[1]ZHANG Jing,XU Linjun,YUAN Ningyi,等.Photovoltaic Molecule Containing Bi-4-Hexyl-Thienylenevinylene(BHTV)as the Conjugated Pi-Bridge for Bulk-Heterojunction Organic Solar Cells[J].常州大学学报(自然科学版),2018,30(06):17-24.[doi:10.3969/j.issn.2095-0411.2018.06.003]
　,,et al.长共轭桥的分子材料在太阳能电池中的应用[J].Journal of Changzhou University(Natural Science Edition),2018,30(06):17-24.[doi:10.3969/j.issn.2095-0411.2018.06.003]
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Photovoltaic Molecule Containing Bi-4-Hexyl-Thienylenevinylene(BHTV)as the Conjugated Pi-Bridge for Bulk-Heterojunction Organic Solar Cells()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第30卷
期数:
2018年06期
页码:
17-24
栏目:
材料科学与工程
出版日期:
2018-11-28

文章信息/Info

Title:
长共轭桥的分子材料在太阳能电池中的应用
作者:
ZHANG Jing;  XU Linjun;  YUAN Ningyi;  DING Jianning
(School of Materials Science & Engineering, Changzhou University, Changzhou 213164, China)
Author(s):
张 婧; 许林军; 袁宁一; 丁建宁
(常州大学 材料科学与工程学院,江苏 常州 213164)
关键词:
solution-processed photovoltaic molecules;  organic solar cells;  bi-4-hexyl-thienylenevinylene π conjugated bridge
Keywords:
溶液可加工光伏分子;  有机太阳能电池;  双己基噻吩乙烯基共轭桥
分类号:
O 63
DOI:
10.3969/j.issn.2095-0411.2018.06.003
文献标志码:
A
摘要:
Linear D-A-D molecule with bi-(4-hexylthiophen-2-yl)vinyl(BHTV)as the conjugated π bridge between triphenylamine(TPA)donor unit(D)and 2-(4H-pyran-4-ylidene)malononitrile(PM)acceptor unit(A), TPA-BHTV-PM, has been designed and synthesized. It is applied in solution-processed organic solar cells(OSCs)as the donor material. Bi-(4-hexylthiophen-2-yl)vinyl was a π bridge containing double 4-hexyl-thienylenevinylene units and introduced into the TPA-PM-containing D-A structured molecule aiming to extend the absorbance and improve the photovoltaic properties. Through the investigation of optical and electrochemical properties of the molecule, TPA-BHTV-PM exhibits broad absorption in visible region from 350 nm to 700 nm and lower highest occupied molecular orbit(HOMO)energy level, which are fundamentals as donor in organic solar cells. The OSC devices were fabricated by spin-coating the blend solution of the TPA-BHTV-PM and PC71BM. The OSC device displayed an open circuit voltage(VOC)of 0.76 V, a short circuit current density(JSC)of 6.97 mA/cm2 and a fill factor(FF)of 38.7% which leading a power conversion efficiency(PCE)of 2.10%, under the illumination of AM.1.5, 100 mW/cm2.
Abstract:
可溶液加工有机分子太阳能电池因为同时具有聚合物太阳能电池制备工艺简单、成本低、质量轻、可制备成柔性器件,以及有机分子蒸镀太阳能电池材料分子结构确定和器件性能容易重复的优点而受到广泛关注。设计合成了以三苯胺为给体单元、二腈基吡喃为受体单元、双己基噻吩乙烯基为共轭桥的D-A结构线型分子材料TPA-BHTV-PM,长共轭桥的引入拓宽分子材料的吸收(350～700 nm)。将分子材料与PC71BM按质量比1/3共混制备光伏器件,可得到0.76 V的开路电压,6.97 mA/cm2的短路电流,38.7%的填充因子和2.10%的能量转换效率。

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备注/Memo

备注/Memo:
收稿日期:2018-07-20。
基金项目:国家自然科学基金资助项目(51272033,51562037,51603021)。
作者简介:张婧(1984—),女,河北唐山人,博士,讲师。E-mail: zhangjing1984@cczu.edu.cn
更新日期/Last Update: 2018-10-28