[1]巫淼鑫,邬国英,林西平,等.影响大豆油生物柴油中总甘油含量因素的研究[J].常州大学学报(自然科学版),2008,(01):22-25.
　WU Miao-xin,WU Guo-ying,LIN Xi-ping,et al.Study of Factors Affecting Total Glycerin Content in Methyl Esters of Soybean Oil[J].Journal of Changzhou University(Natural Science Edition),2008,(01):22-25.
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影响大豆油生物柴油中总甘油含量因素的研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2008年01期
页码:
22-25
栏目:
出版日期:
2008-03-25

文章信息/Info

Title:
Study of Factors Affecting Total Glycerin Content in Methyl Esters of Soybean Oil
作者:
巫淼鑫； 邬国英； 林西平； 宋莎莎； 王俊德；
江苏工业学院化学化工学院； 南京理工大学化工学院 江苏常州213164； 南京理工大学化工学院； 江苏南京210094； 江苏常州213164；
Author(s):
WU Miao-xin1; 2; WU Guo-ying1; LIN Xi-ping1; SONG Sha-sha1; WANG Jun-de2
1.School of Chemistry and Chemical Engineering,Jiangsu Polytechnic University,Changzhou 213164,China;2.School of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China
关键词:
生物柴油;  甲酯;  大豆油;  甘油
Keywords:
bio diesel ; methyl esters ; soy bean oil ; gly cerin
分类号:
O 623.43 ;TQ 645.8
文献标志码:
A
摘要:
以大豆油和甲醇为原料在KOH催化下制备生物柴油。研究认为随反应温度、反应时间、醇/油物质的量比和催化剂用量增加,生物柴油中总甘油含量减少;随水分和游离脂肪酸含量增加,生物柴油中总甘油含量先增加较慢后增加较快。从生物柴油中总甘油含量考虑,将最佳反应温度、反应时间、醇/油物质的量比和催化剂用量分别选择在50℃、60 min、6∶1和植物油质量的1.2%。
Abstract:
Methyle sters (biodiesel)were produced by transesterification of soybean oil with methanol in the presence of cataly st (KOH).It has been found that totalgly cerin in the biodiesel decreases as reaction temperature , reaction time , molar ratio of methanol to oil and cataly st concent ration increase ;total glycerin increases as water and oil acid are added .The optimum conditions were obtained for the transesterification on the basis of totalgly cerin :reaction temperature 50 ℃, reaction t ime 60 min , usage amount of KOH 1.2 % of soy bean oil and molar ratio of methanol to oil 6 ∶1 .

参考文献/References:

[1] Srivast ava A , Prasad R. Triglycerides - based diesel fuels [J] .Renew able and Su st ainable Energy Review s , 2000 , 4 (2):111 -133.
[2] Ma F, H anna M A .Biodi esel product ion :a review [J] . Bioresource Techn ol ogy , 1999 , 70 (1):1 -15.
[3] 黄庆德, 黄凤洪, 郭萍梅.生物柴油生产技术及其开发意义 [J] .粮食与油脂, 2002 , (9):8 -10.
[4] 王一平, 翟怡, 张金利, 等.生物柴油制备方法研究进展[J] .化工进展, 2003 , 22 (1):8 -12.
[5] 忻耀年, Sonderman n B , Emersl eben B.生物柴油的生产与应 用[J] .中国油脂, 2001 , 26 (8):72 -77.
[6] Alcant ara R, Amores J , Can oi ra L, et al.Cat aly tic product ion of biodiesel f rom soy -bean oi l , used f rying oil and t al low [J] .Bi om as s and Bi oenergy , 2000 , 18 (6):515 -527.
[7] Ant olin G , T inaut F V , Bri ceno Y, et al.Opt imi sat ion of bi odiesel p rodu cti on by sunf low er oil transest eri ficat ion [J] . Biomass Technology , 2002 , 83 (2):111 -114.
[8] 盛梅, 郭登峰, 张大华. 大豆油制备生物柴油的研究[J] . 中国油脂, 2001 , 27 (1):70 -72.
[9] Shimada Yuji , Wat anabe Yomi , Sugihara Akio , et al.Enzymat ic al coholysi s f or bi odiesel fuel producti on and applicati on of the reacti on t o oi l processing [J] .Journal of Molecular Cat alysi s B:Enzym at ic, 2002 , 17 (3 -5):133 -142.
[10] Meher L C , Vidya Sagar D, Naik S N .Technical aspect s of bi odiesel product ion by t ran ses terifi cation -a review [J] .Renew ab le and Sus tainable Energy Review s , 2006 , 10 (3):248 -268.
[11] 邬国英, 巫淼鑫, 林西平, 等.植物油制备生物柴油[J] . 江苏石油化工学院学报, 2002 , 14 (3):8 -11.
[12] 黄忠水, 纪威, 李淑艳, 等.国外生物柴油的应用[J] . 节 能与环保, 2003 , (1):38 -41.
[13] 巫淼鑫, 邬国英, 韩瑛, 等.6 种食用植物油及其生物柴油中 脂肪酸成分的比较研究[J] .中国油脂, 2003 , 28 (12):65 -67.

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备注/Memo

备注/Memo:
基金项目:中国石化集团总公司资助项目(102019) 作者简介:巫淼鑫(1964 -), 男, 浙江武义人, 副研究员, 博士研究生, 主要从事化学分析和仪器分析以及生物柴 油制备方面研究。
更新日期/Last Update: 2008-03-25