[1]郑旭东,崔亚文,王丹丹,等.印迹复合壳聚糖膜的制备及其选择性吸附分离铜离子[J].常州大学学报(自然科学版),2022,34(06):9-19.[doi:10.3969/j.issn.2095-0411.2022.06.002]
　ZHENG Xudong,CUI Yawen,WANG Dandan,et al.Preparation of Imprinted Composite Chitosan Membrane and Their Selective Adsorption and Separation of Copper Ions[J].Journal of Changzhou University(Natural Science Edition),2022,34(06):9-19.[doi:10.3969/j.issn.2095-0411.2022.06.002]
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印迹复合壳聚糖膜的制备及其选择性吸附分离铜离子()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第34卷
期数:
2022年06期
页码:
9-19
栏目:
环境科学与工程
出版日期:
2022-11-28

文章信息/Info

Title:
Preparation of Imprinted Composite Chitosan Membrane and Their Selective Adsorption and Separation of Copper Ions
文章编号:
2095-0411(2022)06-0009-11
作者:
郑旭东; 崔亚文; 王丹丹; 张雨哲; 李忠玉
(常州大学环境科学与工程学院,江苏常州213164)
Author(s):
ZHENG Xudong;  CUI Yawen;  WANG Dandan;  ZHANG Yuzhe;  LI Zhongyu
(School of Environmental Science and Engineering, Changzhou University, Changzhou 213164, China)
关键词:
壳聚糖;  选择性吸附;  离子印迹;  蒙脱土;  聚乙烯醇
Keywords:
chitosan;  selective adsorption;  ion imprinting;  montmorillonite;  polyvinyl alcohol
分类号:
X 756
DOI:
10.3969/j.issn.2095-0411.2022.06.002
文献标志码:
A
摘要:
提出一种大孔印迹复合壳聚糖(CS)膜吸附材料,采用离子印迹技术和胶体晶体模板对水中铜离子进行吸附。加入聚苯乙烯(PS)微球和铜模板,分别形成三维大孔结构和离子印迹位点。此外,还加入聚苯乙烯和蒙脱土(MMT)对膜材料进行有机和无机的改性,达到其机械性能增强、结构稳定牢固的目的。最后,通过干燥形成薄膜。吸附实验表明,壳聚糖/蒙脱土(CS/MMT)印迹复合膜在水溶液中对Cu2+的去除效果良好,在pH=7.0的中性条件下具有良好的吸附性能,吸附效率高,最大吸附量为230.48 mg/g,吸附过程更符合准二级动力学模型和Langmuir等温线,对Cu2+有较好的选择性吸附。此外,CS/MMT印迹复合膜可以多次再生,作为吸附剂重复使用,保持了较高的吸附容量。这种印迹模板法对生物材料中污染物的选择性吸附具有重要意义,值得深入研究。
Abstract:
Copper ion imprinting and colloidal crystal template were used to adsorb in water. Polystyrene microspheres and copper templates were added to form three-dimensional macroporous structure and ion imprinted sites, respectively. In addition, polyvinyl alcohol and montmorillonite were added to modify the membrane materials organically and inorganically, so as to enhance its mechanical properties and stabilize its structure. Finally, the film was formed by drying. The adsorption experiments showed that CS/MMT imprinted composite membrane had a good removal effect on Cu2+ in aqueous solution. CS/MMT imprinted composite membrane has good adsorption performance and high adsorption efficiency under the neutral condition of pH=7.0. The maximum adsorption capacity of CS/MMT imprinted composite membrane was 230.48 mg/g. The adsorption process is more consistent with the quasi second-order kinetic model and Langmuir isotherm. CS/MMT imprinted composite membrane has good selective adsorption for Cu2+. In addition, it can be regenerated for many times and reused as adsorbent, maintaining a high adsorption capacity. This imprinting template method is of great significance for the selective adsorption of pollutants in bio-materials, and is worth further study.

参考文献/References:

[1] CHENG Y W, DING F Q, SHENG M X. Significance, status and important issues for recycling utilization of metal secondary resource in China[J]. The Chinese Journal of Nonferrous Metals, 2008, 18(1): 359-366.
[2] 孟多, 周立岱, 于常武. 水体重金属污染现状及治理技术[J]. 辽宁化工, 2006, 35(9): 534-536, 549.
[3]于天宇, 胡思雨. 水体重金属污染现状及治理方法概述[J]. 建筑与预算, 2019(6): 75-78.
[4] AVRAMOVIC-CINGARA G, OSOSKOV Y, JAIN M K, et al. Effect of martensite distribution on damage behaviour in DP600 dual phase steels[J]. Materials Science and Engineering: A, 2009, 516(1/2): 7-16.
[5] 陈东, 张凤娥, 相金刚, 等. 氨基嫁接复合高龄土对含铜废水吸附性能研究[J]. 常州大学学报(自然科学版), 2022, 34(2): 28-37.
[6] 姜玉娟, 陈志强. 电镀废水处理技术的研究进展[J]. 环境科学与管理, 2015, 40(3): 45-48.
[7] 蔡静. 改性木屑的制备及其对铜离子的吸附研究[D]. 北京: 北京化工大学, 2016.
[8] 鲍旭. 粉煤灰@壳聚糖磁性铜离子吸附剂的制备及性质研究[D]. 淮南: 安徽理工大学, 2017.
[9] 张楠. 壳聚糖基吸附剂去除水溶液中金属离子的研究进展[J]. 科技创新与应用, 2020(18): 44-45.
[10] 段久芳. 天然高分子材料[M]. 武汉: 华中科技大学出版社, 2016.
[11] GUILHERME M R, MATTOSO L H C, GONTARD N, et al. Synthesis of nanocomposite films from wheat gluten matrix and MMT intercalated with different quaternary ammonium salts by way of hydroalcoholic solvent casting[J]. Composites Part A: Applied Science and Manufacturing, 2010, 41(3): 375-382.
[12] KUMAR P, SANDEEP K P, ALAVI S, et al. Preparation and characterization of bio-nanocomposite films based on soy protein isolate and montmorillonite using melt extrusion[J]. Journal of Food Engineering, 2010, 100(3): 480-489.
[13] ENOMOTO H, MATSUMOTO S, LERNER M M. Synthesis and characterization of conductive polypyrrole/montmorillonite nanocomposite[J]. Japanese Journal of Applied Physics, 2005, 44(6): L224-L226.
[14] 李桂娟, 夏伟, 罗海希, 等. 纳米纤维素晶须-壳聚糖/聚乙烯醇复合膜性能与细胞相容性[J]. 化工进展, 2020, 39(1): 356-364.
[15] FU J Q, CHEN L X, LI J H, et al. Current status and challenges of ion imprinting[J]. Journal of Materials Chemistry A, 2015, 3(26): 13598-13627.
[16] ZARGHAMI S, MOHAMMADI T, KAZEMIMOGHADAM M. Adsorption behavior of Cu(II)ions on crosslinked chitosan/polyvinyl alcohol ion imprinted membrane[J]. Journal of Dispersion Science and Technology, 2015, 36(2): 190-195.
[17] SALEHI E, MADAENI S S, VATANPOUR V. Thermodynamic investigation and mathematical modeling of ion-imprinted membrane adsorption[J]. Journal of Membrane Science, 2012, 389: 334-342.
(责任编辑:谭晓荷)

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备注/Memo

备注/Memo:
收稿日期: 2022-04-20。
基金项目: 国家自然科学基金资助项目(U1507115,U1507118)。
作者简介: 郑旭东(1988—), 男, 辽宁大连人, 博士, 副教授。E-mail: zheng@cczu.edu.cn
更新日期/Last Update: 1900-01-01