[1]王 非,毕研帅,方启华,等.一步法制备火龙果型Ni/C用于肉桂醛加氢反应[J].常州大学学报(自然科学版),2019,31(06):11-16,30.
　WANG Fei,BI Yanshuai,FANG Qihua,et al.A Facile One-Pot Synthesis of Dragon Fruit-Like Ni/C Composites Using Glucose as Template for Selective Hydrogenation of Cinnamaldehyde[J].Journal of Changzhou University(Natural Science Edition),2019,31(06):11-16,30.
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一步法制备火龙果型Ni/C用于肉桂醛加氢反应()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
第31卷
期数:
2019年06期
页码:
11-16,30
栏目:
化学化工
出版日期:
2019-11-28

文章信息/Info

Title:
A Facile One-Pot Synthesis of Dragon Fruit-Like Ni/C Composites Using Glucose as Template for Selective Hydrogenation of Cinnamaldehyde
文章编号:
2095-0411(2019)06-0011-06
作者:
王 非; 毕研帅; 方启华; 胡 凯
(常州大学 石油化工学院,江苏 常州 213164)
Author(s):
WANG Fei;  BI Yanshuai;  FANG Qihua;  HU Kai
(School of Petrochemical Engineering, Changzhou University, Changzhou 213164, China)
关键词:
镍;  碳;  一步法;  肉桂醛;  加氢
Keywords:
nickel;  carbon;  one-step;  cinnamaldehyde;  hydrogenation
分类号:
O 643.3
文献标志码:
A
摘要:
以硝酸镍和葡萄糖为原料,通过一步法制备了Ni/C复合材料。Ni/C复合物具有火龙果状结构,Ni纳米颗粒均匀地分散在碳中。所得的30%Ni/C复合催化剂在肉桂醛选择性加氢反应实验中表现出较高的加氢活性和循环稳定性,其原因在于Ni的高分散性和碳的限域效应。将这种方法应用于碳负载其他金属和合金NPs复合材料,可能对未来的工业生产应用也会有重要的意义。
Abstract:
Ni/C composites were successfully prepared by a facile one-step solution synthesis using nickel nitrate and glucose as starting materials. The Ni/C composite has a structure of dragon fruit-like and Ni nanoparticles(NPs)were uniformly dispersed within carbon. The obtained 30% Ni/C composite catalyst exhibited high hydrogenation activity and superior stability in recycling tests for selective hydrogenation of cinnamaldehyde, which was attributed to high dispersion of Ni and confinement effect of carbon. This facile synthesis strategy for carbon supported other metal and alloy NPs materials will be of great importance for the future industrial production and application.

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备注/Memo

备注/Memo:
收稿日期:2019-05-31。
基金项目:国家自然科学基金青年基金资助项目(21503023)。
作者简介:王非(1985-),男,陕西安康人,博士,助理研究员。E-mail: wangfei@cczu.edu.cn
更新日期/Last Update: 2019-12-02