[1]李 萍,赵 文,符孟乐,等.气相色谱内标曲线法测定酯交换反应体系中苯甲酸乙烯酯含量[J].常州大学学报(自然科学版),2012,(01):7-9.
　LI Ping,ZHAO Wen,FU Meng-le,et al.Determination of Vinyl Benzoate in the Vinyl Interchange Reactionby Internal Standard Gas Chromatography[J].Journal of Changzhou University(Natural Science Edition),2012,(01):7-9.
点击复制

气相色谱内标曲线法测定酯交换反应体系中苯甲酸乙烯酯含量()
分享到：

常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2012年01期
页码:
7-9
栏目:
出版日期:
2012-01-01

文章信息/Info

Title:
Determination of Vinyl Benzoate in the Vinyl Interchange Reactionby Internal Standard Gas Chromatography
作者:
李 萍; 赵 文; 符孟乐; 于鼎杰; 郭登峰
常州大学 石油化工学院,江苏 常州 213164
Author(s):
LI Ping; ZHAO Wen; FU Meng-le; YU Ding-jie; GUO Deng-feng
School of Petrochemical Engineering,Changzhou University,Changzhou 213164,China
关键词:
气相色谱;  苯甲酸乙烯酯;  内标曲线法;  分析
Keywords:
gas chromatography;  vinyl benzoate;  internal standard curve method;  analysis
分类号:
TQ 415
文献标志码:
A
摘要:
采用气相色谱内标曲线法测定醋酸乙烯和苯甲酸酯交换反应体系中苯甲酸乙烯酯含量,对色谱柱、内标物等色谱条件进行了研究。结果表明:选用乙二醇丁醚醋酸酯为内标物,FFAP毛细管色谱柱,采用程序升温,样品中各组分能实现有效分离。采用内标曲线法测定反应液中苯甲酸乙烯酯,线性关系良好,线性回归方程为y=6.011 6x+0.103 6,线性相关系数为0.995 9。相对标准偏差0.66%,加标回收率为98.99%-101.30%。该分析方法简单、快速、准确,对苯甲酸乙烯酯生产和质量控制有一定的指导意义。
Abstract:
A method for determination of vinyl benzoate in ester exchange reaction between vinyl acetate and benzoic acid was studied. With ethylene glycol monobutyl ether acetate as internal standard, Gas chromatographic analysis was made by using FFAP capillary column and programming temperature. The results showed that good separation effect was obtained. The linearity was good forvinyl benzoate.The linear equation was y=6.011 6x+0.103 6 and the linearcorrelation coefficient was 0.995 9. The relative standard deviation was 0.66%and the average recovery ranged between 98.99%-101.30%.The analysis method proved simple,accurate and reproducible.

参考文献/References:

[1]刘红波,林峰.紫外光固化材料的研究热点[J].现代涂料与涂装,2008(9):31-34.
[2]魏杰,金养智.光固化涂料[M].北京:化学工业出版社,2008:69-98.
[3]金养智.紫外光固化活性稀释剂的进展[J].影像技术,2009(2):12-19.
[4]李浩春.气相色谱分析[M].北京:化学工业出版社,1999:536-550.

相似文献/References:

[1]许　宁,林西平,邬国英,等.酸化棕榈油生物柴油的多相催化合成[J].常州大学学报(自然科学版),2009,(02):5.
　XU Ning,LIN Xi -ping,WU Guo -ying,et al.Production of Biodiesel from Waste Palm oil Using Heterogeneous Catalyst[J].Journal of Changzhou University(Natural Science Edition),2009,(01):5.
[2]雷春生,周家斌,王春江,等.气相色谱测定环境空气中苯系物方法改进[J].常州大学学报(自然科学版),2005,(01):28.
　LEI Chun -sheng,ZHOU Jia -bin,WANG Chun -jiang,et al.Improved Determination Method of Benzene Analogues by Gas Chromatography[J].Journal of Changzhou University(Natural Science Edition),2005,(01):28.
[3]杜晓刚,杨　扬,金凤明,等.超声波萃取法测定茶叶中有机磷类的农药残留方法[J].常州大学学报(自然科学版),2005,(02):20.
　DU Xiao -gang,YANG Yang,JIN Feng -ming,et al.Research on Determination of Organophosphorous Pesticides Residues in Tea by Ultrasonic Extraction[J].Journal of Changzhou University(Natural Science Edition),2005,(01):20.
[4]郭登峰,潘剑波,严小丽,等.高效SE - 54 色谱毛细管交联柱的制备和研究[J].常州大学学报(自然科学版),2006,(04):56.
　GUO Deng - feng,PAN J ian - bo,YAN Xiao - li,et al.Preparation of High Eff icient Capillary Columns and Investigation on Chromatographic Performance[J].Journal of Changzhou University(Natural Science Edition),2006,(01):56.
[5]杜晓刚,杨　扬.毛细管色谱法测定溶剂型木器涂料中三苯含量[J].常州大学学报(自然科学版),2003,(01):36.
　DU Xiao -gang,YANG Yang.Determination of Benzene, Toluene and Xylene of Paint Using GC with Capi llay Column[J].Journal of Changzhou University(Natural Science Edition),2003,(01):36.
[6]郭登峰,罗士平.大口径毛细管气相色谱法测定巯基乙酸异辛酯[J].常州大学学报(自然科学版),2002,(02):33.
　GUO Deng -feng,LUO Shi -ping.Determination of Isooctyl Mercaptoacetate Using GC with Wide -Bore Capi llary Column[J].Journal of Changzhou University(Natural Science Edition),2002,(01):33.
[7]刘　蓉.二甲基环己胺的气相色谱分析[J].常州大学学报(自然科学版),2000,(01):34.
　LIU Rong.Analysi s of Dimethylcyolohex lemine by Gas Chromatography[J].Journal of Changzhou University(Natural Science Edition),2000,(01):34.

备注/Memo

备注/Memo:
作者简介:李萍(1987-),女,江苏扬州人,硕士生; 通讯联系人:郭登峰。
更新日期/Last Update: 2012-01-01