[1]于金涛,封笑梅,姜 艳,等.铜催化-氧化硅烷合成硅醇反应研究[J].常州大学学报(自然科学版),2016,(01):43-47.[doi:10.3969/j.issn.2095-0411.2016.01.009]
 YU Jintao,FENG Xiaomei,JIANG Yan,et al.Copper-Catalyzed Aerobic Oxidation of Silanes to Silanols[J].Journal of Changzhou University(Natural Science Edition),2016,(01):43-47.[doi:10.3969/j.issn.2095-0411.2016.01.009]
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铜催化-氧化硅烷合成硅醇反应研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2016年01期
页码:
43-47
栏目:
出版日期:
2016-01-28

文章信息/Info

Title:
Copper-Catalyzed Aerobic Oxidation of Silanes to Silanols
文章编号:
2095-0411(2016)01-0043-05
作者:
于金涛封笑梅姜 艳成 江
常州大学 石油化工学院,江苏 常州 213164
Author(s):
YU Jintao FENG Xiaomei JIANG Yan CHENG Jiang
School of Petrochemical Engineering,Changzhou University, Changzhou 213164, China
关键词:
铜催化 硅醇 硅烷 绿色合成
Keywords:
copper-catalyzed silanol silane green synthesis
分类号:
O 621.3
DOI:
10.3969/j.issn.2095-0411.2016.01.009
文献标志码:
A
摘要:
以有机硅烷为原料,水为氧化剂,在Cu(OAc)2催化下,高产率高选择性合成有机硅醇,并用1H NMR,13C NMR以及GCMS对产物结构进行表征。与传统方法相比,该合成策略可以实现无溶剂条件下,水为清洁氧化剂的硅烷氧化水解反应,条件温和且底物兼容性好,为硅醇的合成提供新的途径。
Abstract:
The Cu(OAc)2-catalyzed selective hydrolytic oxidation of silanes toward the silanols using water as the oxidant was achieved. All the products were characterized by 1H NMR, 13C NMR and GCMS. Compared with other methods, this silane hydrolysis protocol is featured with the solvent-free mild reaction conditions using H2O as clean oxidant with good substrate compatibility. This work provides a new approach toward the synthesis of silanols.

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备注/Memo

备注/Memo:
基金项目:国家自然科学基金资助项目(21202013)。作者简介:于金涛(1984—),女,山东聊城人,博士,讲师,主要从事有机合成方法学研究。通讯联系人:成江(1974—),E-mial: jiangcheng@cczu.edu.cn
更新日期/Last Update: 2016-01-28