[J]. RSC Advances,2017,7:26420-26427.
[10]陈文涛,汪称意,陈云云,等. 一种含氟芳香二胺及其聚砜酰亚胺的合成与表征[J]. 高分子学报,2014(2):226-232.
[11]WANG C Y,CHEN W T,XU C,et al. Fluorinated polyimide/POSS hybrid polymers with high solubility and low dielectric constant[J].Chinese Journal of Polymer Science,2016,34(11):1363-1372.
[12]YANG C P,SU Y Y. Synthesis and properties of organosoluble polyimides based on 4,4’-bis(4-amino-2-trifluoromethylphenoxy)-benzophenone[J]. Journal of Polymer Science,2004,42(2):222-236.

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备注/Memo

备注/Memo:
基金项目:国家自然科学基金资助项目(21404016); 江苏省重点研发计划项目(BE2017645)。
作者简介:汪称意(1981—),男,湖北麻城人,博士,副教授。E-mail:wangcy@cczu.edu.cn
更新日期/Last Update: 2018-07-30