[1]单雪影,蒋宽玉,韩 骥,等.介孔SiO2材料制备及其在聚合物阻燃中应用进展[J].常州大学学报(自然科学版),2019,31(01):28-34.[doi:10.3969/j.issn.2095-0411.2019.01.005]
 SHAN Xueying,JIANG Kuanyu,HAN Ji,et al.Preparation of Mesoporous Silica Materials and Their Applications in Flame-Retarded Polymers[J].Journal of Changzhou University(Natural Science Edition),2019,31(01):28-34.[doi:10.3969/j.issn.2095-0411.2019.01.005]
点击复制

介孔SiO2材料制备及其在聚合物阻燃中应用进展()
分享到:

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第31卷
期数:
2019年01期
页码:
28-34
栏目:
材料科学与工程
出版日期:
2019-01-28

文章信息/Info

Title:
Preparation of Mesoporous Silica Materials and Their Applications in Flame-Retarded Polymers
文章编号:
2095-0411(2019)01-0028-07
作者:
单雪影1蒋宽玉2韩 骥1李锦春2
(1.常州大学 环境与安全工程学院,江苏 常州 213164; 2.常州大学 材料科学与工程学院,江苏 常州 213164)
Author(s):
SHAN Xueying1 JIANG Kuanyu2 HAN Ji1 LI Jinchun2
(1.School of the Environmental and Safety Engineering, Changzhou University, Changzhou 213164, China; 2.School of Materials Science and Engineering, Changzhou University, Changzhou 213164, China)
关键词:
二氧化硅 制备 聚合物 阻燃 抑烟
Keywords:
silica preparation polymers flame retardant smoke suppression
分类号:
TQ 325
DOI:
10.3969/j.issn.2095-0411.2019.01.005
摘要:
介绍了介孔SiO2(M-SiO2)材料的制备方法及其在聚合物阻燃中的应用进展,其制备方法主要有溶胶-凝胶法、水热合成法、室温合成法、微波辐射合成法4类,文中分别阐述了这4种方法在材料制备过程中的特点。根据M-SiO2的应用类型,其在聚合物中的阻燃应用主要包括直接将M-SiO2材料作为阻燃协效剂使用; 将M-SiO2功能化改性后使用; 制备M-SiO2基复合材料; 制备介孔中空SiO2(HM-SiO2)基材料。基于M-SiO2材料目前的应用情况,文中对其在聚合物阻燃中的发展提出展望。
Abstract:
The preparation methods of M-SiO2 and the research development of M-SiO2 materials in flame-retarded polymers were reviewed in this paper. The preparation methods mainly included sol-gel method, hydrothermal synthesis, room temperature synthesis and microwave irradiation synthesis. The characterizations of four methods were described in this paper. According to the application types of M-SiO2, its flame retardant applications in polymers mainly included the direct use of Mi-SiO2 as flame retardant synergist, functionalized M-SiO2, preparation of M-SiO2 composites and hollow mesoporous silica(HM-SiO2)materials. Based on the current applications, the development of M-SiO2 materials in flame-retarded polymers is proposed.

参考文献/References:


[1] KAPOORA M P, VINU A, FUJII W, et al. Self-assembly of mesoporous silicas hollow microspheres via food grade emulsifiers for delivery systems[J]. Microporous and Mesoporous Materials, 2010, 128(1/2/3): 187-193.
[2]TENG Z G, SUN C H, SU X D, et al. Superparamagnetic high-magnetization composite spheres with highly aminated ordered mesoporous silica shell for biomedical applications[J]. Journal of Materials Chemistry B, 2013, 1(36): 4684-4691.
[3]HOFFMANN F, CORNELIUS M, MORELL J, et al. Silica-based mesoporou organic-inorganic hybrid materials[J]. Angewandte Chemie-International Edition, 2006, 45(20): 3216-3251.
[4]杨冲. 介孔二氧化硅的制备及银的负载性研究[D]. 南京:南京理工大学, 2010.
[5]QI L M,MA J M,CHENG H M,et al. Micrometer-sized mesoporous silica spheres grown under static conditions[J].Chemistry of Materials, 1998, 10(6):1623-1626.
[6]HUO Q H, MARGOLESE D I,CIESLA U, et al. Organization of organic molecules with inorganic molecular species into nanocomposite biphasearrays[J].Chemistry of Materials, 1994, 6(8): 1176-1198.
[7]秦振平, 郭红霞.模板法合成有序多孔材料研究进展[J]. 化工进展, 2002, 21(5): 323-327.
[8]LEI J H,CHEN Y X,CUO L P, et al.Different synthesis methods for ordered mesoporous silica and their characteristics comparison[J].Journal of Wuhan University of Technology Master, 2003, 19(3): 59-61.
[9]树信, 霍翼川, 李炜罡.多孔材料合成进展[J].化工新型材料, 2004, 32(2): 13-17.
[10]齐凯, 杨振忠, 赵得禄, 等. 模板技术制备单块介孔分子筛[J]. 高等学校化学学报, 2002, 23(2): 339-341.
[11]NAJAFI A,GHASEMI S. A study of APC surfactant role on the surface characteristics, size and morphology improvements of synthesizedmesoporous silica nanopowder through a sol-gel process[J]. Journal of Alloys & Compounds, 2017, 720(1): 423-431.
[12]SETYAWAN H, YUWANA M, BALGIS R. PEG-templated mesoporous silicas using silicate precursor and their applications in desiccant dehumidification cooling systems[J]. Microporous & Mesoporous Materials, 2015, 218: 95-100.
[13]DONG X, WANG Y, DAN H, et al. A facile route to synthesize mesoporous SBA-15 silica spheres from powder quartz[J]. Materials Letters, 2017, 204(1): 97-100.
[14]GOLEZANI A S, FATEH A S, MEHRABI H A. Synthesis and characterization of silica mesoporous material produced by hydrothermal continues pH adjusting path way[J]. Progress in Natural Science: Materials International, 2016, 26(4): 411-414.
[15]HUANG F, FU Z Y, JIA T K, et al. Effect of the methanol on structure and morphology of ordered mesoporous silica[J]. Rare Metal Materials and Engineering, 2009, 28(2): 373-376.
[16]梁静霞. 介孔二氧化硅材料的制备与表征[D]. 济南:山东师范大学, 2014.
[17]HUO Q, MARGOLESE D I, CLESLA U, et al. Generalized synthesis of periodic surfactant/inorganic composite materials[J]. Nature, 1994, 368(6469): 317-321.
[18]ZHANG J, LIU M, ZHANG A, et al. Facile synthesis of mesoporous silica nanoparticles with controlled morphologies using water-acetone media[J]. Solid State Sciences, 2010, 12(2): 267-273.
[19]WU C G, BEIN T. Microwave synthesis of molecular sieve MCM-41[J]. The Royal Society of Chemistry, 1996, 8(8): 925-926.
[20]PALANI A, WU H Y, TING C C, et al. Rapid temperature-assisted sonochemical synthesis of mesoporous silica SBA-15[J]. Microporous & Mesoporous Materials, 2010, 131(1): 385-392.
[21]JIN D, PARK K W, JI H L, et al. The selective immobilization of curcumin onto the internal surface of mesoporous hollow silica particles by covalent bonding and its controlled release[J]. Journal of Materials Chemistry, 2011, 21(11): 3641-364.
[22]KARAMAN D S, GULIN-SARFRAZ T, ZHANG J X, et al. One-pot synthesis of pore-expanded hollow mesoporous silica particles[J]. Materials Letters, 2015, 143: 140-143.
[23]JIANG S D, SONG L, ZENG W R, et al. Self-assembly fabrication of hollow mesoporous silica@Co-Al layered doublehydroxide@graphene and application in toxic effluents elimination[J]. Acs Applied Materials & Interfaces, 2015, 7(16): 8506-8514.
[24]MA H Y, TONG L F, XU Z B, et al. Intumescent flame retardant-montmorillonite synergism in ABS nanocomposites[J]. Applied Clay Science, 2008, 42(1): 238-45.
[25]LI Y T, LI B, DAI J F, et al. Synergistic effects of lanthanum oxide on a novel intumescent flame retardant polypropylene system[J]. Polymer Degradation and Stablity, 2008, 93(1): 9-16.
[26]WANG N, SHI Z X, ZHANG J, et al. The influence of modification of mesoporous silica with polyethylene viain situ Ziegler-Natta polymerization on PE/MCM-41 nanocomposite [J]. Journal of Composite Materials, 2008, 42(12): 1151-1157.
[27]ZHANG F A, LEE D K, PINNAVAIA T J. PMMA/mesoporous silica nanocomposites: effect of framework structure andpore size on thermomechanical properties [J]. Polymer Chemistry, 2010, 1(1): 107-113.
[28]王鹏, 蔡再生. DOPO基低聚物与介孔二氧化硅协同阻燃环氧树脂[J]. 工程塑料应用, 2016, 44(11): 100-104.
[29]PATRICK L W K, MARIATTI M, CHOW W S, et al. Effect of intumescent ammonium polyphosphate(APP)and melamine cyanurate(MC)on the properties of epoxy/glass fiber composites[J]. Composite B, 2012, 43(2): 124-128.
[30]WANG N, MI L, WU Y X, et al. Enhanced flame retardancy of natural rubber composite with addition of microencapsulated ammonium polyphosphate and MCM-41 fillers[J]. Fire Safety Journal, 2013, 62(4): 281-288.
[31]LI J, WEI P, LI L, et al. Synergistic effect of mesoporous silica SBA-15 on intumescent flame-retardant polypropylene[J]. Fire and Materials, 2011, 35(2): 83-91.
[32]WANG N, ZHANG J, FANG Q H, et al. Influence of mesoporous fillers with PP-g-MA on flammability and tensile behavior of polypropylene composites[J]. Composites Part B-Engineering, 2013, 44(1): 467-471.
[33]MATAR M, COCHEZ B, VAHABI M, et al. Influence of modified mesoporous silica SBA-15 on the flammability of intumescent high-density polyethylene[J]. Polymers for Advanced Technologies, 2016, 27(10): 1363-1375.
[34]WEI P, TIAN G H, YU H Z, et al. Synthesis of a novel organic-inorganic hybrid mesoporous silica and its flame retardancy application in PC/ABS[J]. Polymer Degradation and Stability, 2013, 98(5): 1022-1029.
[35]SHABANIAN M, KHOOBI M, HEMATI F, et al. Effects of polyethyleneimine-functionalized MCM-41 on flame retardancy and thermal stability of polyvinyl alcohol[J]. Particuology, 2015, 19(2): 14-21.
[36]QIAN Y, WEI P, JIANG P K, et al. Aluminated mesoporous silica as novel high-effective flame retardant in polylactide[J]. Composites Science and Technology, 2013, 82(15): 1-7.
[37]PAN Y T, TREMPONT C, WANG D Y, et al. Hierarchical nanoporous silica doped with tin as novel multifunctional hybrid material to flexible poly(vinyl chloride)with greatly improved flame retardancy and mechanical properties[J]. Chemical Engineering Journal, 2016, 295(1): 451-460.
[38]夏燎原, 胡云楚, 吴义强, 等. 介孔SiO2-APP复合阻燃剂的制备及其对木材的阻燃抑烟作用[J].中南林业科技大学学报, 2012, 32(1): 9-13.
[39]ZHU Y F, SHI J L, SHEN W H, et al. Stimuli-responsive controlled drug release from a hollow mesoporous silica sphere/polyelectrolyte multilayer core-shell structure[J]. Angewandte Chemie International Edition, 2005, 44(32): 5083-5087.
[40]ZHU F, LIU D, CAI G P, et al. Thermal stability and flammability performance of polypropylene composites with silica pillared montmorillonites[J]. Polymers for Advanced Technologies, 2014, 25(2): 211-216.
[41]SHE X D, CHEN L J, VELLEMAN L, et al. Fabrication of high specificity hollow mesoporous silica nanoparticles assisted by Eudragit for targeted drug delivery [J]. Journal of Colloid and Interface Science, 2015, 445(1): 151-160.
[42]YANG S, LI N J, CHEN D Y, et al. Visible-light degradable polymer coated hollow mesoporous silica nanoparticles for controlled drug release and cell imaging [J]. Journal of Materials Chemistry B, 2013, 1(36): 4628-4636.
[43]SUN Y F, SUN Y L, WANG L Z, et al. Nanoassembles constructed from mesoporous silica nanoparticles and surface-coated multilayer polyelectrolytes for controlled drug delivery[J]. Microporous and Mesoporous Materials, 2014, 185(2): 245-253.
[44]RUN M T, WU S Z, ZHANG D Y, et al. Melting behaviors and isothermal crystallization kinetics of poly(ethylene terephthalate)/mesoporous molecular sieve composite[J]. Polymer, 2005, 46(14): 5308-5316.
[45]江曙东. 介孔二氧化硅的功能化改性及其环氧树脂复合材料的热解与燃烧性能研究[D]. 合肥:中国科学技术大学, 2015.
[46]HUANG Z Q, JIANG S D, HONG N N,et al. Synthesis of highly active HM-SiO2@CeO2/NiO hybrids for fire safety applications of epoxy resins[J]. Composites: Part A, 2017, 95(1): 337-345.
[47]JIANG S D, BAI Z M, HU Y, et al. Synthesis of mesoporous silica@Co-Al layered double hydroxide spheres: layer-by-layer method and their effects on the flame retardancy of epoxy resins[J].ACS Applied Materials & Interfaces, 2014, 6(16): 14076-14086.

相似文献/References:

[1]陶永新,等.侧链含2, 5- 二苯基- 1, 3, 4- 噻二唑聚乙烯的 制备及其性能[J].常州大学学报(自然科学版),2009,(04):16.
 TAO Yong- x in,YANG Xue- bo,et al.Study of Synthesis and Properties of Polystyrene Containing 2, 5- Diphenyl- 1, 3, 4- Thiadiazole in Side Chain[J].Journal of Changzhou University(Natural Science Edition),2009,(01):16.
[2]徐万平,邓凤霞,曹引梅.苯基二氯化膦的新工艺[J].常州大学学报(自然科学版),2010,(03):31.
 XU Wan- ping,DENG Feng- xia,CAO Yin- mei.Improved Synthetic Method of Dicholrophenylphosphine[J].Journal of Changzhou University(Natural Science Edition),2010,(01):31.
[3]陈爱莲,李霞章,陈?? 杨.纳米CeO2 粉体的制备及应用[J].常州大学学报(自然科学版),2006,(02):10.
 CHEN Ai- lian,LI Xia- zhang,CHEN Yang.Preparation and Application of Nanometer CeO2 Powder[J].Journal of Changzhou University(Natural Science Edition),2006,(01):10.
[4]郭登峰,潘剑波,严小丽,等.高效SE - 54 色谱毛细管交联柱的制备和研究[J].常州大学学报(自然科学版),2006,(04):56.
 GUO Deng - feng,PAN J ian - bo,YAN Xiao - li,et al.Preparation of High Eff icient Capillary Columns and Investigation on Chromatographic Performance[J].Journal of Changzhou University(Natural Science Edition),2006,(01):56.
[5]朱毅青,宗封琦,赖梨芳,等.超细铜基催化剂上CO2 加氢合成甲醇催化性能研究[J].常州大学学报(自然科学版),2003,(02):12.
 ZHU Yi-qing,ZONG Feng -qi,LAI Li -fang,et al.Study on Ultraf ine Copper Catalysts for Methanol Synthesis from CO2 and H2[J].Journal of Changzhou University(Natural Science Edition),2003,(01):12.
[6]姚 超,等.SiO2 对金红石相纳米TiO2 热稳定性的影响[J].常州大学学报(自然科学版),2003,(04):1.
 YAO Chao,GAO Guo -sheng,et al.Ef fect of Si lica Dioxide on the Thermal Stability of Nanosized Ti tanium Dioxide in the Rutile Phase[J].Journal of Changzhou University(Natural Science Edition),2003,(01):1.
[7]王龙耀,蔡梦云,赵宇培,等.联苯双醚型聚酰亚胺的合成与表征[J].常州大学学报(自然科学版),2017,(02):13.[doi:10.3969/j.issn.2095-0411.2017.02.003]
 WANG Longyao,CAI Mengyun,ZHAO Yupei,et al.Synthesis and Characterization of Biphenylether Polyimide[J].Journal of Changzhou University(Natural Science Edition),2017,(01):13.[doi:10.3969/j.issn.2095-0411.2017.02.003]
[8]丁 嘉,巢 磊,周诗岽,等.三元聚合物的甲烷水合物动力学抑制剂的制备及评价[J].常州大学学报(自然科学版),2017,(06):32.[doi:10.3969/j.issn.2095-0411.2017.06.005]
 DING Jia,CHAO Lei,ZHOU Shidong,et al.Preparation and Evaluation of Terpolymer Methane Hydrate Kinetic Inhibitors[J].Journal of Changzhou University(Natural Science Edition),2017,(01):32.[doi:10.3969/j.issn.2095-0411.2017.06.005]

备注/Memo

备注/Memo:
收稿日期:2018-09-24。
基金项目:国家自然科学基金面上项目(51574046)。
作者简介:单雪影(1986—),女,安徽宿州人,博士,讲师。通信联系人:李锦春(1965—),E-mail: lijinchun88@163.com
更新日期/Last Update: 2019-02-20