[1]郭登峰,潘剑波,严小丽,等.高效SE - 54 色谱毛细管交联柱的制备和研究[J].常州大学学报(自然科学版),2006,(04):56-59.
　GUO Deng - feng,PAN J ian - bo,YAN Xiao - li,et al.Preparation of High Eff icient Capillary Columns and Investigation on Chromatographic Performance[J].Journal of Changzhou University(Natural Science Edition),2006,(04):56-59.
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高效SE - 54 色谱毛细管交联柱的制备和研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2006年04期
页码:
56-59
栏目:
出版日期:
2006-12-25

文章信息/Info

Title:
Preparation of High Eff icient Capillary Columns and Investigation on Chromatographic Performance
作者:
郭登峰;  潘剑波;  严小丽;  柳　娜
江苏工业学院化学工程系, 江苏 常州 213164
Author(s):
GUO Deng - feng ;  PAN J ian - bo ;  YAN Xiao - li ;  L IU Na
Department of Chemical Engineering , J iangsu Polytechnic University , Changzhou 213164 , China
关键词:
气相色谱;  石英毛细管柱;  制备;  分析
Keywords:
gas chromatography ;  capillary column ;  crosslinking ;  preparation
分类号:
O 657.8
文献标志码:
A
摘要:
研究了石英毛细管内表面活性点处理方法, 并在适当的温度下, 用C1P 引发交联, 制备SE - 54 石英毛细管柱。实验结 果表明: 经预脱活毛细管内表面与固定相的润湿性得到显著改善, 同时提高了色谱柱的柱效和耐温性能, 降低了柱流失, 柱效 达2 700 块/ m 以上。讨论了柱温对分离参数的影响, 并应用于几个分析实例, 得到了令人满意的结果。
Abstract:
A new method of preparing high effcient capillary column was studied. The wall of fused - silica cap2 illary tube was pret reated to delete active sites prior to coating stationary phase. The columns were coated by superdynamic method with C. P as cross - linking reaction agent under proper temperature. The separation and retention behaviors under different oven temperture were also investigated. The experiment results showed that the number of effective plates was over 2 700/ m. The cross - linked capillary columns possess excellent separation efficiency , wettability , inertness and stability at high temperature. The prepared capillary column was applied to several sample analysis with satisfactory results.

参考文献/References:

[1] 卢佩章1 色谱理论基础[M] 1 北京: 科学出版社, 19891
[2] 吴采樱, 曾昭睿1 现代毛细管气相色谱法[M] 1 武汉: 武汉 大学出版社, 19901
[3] 傅若农, 戴荣继, 周伟1 毛细管气相色谱在工业分析中的应用 [J] 1 北京理工大学学报, 1996 , 16 (2) : 176 - 1801
[4] Wantanabe C , Tomita H. Glass SCOT Column Preparation of Nonpolar Liguid Coated Columns [J] . Chromatogr Sci , 1975 , (3) : 1231
[5] 黄爱令, 南楠, 陈敏, 等1 玻璃毛细柱内壁粗燥化的一种改进 的氯化钠沉淀积法[J] 1 北京大学学报( 自然科学版) , 1988 , (4) : 418 - 4191
[6] Grob K, Grob B Blum , Walthger W. Preparation of Inert Glass Capillary Columns for Gas Chromatography [J] . Chromatogr , 1982 , 244 : 197 - 1981
[7] 黎宏彦, 吴采樱1 弹性石英毛细柱FFAP 去活方法的研究[J] 1 色谱, 1990 , 8 (2) : 94 - 951

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备注/Memo

备注/Memo:
基金项目: 江苏工业学院科技基金资助 作者简介: 郭登峰(1964 - ) , 男, 江苏南通人, 硕士, 副教授, 主要从事气相色谱及工业分析方面的教学和研究。
更新日期/Last Update: 2006-12-25