[1]陈艳丽,张龙生,刘权坤,等.以猕猴桃皮为碳源荧光碳点的制备及应用[J].常州大学学报(自然科学版),2019,31(05):16-23.[doi:10.3969/j.issn.2095-0411.2019.05.003]
 CHEN Yanli,ZHANG Longsheng,LIU Quankun,et al.Facile Synthesis and Application of Fluorescent Carbon Dots Using Kiwi Fruit Peel as Carbon Source[J].Journal of Changzhou University(Natural Science Edition),2019,31(05):16-23.[doi:10.3969/j.issn.2095-0411.2019.05.003]
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以猕猴桃皮为碳源荧光碳点的制备及应用()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第31卷
期数:
2019年05期
页码:
16-23
栏目:
化学化工
出版日期:
2019-09-28

文章信息/Info

Title:
Facile Synthesis and Application of Fluorescent Carbon Dots Using Kiwi Fruit Peel as Carbon Source
文章编号:
2095-0411(2019)05-0016-08
作者:
陈艳丽12张龙生1刘权坤1曹剑瑜12许 娟12陈智栋12
(1.常州大学 石油化工学院,江苏 常州 213164; 2.江苏省绿色催化材料与技术重点实验室,江苏 常州 213164)
Author(s):
CHEN Yanli12ZHANG Longsheng1LIU Quankun1CAO Jianyu12XU Juan12CHEN Zhidong12
(1. School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China; 2. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology,Changzhou 213164,China)
关键词:
荧光碳点 水热法 稳定性 荧光油墨
Keywords:
fluorescent carbon dots hydrothermal method stability fluorescent ink
分类号:
O 64
DOI:
10.3969/j.issn.2095-0411.2019.05.003
文献标志码:
A
摘要:
以猕猴桃皮为碳源,通过水热法制备出了水溶性的荧光碳点,制备步骤简单、成本低廉。通过透射电镜(TEM)、X-射线粉末衍射(XRD)、红外光谱(FT-IR)、拉曼光谱(Raman)等手段对荧光碳点形貌和化学组成进行分析,并通过紫外可见吸收光谱(UV-Vis)和荧光发射光谱(PL)对其光学性能进行研究,还对其在荧光油墨方面的应用做了初步尝试。结果表明:所制备的荧光碳点在365 nm紫外灯照射下呈现蓝色荧光,并表现出激发波长依赖性,具有很好的稳定性和抗离子干扰能力; 该荧光碳点用作绿色、低成本的荧光油墨,用其书写或印刷的图文在可见光下隐形,可用于记录、存储和加密信息。
Abstract:
Fluorescent carbon dots were successfully prepared by hydrothermal treatment using kiwi fruit peel as the carbon source. The preparation procedure was simple and low-cost. The morphologies and chemical compositions of the fluorescent carbon dots were analyzed by transmission electron microscope(TEM), X-ray diffraction(XRD), Fourier transform infrared spectra(FT-IR), Raman spectra(Raman)and other characterization methods. The optical properties were also studied by ultraviolet visible absorption spectroscopy(UV-Vis)and fluorescence emission spectroscopy(PL). At the same time, the application of fluorescent carbon dots in fluorescent ink has also been preliminarily tried. The results showed that the prepared fluorescent carbon dots presented blue fluorescence under ultraviolet irradiation at 365 nm. The fluorescent carbon dots exhibited excitation-wavelength-dependent fluorescence properties. Moreover, it had good stability and ability to resist ion interference. As a green low-cost fluorescent ink, the fluorescent carbon dots can be used to record, store and encrypt information owing to its characteristics that the texts and graphics written or printed by it were invisible in visible light.

参考文献/References:

[1] BAKER S N,BAKER G A. Luminescent carbon nanodots: emergent nanolights[J]. Angewandte Chemie International Edition,2010,49(38):6726-6744.
[2]WANG C,SUN D,ZHUO K,et al. Simple and green synthesis of nitrogen-, sulfur-, and phosphorus-co-doped carbon dots with tunable luminescence properties and sensing application[J]. RSC Advances,2014,4(96):54060-54065.
[3]HUANG H,LYU J J,ZHOU D L,et al. One-pot green synthesis of nitrogen-doped carbon nanoparticles as fluorescent probes for mercury ions[J]. RSC Advances,2013,3(44):21691-21696.
[4]GUO Y,WANG Z,SHAO H,et al. Hydrothermal synthesis of highly fluorescent carbon nanoparticles from sodium citrate and their use for the detection of mercury ions[J]. Carbon,2013,52(2):583-589.
[5]HUANG P,LIN J,WANG X,et al. Light-triggered theranostics based on photosensitizer-conjugated carbon dots for simultaneous enhanced-fluorescence imaging and photodynamic therapy[J]. Advanced Materials,2012,24(37):5104-5110.
[6]冯昌,邓晓燕,倪晓晓,等. 碳点修饰多孔ZnO纳米棒增强光催化性能[J]. 物理化学学报,2015,31(12):2349-2357.
[7]ZHU S,MENG Q,WANG L,et al. Highly photoluminescent carbon dots for multicolor patterning, sensors, and bioimaging[J]. Angewandte Chemie International Edition,2013,52(14):3953-3957.
[8]GAO S Y,CHEN Y L,FAN H,et al. A green one-arrow-two-hawks strategy for nitrogen-doped carbon dots as fluorescent ink and oxygen reduction electrocatalysts[J]. Journal of Materials Chemistry A,2014,2(18):6320-6325.
[9]QU S,WANG X,LU Q,et al. A biocompatible fluorescent ink based on water-soluble luminescent carbon nanodots[J]. Angewandte Chemie,2012,124(49):12381-12384.
[10]HSU P C,CHEN P C,OU C M,et al. Extremely high inhibition activity of photoluminescent carbon nanodots toward cancer cells[J]. Journal of Materials Chemistry B,2013,1(13):1774-1781.
[11]YANG S T,CAO L,LUO P G,et al. Carbon dots for optical imaging in vivo[J]. Journal of the American Chemical Society,2009,131(32):11308-11309.
[12]MEHTA V N,JHA S,KAILASA S K. One-pot green synthesis of carbon dots by using saccharum officinarum juice for fluorescent imaging of bacteria( escherichia coli )and yeast( saccharomyces cerevisiae )cells[J]. Materials Science & Engineering C,2014,38(9):20-27.
[13]YUAN M,ZHONG R B,GAO H Y,et al. One-step, green, and economic synthesis of water-soluble photoluminescent carbon dots by hydrothermal treatment of wheat straw, and their bio-applications in labeling, imaging, and sensing[J]. Applied Surface Science,2015,355:1136-1144.
[14]ZHU C,ZHAI J,DONG S. Bifunctional fluorescent carbon nanodots: green synthesis via soy milk and application as metal-free electrocatalysts for oxygen reduction[J]. Chemical Communications,2012,48(75):9367-9369.
[15]LU W B,QIN X Y,LIU S,et al. Economical, green synthesis of fluorescent carbon nanoparticles and their use as probes for sensitive and selective detection of mercury(ii)ions[J]. Analytical Chemistry,2012,84(12):5351-5357.
[16]SAHU S,BEHERA B,MAITI T K,et al. Simple one-step synthesis of highly luminescent carbon dots from orange juice: Application as excellent bio-imaging agents[J]. Chemical Communications,2012,48(70):8835-8837.
[17]MIAO H,WANG L,ZHUO Y,et al. Label-free fluorimetric detection of cea using carbon dots derived from tomato juice[J]. Biosensors and Bioelectronics,2016,86:83-89.
[18]DE B,KARAK N. A green and facile approach for the synthesis of water soluble fluorescent carbon dots from banana juice[J]. RSC Advances,2013,3(22):8286-8290.
[19]YANG R,GUO X F,JIA L H,et al. Green preparation of carbon dots with mangosteen pulp for the selective detection of Fe3+ ions and cell imaging[J]. Applied Surface Science,2017,423:426-432.
[20]CHATZIMITAKOS T,KASOUNI A,SYGELLOU L,et al. Two of a kind but different: luminescent carbon quantum dots from citrus peels for iron and tartrazine sensing and cell imaging[J]. Talanta,2017,175:305-312.
[21]DANG D K,SUNDARAM C,NGO Y L T,et al. One pot solid-state synthesis of highly fluorescent N and S co-doped carbon dots and its use as fluorescent probe for Ag+ detection in aqueous solution[J]. Sensors and Actuators B: Chemical,2018,255:3284-3291.
[22]WANG L,BI Y,HOU J,et al. Facile, green and clean one-step synthesis of carbon dots from wool: application as a sensor for glyphosate detection based on the inner filter effect[J]. Talanta,2016,160:268-275.
[23]ZHOU L,LIN Y,HUANG Z,et al. Carbon nanodots as fluorescence probes for rapid, sensitive, and label-free detection of Hg2+ and biothiols in complex matrices[J]. Chemical Communications,2012,48(8):1147-1149.
[24]李颖. 荧光碳点的制备与性质研究[D]. 上海:华东师范大学,2017.
[25]曹剑瑜,陈利娟,赵卫芳,等. 牺牲模板法制高比电容的氮修饰石墨烯及其电化学性能研究[J]. 常州大学学报(自然科学版),2015,27(3):56-60.
[26]SUN Y P,ZHOU B,LIN Y,et al. Quantum-sized carbon dots for bright and colorful photoluminescence[J]. Journal of the American Chemical Society,2006,128(24):7756-7757.
[27]孙钰朋,许亮,杨梅,等. 具有pH敏感性的氮、磷、硫共掺杂碳点的制备及其光谱研究[J]. 光散射学报,2015,27(4):336-341.

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备注/Memo

备注/Memo:
收稿日期:2018-07-14。
基金项目:国家自然科学基金资助项目(51574047); 常州大学科研基金项目(ZMF17020038)。
作者简介:陈艳丽(1986—),女,河南信阳人,博士,讲师。通信联系人:陈智栋(1964—),E-mail:zdchen@cczu.edu.cn
更新日期/Last Update: 2019-09-30