[1]林本才,冯天,乔刚,等.交联剂含量对碱性阴离子交换膜性能的影响[J].常州大学学报(自然科学版),2015,(03):13-17.[doi:10.3969/j.issn.2095-0411.2015.03.003]
　LIN Bencai,FENG Tianying,QIAO Gang,et al.Effect of the Content of Crosslinker on the Performance of Alkaline Anion Exchange Membrane[J].Journal of Changzhou University(Natural Science Edition),2015,(03):13-17.[doi:10.3969/j.issn.2095-0411.2015.03.003]
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交联剂含量对碱性阴离子交换膜性能的影响()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2015年03期
页码:
13-17
栏目:
出版日期:
2015-07-25

文章信息/Info

Title:
Effect of the Content of Crosslinker on the Performance of Alkaline Anion Exchange Membrane
作者:
林本才1; 2; 冯天1; 乔刚1; 储富强1; 袁宁一1; 2; 丁建宁1; 2
1.常州大学 材料科学与工程学院，江苏 常州 213164；2. 江苏省光伏科学与工程协同创新中心，江苏 常州 213164
Author(s):
LIN Bencai1; 2;  FENG Tianying1;  QIAO Gang1;  CHU Fuqiang1;  YUAN Ningyi1; 2;  DING Jianning1; 2
1.School of Materials Science and Engineering，Changzhou University，Changzhou 213164，China； 2. Jiangsu Collaborative Innovation Center of Photovolatic Science and Engineering，Changzhou 213164，China
关键词:
离子液体; 交联剂; 阴离子交换膜; 燃料电池
Keywords:
ionic liquids;  cross-linker;  anion exchange membrane;  fuel cells
分类号:
O 69
DOI:
10.3969/j.issn.2095-0411.2015.03.003
文献标志码:
A
摘要:
通过紫外光引发聚合的方法制备了碱性阴离子交换膜，通过万能试样机、热重分析仪和电化学工作站研究了碱性阴离子交换膜的机械性能、热稳定性和电导率，并考察了交联剂对二乙烯基苯的含量对碱性阴离子交换膜性能的影响。实验结果表明交联剂的含量对碱性阴离子交换膜热稳性几乎没有影响；随着交联剂含量的增加，碱性阴离子交换膜的弹性模量和抗张强度逐渐增大，但是阴离子交换膜的吸水率、溶胀度和电导率逐渐降低。通过控制交联剂的含量可以很好地调节碱性阴离子交换膜的综合性能，当交联剂质量分数为4%时，碱性阴离子交换膜的抗张强度为13.6〖KG3x〗MPa，弹性模量为449〖KG3x〗MPa，30〖KG3x〗℃时电导率达到3.3×10-2〖KG3x〗S·cm-1，这些实验结果表明该类碱性阴离子交换膜具有很好的应用前景。
Abstract:
Alkaline anion-exchange membranes (AEMs) are prepared by irradiation with UV light. The thermal stability, mechanical properties and conductivity of AEMs were characterized by thermogravimetric analyzer, Instron universal testing machine and electrochemical workstation, respectively. The effect of crosslinker (divinylbenzene, DVB) content on the properties of the AEMs was systematically studied. The results showed that the crosslinker content has little influence on the thermal stability of the AEMs. The values of tensile strength and elastic modulus of the AEMs are increased, while the water uptake, swelling degree and conductivity of AEMs are decreased with increasing the crossliker content. The properties of the AEMs could be well adjusted by changing the content of crosslinker. The AEM with 4% DVB shows the tensile strength of 136〖KG3x〗MPa, elastic modulus of 449〖KG3x〗MPa, and the conductivity of 3.3×10-2〖KG3x〗S·cm-1 at 30〖KG3x〗℃. The AEMs show good potential applications in alkaline anion exchange membrane fuel cells.

参考文献/References:

[1]刘勇，刘世斌，张忠林，等. 阴离子膜直接甲醇燃料电池 [J]. 电源技术, 2006, 30 (2): 125-129.
[2]于景荣，邢丹敏，刘富强，等. 燃料电池用质子交换膜的研究进展 [J]. 电化学, 2001, 7 (4): 385-395.
[3]XU T, LIU Z, LI Y, et al. Preparation and characterization of type II anion exchange membranes from poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) [J]. J Memb Sci, 2008, 320 (1-2): 232-239.
[4]COUTURE G, ALAAEDDINE A, BOSCHET F, et al. Polymeric materials as anion-exchange membranes for alkaline fuel cells [J]. Prog Polym Sci, 2011, 36 (11): 1521-1557.
[5]LIN B, QIU L, LU J, YAN F. Cross-linked alkaline ionic liquid-based polymer electrolytes for alkaline fuel cell applications [J]. Chem Mater, 2010, 22 (24): 6718-6725.
[6]LIN B, QIU L, QIU B, et al. A soluble and conductive polyfluorene ionomer with pendant imidazolium groups for alkaline fuel cell applications [J]. Macromolecules, 2011, 44 (24): 9642-9649.
[7]GU S, CAI R, LUO T, et al. A soluble and highly conductive ionomer for high-performance hydroxide exchange membrane fuel cells [J]. Angew Chem Int Ed, 2009, 48 (35): 6499-6502.
[8]WANG J, LI S, ZHANG S. Novel hydroxide-conducting polyelectrolyte composed of an poly(arylene ether sulfone) containing pendant quaternary guanidinium groups for alkaline fuel cell applications [J]. Macromolecules, 2010, 43 (8): 3890-3896.
[9]刘健美. 燃料电池用新型聚醚砜类电解质膜的制备及性能[D]. 南京:南京理工大学, 2012.
[10]邢丹敏, 刘富强, 于景荣, 等. 磺化聚砜膜的燃料电池性能初步研究 [J]. 膜科学与技术，2002, 22 (5): 12-16.
[11]LEE C H, PARK H B, LEE Y M, et al. Importance of proton conductivity measurement in polymer electrolyte membrane for fuel cell application [J]. Industrial & Engineering Chemistry Research, 2005, 44 (20): 7617-7626.
[12]PAN J, LU S, LI Y, et al. High-performance alkaline polymer electrolyte for fuel cell applications [J]. Adv Funct Mater, 2010, 20 (2): 312-319.
[13]LUO Y,GUO J,WANG C,et al.Quaternized poly(methylmethacrylate-co-butyl acrylate-co-vinylbenzyl chloride) membrane for alkaline fuelcells[J]. J Power Sources 2010,195 (12):3765-3771.
[14]XU H,FANG J,GUO M,et al. Novel anion exchangemembrane based on copolymer of methyl methacrylate,vinylbenzyl chloride and ethylacrylate for alkaline fuel cells[J]. Journal of Membrane Science,2010,354 (1-2): 206-211.
[15]WU Y,WU C,XU T,et al. Novelsilica/poly(2,6-dimethyl-1,4-phenylene oxide) hybrid anion-exchange membranes foralkaline fuel cells: Effect of heat treatment[J]. Journal of Membrane Science,2009,338(1-2): 51-60.
[16]于鼎杰,郭冰,顾小芳,等.聚苯并咪唑/两性离子修饰氧化石墨烯复合质子交换膜的制备与表征[J].常州大学学报（自然科学版）,2013, 25(4): 69-73

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备注/Memo

备注/Memo:
国家自然科学基金资助项目（51303017，21476031）
更新日期/Last Update: 2015-11-26