[1]张卫红,宗志敏,魏贤勇.多环芳烃与N -溴代丁二酰亚胺的光化学反应[J].常州大学学报(自然科学版),2000,(01):15-18.
　ZHANG Wei -hong,ZONG Zhi -min,WEI Xian -yong.Photochemical Reaction of Aromatic Hydrocarbon with N-Bromosuccinimide[J].Journal of Changzhou University(Natural Science Edition),2000,(01):15-18.
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多环芳烃与N -溴代丁二酰亚胺的光化学反应()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2000年01期
页码:
15-18
栏目:
出版日期:
2000-03-25

文章信息/Info

Title:
Photochemical Reaction of Aromatic Hydrocarbon with N-Bromosuccinimide
作者:
张卫红1 ;  宗志敏2 ;  魏贤勇2
1.江苏石油化工学院化学工程系, 江苏 常州 213016;2.中国矿业大学能源利用与化学工程系, 江苏徐州221008
Author(s):
ZHANG Wei -hong1 ;  ZONG Zhi -min2 ;  WEI Xian -yong2
1 .Department of Chemical Engineering , Jiangsu Inst itute of Petrochemical Technology , Changzhou 213016 , China ;2 .Department of Energy U tilization and Chemical Eng ineering , CUMT , Xuzhou 221008 , China
关键词:
N -溴代丁二酰亚胺; 多环芳烃; 光溴化反应
Keywords:
N -bromosuccimide ; aromatic hydrocarbon ; photochemical reaction
分类号:
T Q 24
文献标志码:
A
摘要:
在可见光照射, 苯为溶剂, 氮气气氛中考察了数种多环芳烃与N -溴代丁二酰亚胺的反应。采用气相色谱跟踪了反应过 程, 解释了产物因结构而异的原因。结果表明:甲基芳烃仅得到单溴代产物, 氢化芳烃主要生成脱氢产物, 蒽全部转化为9 , 10 -二溴代蒽。
Abstract:
Using benzene as solvent , the react ions of several aromatic hydrocarbons wi th N -bromosuccinimide at visible light and ni trogen atmosphere were examined .The reaction processes were traced by GC and the causes of different resultants were explored .The results show that methy l aromatic hydrocarbons merely produced mono -bromide and that hy drogenated aromatic hy drocarbons predominant ly affo rded dehydrogenated products , whereas all of anthracene turned into 9 , 10 -dibromoanthracene .

参考文献/References:

〔1〕Bhalla Gulzari Lai , Sood Rakesh Chandra, Kumar Ajay Sharma , et al.A Process f or the Preparati on of P -xylene Dib romide 〔P〕. Indian:168345 , 1991 .
〔2〕Futamura S hin .Manufacture of Bis (b romomethyl) -containing Aromatic Hydrocarbons 〔P〕.JP :04282327 , 1992 .
〔3〕Russel G A , Desmond K M .Directive Effect s in Aliphatic S ubst itutions 〔J〕.J Am Chem S oc, 1963 , 85 (20):3 139 -3 141 .
〔4〕Zong Z M , Wei X Y .Eff ect s of Molecular Hydrogen and Hydrogen Donor Additives on 1 , 2 -Di (1 -naphthyl) ethane Thermolysis 〔J〕.Fuel Processing Technology , 1994, 41 (1):79 - 85 .
〔5〕程谟杰, 杨亚书.ZnHZSM -5 上脱氢环化芳构化过程的探讨 〔J〕.分子催化, 1996 , 10 (6):418 -422 .
〔6〕张春雷, 吴志芸, 阚秋斌.FeZSM -5 沸石上乙苯的吸附态及 氧化脱氢〔J〕.催化学报, 1996 , 17 (1):34 -39 .

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备注/Memo

备注/Memo:
作者简介:张卫红(1972 -), 女, 重庆江津人, 硕士, 现主要从事有机合成方面的研究。
更新日期/Last Update: 2000-03-25