[1]彭勇刚,纪俊玲,汪媛,等.ZnSn(OH)6/氧化石墨烯复合材料的水热合成及其光催化性能[J].常州大学学报(自然科学版),2016,(04):25-29.[doi:10.3969/j.issn.2095-0411.2016.04.005]
 PENG Yonggang,JI Junling,WANG Yuan,et al.Hydrothermal Preparation of ZnSn(OH)6/GO Composites and Their Photocatalytic Activities[J].Journal of Changzhou University(Natural Science Edition),2016,(04):25-29.[doi:10.3969/j.issn.2095-0411.2016.04.005]
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ZnSn(OH)6/氧化石墨烯复合材料的水热合成及其光催化性能()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2016年04期
页码:
25-29
栏目:
化学化工
出版日期:
2016-07-30

文章信息/Info

Title:
Hydrothermal Preparation of ZnSn(OH)6/GO Composites and Their Photocatalytic Activities
作者:
彭勇刚12纪俊玲1汪媛1万怀新3
1.常州大学 石油化工学院,江苏 常州 213164; 2.江苏省精细石油化工重点实验室(常州大学),江苏 常州 213164; 3.江苏麦阁吸附剂有限公司,江苏 盱眙 211700
Author(s):
PENG Yonggang12 JI Junling1 WANG Yuan1 WAN Huaixin3
1. School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China; 2. Jiangsu Key Laboratory of Fine Petrochemical Engineering,Changzhou University, Changzhou 213164, China; 3. Jiangsu Mai Ge Adsorbent Co., Ltd., Xuyi 211700, China
关键词:
ZnSn(OH)6 氧化石墨烯 水热 光催化
Keywords:
ZnSn(OH)6 graphene oxide hydrothermal photocatalysis
分类号:
TQ 426.6
DOI:
10.3969/j.issn.2095-0411.2016.04.005
文献标志码:
A
摘要:
以氧化石墨烯(GO)、Zn(NO3)2·6H2O和SnCl4·5H2O为起始原料,采用水热合成法制备ZnSn(OH)6/GO复合材料。通过X射线衍射(XRD)、 透射电子显微镜(TEM)对材料结构进行表征,并对ZnSn(OH)6/GO复合材料形成机理进行了探讨。以亚甲基蓝(MB)作为模拟污染物,对复合材料的光催化活性进行了探讨。结果表明:与氧化石墨烯复合后,ZnSn(OH)6光催化活性和光稳定性明显提高。紫外光辐照120 min后,ZnSn(OH)6/GO复合材料对MB的降解率达到了98.1%; 重复使用6次后, ZnSn(OH)6/GO复合材料对MB的光催化降解率仅降低了8.9%。
Abstract:
ZnSn(OH)6/GO composites were synthesized via hydrothermal method using GO,Zn(NO3)2·6H2O and SnCl4·5H2O as raw materials.The as-prepared samples were characterized by X-ray diffraction(XRD)and Transmission electron microscopy(TEM).The formation mechanism of ZnSn(OH)6/GO composites was discussed in the paper.The photocatalytic activity of prepared ZnSn(OH)6/GO composites was evaluated by photocatalytic degradation of Methylene Blue(MB)under UV irradiation. The results indicated ZnSn(OH)6/GO composites had better photocatalytic activities and stabilities under UV irradiations.After 120 min UV irradiation, the photocatalytic degradation rate of ZnSn(OH)6/GO composites for MB reached 98.1%.After six successive cycles, their photocatalytic activities for degradation of MB only decreased by 8.9%.

参考文献/References:

[1]CHEN Y B, LI D Z, HE M, et al. High photocatalytic performance of zinc hydroxystannate toward benzene and methyl orange[J]. Applied Catalysis B-Environmental, 2012, 113(SI): 134-140.
[2]WANG M, CAO X L, HUANG Y F, et al. Solvent-free mechanochemical synthesis of well-dispersed single crystalline zinc hydroxystannate and their photocatalytic properties[J]. Crystal Engineering Communication, 2012, 14(8): 2950-2953.
[3]RAO C N R,SOOD A K,SUBRAHMANYAM K S, et al. Graphene: The new two-dimensional nanomaterial[J]. Angewandte Chemmie: International Edition,2009,48(42):7752-7777.
[4]LEE C, WEI X D, KYSAR J W, et al. Measurement of the Elastic Properties and Intrinsic Strength of Monolayer Graphene [J]. Science, 2008, 321(5887): 358-388.
[5]HE G Y, CHEN H Q, ZHU J W, et al. Synthesis and characterization of graphene paper with controllable properties via chemical reduction[J]. Journal of Materials Chemistry, 2011, 21(38): 14631-14638.
[6]HUMMERS W S,OFFEMAN R E. Preparation of graphitic oxide [J]. Journal of the American Chemical Society, 1958, 80(6): 1339-1339.
[7]FU D Y, HAN G Y, CHANG Y Z, et al. The synthesis and properties of ZnO-graphene nano hybrid for photodegradation of organic pollutant in water[J]. Materials Chemistry and Physics, 2012,132(2/3):673-681.
[8]LV T, PAN L K, LIU X J, et al. Enhanced photocatalytic degradation of methylene blue by ZnO-reduced graphene oxide composite synthesized via microwave-assisted reaction[J]. Journal of Alloys and Compounds, 2011,509(41):10086-10091.

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备注/Memo

备注/Memo:
收稿日期:2016-05-23。基金项目:淮安市科技计划项目-重点研发计划(HAG2015016); 江苏省精细石油化工重点实验室开放课题基金资助项目(KF1305); 常州大学博士启动基金(ZMF14020065 )。作者简介:彭勇刚(1979—),男,湖北天门人,博士,讲师,主要从事光催化材料的制备及性能研究。
更新日期/Last Update: 2016-08-30