[1]张艳松,马江权,陆?? 敏,等.浅色C9 芳烃石油树脂的合成与改性??[J].常州大学学报(自然科学版),2007,(02):15-18.
　ZHANG Yan- song,MA Jiang- quan,LU Min,et al.Research of Preparation and Modification of Light- Colored C9 Aromatic Petroleum Resins[J].Journal of Changzhou University(Natural Science Edition),2007,(02):15-18.
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浅色C9 芳烃石油树脂的合成与改性??()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2007年02期
页码:
15-18
栏目:
出版日期:
2007-06-25

文章信息/Info

Title:
Research of Preparation and Modification of Light- Colored C9 Aromatic Petroleum Resins
作者:
张艳松 1 ;  马江权1;  陆?? 敏1;  2 ;  杨利民1;  黄荣荣1
1.江苏工业学院江苏省精细石油化工重点实验室, 江苏 常州 213164; 2.常州工程职业技术学院, 江苏 常州 213164
Author(s):
ZHANG Yan- song 1 ;  MA Jiang- quan 1 ;  LU Min 1;  2 ;  YANG Li- min 1 ;  HUANG Rong- rong 1
1. Jiangsu Key Laboratory of Fine Petrochemical Engineering, Jiangsu Polytechnic University, Changzhou 213164, China; 2. Chang zhou Inst itute of Eng ineering Technology, Changzhou 213164, China
关键词:
C9 石油树脂;  阳离子聚合;  改性
Keywords:
C9 pet roleum resins;  cat ionic polymerization;  modif icat ion
分类号:
T Q 052.4 ??
文献标志码:
A
摘要:
C9 馏分经过预处理, 再以三氟化硼乙醚溶液( BF3??Et 2O) 作聚合催化剂合成C9 石油树脂, 考察了催化剂用量、反应温 度、反应时间、抗氧剂对产品质量的影响。合适的工艺条件是: 将C9 馏份进行蒸馏, 收集130~ 180 ℃??之间的馏份, 用0. 3% ~ 0.5% BF3??Et 2O 在2~ 10 ℃下反应4 h, 用10%Na2CO3 水溶液中和并脱除催化剂, 水洗后减压蒸馏可得到色泽浅、软化点高 的C9 石油树脂。同时介绍了石油树脂的加氢改性和化学改性方法, 进一步改善了石油树脂的性能。
Abstract:
C9 petroleum resins have been prepared by pret reatment of C9 petroleum fractions, in the presence of catalyst BF3??Et 2O. The quantity of catalyst, reaction temperature, reaction time and ant iox idant on product quality were studied. T he reasonable process condit ions were described as follows: the distillates w ith a boiling range of 130- 180 ℃ obtained by dist illation of C9 fraction were polymerized 4 h at 2- 10 ℃?? in the presence of 0.?3%- 0.5% BF3??Et2O. The product was neut ralized with 10% Na2CO3, washed and dist illed in vacuum giving light- colored C9 pet roleum resins with high softening point . Hydrogenat ion modification and chemical modification of C9 petroleum resins were studied, providing pet roleum resins with a high quality.

参考文献/References:

[1] 彭高聪, 路宝田, 向绍基, 等?? 浅色度C9 石油树脂研究?? ?? 树脂合成与生色机制[J] ?? 涂料工业, 1997, ( 2) : 15- 17??
[2] Takahashi A, Ochiai F, Ikeda Y, et al . Process f or manufacturing pet roleum resin [P] . US: 5206358, 1993- 04- 27??
[3] Small Aguestus Baily, Evans Morris L ess. Aromatic sof t ening high point pet roleum resin and process f or it s preparat ion [P] . EP: 0225945, 1987- 06- 24.
[4] Zohuriaan - Mehr M J, Omidian H . Pet roleum resins overview [J] . Journal of Macromolecular Science, 2000, 1: 23- 45.
[5] Okazaki T, Nahahara E, Keshi H, et al. Process f or producing hydrogenat ed C9 pet roleum resin and hydrogenat ed C9 pet roleum resin obt ained by the process [P] . U S: 6458902, 2002 - 10 - 01??
[6] Yamane, Hideki. Method for producing pet roleum res in and hydrogenat ed pet roleum resin [P] . US : 20060063892, 2006- 03 - 23.
[7] 李春生, 寿崇琦, 顾尧??C9 石油树脂的改性[J] ?? 石油化工, 1999, 28 ( 2) : 104- 106??
[8] 闫卫东, 肖翠玲??C9 石油树脂改性研究状况[J] ?? 齐齐哈尔 大学学报, 1995, 11 ( 4) : 76- 78??

备注/Memo

备注/Memo:
基金项目: 扬子石油化工股份有限公司资助项目( 03JSNJYZ110032) 作者简介: 张艳松( 1981- ) , 女, 江苏射阳人, 硕士研究生; 联系人: 黄荣荣。
更新日期/Last Update: 2007-06-25