[1]张东亮,蒋必彪,任　强,等.新型自引发聚合单体AB＊的合成[J].常州大学学报(自然科学版),2005,(02):13-15.
　ZHANG Dong -liang,JIANG Bi -biao,REN Qiang,et al.Study of the Synthesis of a Novel Self -Initiated Polymerized AB＊Monomer[J].Journal of Changzhou University(Natural Science Edition),2005,(02):13-15.
点击复制

新型自引发聚合单体AB＊的合成()
分享到：

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2005年02期
页码:
13-15
栏目:
出版日期:
2005-06-25

文章信息/Info

Title:
Study of the Synthesis of a Novel Self -Initiated Polymerized AB＊Monomer
作者:
张东亮1 ;  蒋必彪1 ;  任　强1 ;  席海涛2
1.江苏工业学院材料科学与工程系, 江苏 常州 213016 ;2.江苏工业学院化学工程系, 江苏 常州 213016
Author(s):
ZHANG Dong -liang1 ;  JIANG Bi -biao1 ;  REN Qiang1 ;  XI Hai -tao2
1 .Department of Materials Science and Engineering , Jiangsu Polytechnic University , Changzhou 213016 , China ;2 .Department of Chemical Engineering , Jiangsu Poly technic University , Changzhou 213016 , China
关键词:
自引发聚合单体; N -[ 4 -(α溴代丁酰氧基)苯基] 马来酰亚胺; 合成
Keywords:
self -initiated polymerized monomer ; N -[ 4 -(α-Bromobuty roxy)pheny l] maleimide ; synthesis
分类号:
O 633.4
文献标志码:
A
摘要:
通过分子设计合成了一种新型自引发聚合单体:N - [ 4 - (α-溴代丁酰氧基) 苯基] 马来酰亚胺(AB＊), 主要研究了 国产与进口原料、原料配比、催化剂用量等因素对产率的影响。研究结果表明:溴丁酰氯与N - (4 -羟基苯基) 马来酰胺 (HPM) 物质的量配比为1.3∶1 , 催化剂三乙胺与HPM 物质的量配比为1.5∶1 时, 所制AB＊单体的单步产率可达75.4 %, 采用 国产溴丁酸制备AB＊的产率要低于使用进口原料的产率, 但两者产物经精制后纯度相差不大。
Abstract:
A new substitute phenyl maleimide :N - [ 4 - (α-Bromobuty roxy) phenyl] maleimide (AB ＊), w hich can self -init iatedly polymerize , w as desig ned and synthesized .The effects of the domestic and foreign material , ratio of raw material , amount of cataly st on yield were mainly studied .The result s show ed that the single step yield of AB ＊ could reach 75.4 %w hile the molar ratio of α-Bromobuty ry l chloride and N - [ 4 - hydroxy phenyl] maleimide (HPM)was 1.3∶1 , cataly st t riethy lamine and HPM w as 1.5∶1 , and the yield of AB ＊ made from the domestic material was lower than that of using foreign material , but the difference of the purity w as not much w hen both product s were purified .

参考文献/References:

[1] 王国建, 颜德岳.高支化聚合物的合成与表征[J] .高分子 通报, 1999 , (2):1 -10.
[2] 魏焕郁, 施文芳.超支化聚合物的结构特征、合成及其应用 [J] .高等学校化学学报, 2001 , 22 (2):338 -344.
[3] Voit B .New Development in Hyperbranched Polymers [J] .J Polym Sci , Part A :Polym Chem , 2000 , 38 (14):2 505 -2 525.
[4] Kim Y H .Hyperbranched Polymers 10 YearsAf ter [J] .J Polym S ci , Part A:Polym Chem , 1998 , 36 (11):1 685 -1 698.
[5] 张东亮, 蒋必彪, 方建波.N - (4 -羟基苯基) 马来酰亚胺合 成研究[J] .江苏工业学院学报, 2003 , 15 (4):8 -10.

备注/Memo

备注/Memo:
基金项目:国家自然科学基金项目资助(20174015);江苏工业学院科技基金资助(02020038) 作者简介:张东亮(1965 - ), 男, 江苏 常州 人, 副教授;本院材料系2004 年毕业生陆胜忠, 周勇参与部分工作。
更新日期/Last Update: 2005-06-25