[1]王 莹,顾正鹏,崔玲玲,等.氧化石墨烯对钛合金表面水润滑性能的影响[J].常州大学学报(自然科学版),2019,31(03):57-62.[doi:10.3969/j.issn.2095-0411.2019.03.006]
　WANG Ying,GU Zhengpeng,CUI Lingling,et al.Effect of Graphene Oxide on Water Lubrication on the Surface of Titanium Alloy[J].Journal of Changzhou University(Natural Science Edition),2019,31(03):57-62.[doi:10.3969/j.issn.2095-0411.2019.03.006]
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氧化石墨烯对钛合金表面水润滑性能的影响()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第31卷
期数:
2019年03期
页码:
57-62
栏目:
材料科学与工程
出版日期:
2019-05-28

文章信息/Info

Title:
Effect of Graphene Oxide on Water Lubrication on the Surface of Titanium Alloy
文章编号:
2095-0411(2019)03-0057-06
作者:
王 莹1; 2; 顾正鹏1; 崔玲玲1; 储富强1; 袁宁一1; 丁建宁1; 2
(1. 常州大学 江苏省光伏工程科学国家重点实验室培育建设点 江苏省光伏科学与工程协同创新中心 材料科学与工程学院,江苏 常州213164; 2. 江苏大学 微纳科学与技术中心,江苏 镇江 212013)
Author(s):
WANG Ying1; 2;  GU Zhengpeng1;  CUI Lingling1;  CHU Fuqiang1;  YUAN Ningyi1;  DING Jianning1; 2
(1. Changzhou University, Jiangsu Province Cultivation base for State Key Laboratory of Photovoltaic Science and Technology, Jiangsu Collaborative Innovation Center for Photovoltic Science and Engineering, School of Materials Science and Engineering, Changzhou 213164, China; 2. Jiangsu University, Micro/Nano Science and Technology Center, Zhenjiang 212013, China)
关键词:
钛合金;  氧化石墨烯;  水润滑;  摩擦;  磨损
Keywords:
Key words:titanium alloy;  graphene oxide;  water lubrication;  friction;  wear
分类号:
TH 117.2; TG 146.2
DOI:
10.3969/j.issn.2095-0411.2019.03.006
摘要:
利用环境友好的氧化石墨烯优异的减摩抗磨性能来改善钛合金表面的摩擦学行为。制备了多层并具有晶状结构的氧化石墨烯,系统研究了氧化石墨烯对钛合金表面水润滑性能的影响。利用原子力显微镜、Raman和XRD研究了所制备氧化石墨烯的微观结构和成分。采用UMT-2型摩擦磨损实验机和三维光学轮廓仪研究了钛合金在不同润滑条件下的摩擦学性能。研究结果表明:与纯水溶液和含石墨粉的水溶液相比较,钛合金在以氧化石墨烯作为添加剂的水润滑条件下的摩擦系数最低,磨痕也最浅。这可能是因为氧化石墨烯在水溶液中具有良好的分散性,而且氧化石墨烯独特的层状结构使其具有低的剪切力,从而有利于改善其水润滑性能。
Abstract:
Graphene oxide with outstanding friction-reducing and anti-wear properties were expected to improve the frictional behavior of titanium alloys. Multi-layered graphene oxide with crystal structure was fabricated and the effect of graphene oxide on the water lubricating property of titanium alloys were systematically investigated. AFM, Raman and XRD were used to measure the microstructure of the as-prepared graphene oxide. A UMT-2 tribometer and a 3D noncontact interferometric microscope were performed to evaluate the frictional properties of titanium alloys under different lubricating conditions. It was found that titanium alloys lubricated with graphene oxide-added water lubricants has the lowest coefficient of friction, and the wear scar is also relatively shallow, compared with that lubricated with pure water and graphite-added water lubricants. This may be because of the good dispersive property of graphene oxide in aqueous solution and the unique lamellar structure, which endued it with low shearing force and helped to improve the lubricating properties.

参考文献/References:

[1]DIAO Y, ZHANG K. Microstructure andcorrosion resistance of TC2 Ti alloy by laser cladding with Ti/TiC/TiB2 powders[J]. Applied Surface Science, 2015, 352: 163-168.
[2]BAI L L, LI J, CHEN J L, et al. Effect of the content of B4C on microstructural evolution and wear behaviors of the laser-clad coatings fabricated on Ti6Al4V[J]. Optics & Laser Technology, 2016, 76: 33-45.
[3]马永, 朱红梅, 孙楚光, 等. TC4钛合金表面激光熔覆掺Y2O3复合涂层的显微组织和性能[J]. 表面技术, 2017, 46(6): 238-243.
[4]KAO W H, SU Y L, HOMG J H, et al. Improved tribological, electrochemical and biocompatibility propertier of Ti6Al4V alloy by gas-nitriding and Ti-C:H coating[J]. Surface and Coatings Technology, 2015, 283: 70-79.
[5]叶雪梅, 孙雯, 王燕, 等. 热氧化处理对纯钛耐腐蚀性能影响的研究[J]. 钛工业进展, 2014, 31(1): 21-24.
[6]宋振华, 戈晓岚, 许晓静, 等. TC4钛合金固体渗硼催渗剂的研究[J]. 稀有金属, 2014, 38(4): 548-553.
[7]林乃明, 王娅婷, 邹娇娟, 等. 热氧化温度对Ti6Al4V耐磨性的影响[J]. 稀有金属材料与工程,2016, 45(6): 1615-1619.
[8]周鹏, 林乃明, 田伟, 等. TC4合金微弧氧化层的耐磨性和耐蚀性[J]. 表面技术, 2015, 44(11): 14-20.
[9]YAKOVLEV A, BERTRAND P H, SMUROV I. Laser cladding of wear resistant metal matrix composite coating[J]. Thin Solid Film, 2004, 453/454(1): 133-138.
[10]LI Z X, MA S H, ZHANG G, et al. Soft/hard-coupled amphiphilic polymer nanospheres for water lubrication. ACS Appl Mater Interfaces, 2018, 10: 9178-9187.
[11]YANG Y, ZHANG C H, WANG Y, et al. Friction and wear performance of titanium alloy against tungsten carbide lubricated with phosphate ester[J]. Tribology International, 2016, 95: 27-34.
[12]CAO L, LIU J, WAN Y, et al. Low-friction carbon-based tribofilm from poly-alpha-olefin oil on thermally oxidized Ti6Al4V[J]. Surface & Coatings Technology, 2018, 337: 471-477.
[13]NAJIHA M S, RAHMAN M M. Experimental investigation of flank wear in end milling of aluminum alloy with water-based TiO2 nanofluid lubricant in minimum quantity lubrication technique[J]. International Journal of Advanced Manufacturing Technology, 2016, 86: 2527-2537.
[14]SENATORE A, PISATURO M, GUIDA D. Polyalkylene glycol based lubricants and tribological behaviour: Role of ionic liquids and graphene oxide as additives[J]. Journal of Nanoscience and Nanotechnology, 2018, 18: 913-924.
[15]KUMAR P, WANI M F. Tribological characterisation of graphene oxide as lubricant additive on hypereutectic Al-25Si/steel tribopair[J]. Tribology Transactions, 2018, 61: 335-346.
[16]HUMMERS J W S, OFFEMAN R E. Preparation of graphitic oxide[J]. Journal of the American Chemical Society, 1958, 80(6): 1339-1339.
[17]NEMES-INCZE P, OSVATH Z, KAMARAS K, et al. Anomalies in thickness measurements of graphene and few layer graphite crystals by tapping mode atomic force microcopy[J]. Carbon, 2008, 46: 1435-1442.
[18]FERRARI A C, MEYER J C, SCARDACI V, et al. Raman spectrum of graphene and graphene layers[J]. Physical Review Letters, 2006, 97(18): 187401.
[19]WANG Y, PU J B, XIA L, et al. Fabrication and tribological study of graphene oxide/multiply- alkylated cyclopentanes multilayer lubrication films on Si substrates[J]. Tribology Letters, 2014, 53: 207-214.
[20]DONG H, BELL T. Tribological behavior of alumina sliding against Ti6Al4V in unlubricated contact[J]. Wear, 1999, 225-229: 874-884.

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备注/Memo

备注/Memo:
收稿日期:2018-09-02。
基金项目:国家博士后基金(2016M600366); 清华大学摩擦学国家重点实验室开放课题(SKLTKF16A03); 江苏省高等学校自然科学研究面上项目(17KJB430002)。
作者简介:王莹(1982—),女,河南南阳人,博士,副研究员。E-mail:ywang@cczu.edu.cn
更新日期/Last Update: 2019-05-29