[1]高国生,刘春林,李　毅.甲基丙烯酸缩水甘油酯熔融接枝聚丙烯研究[J].常州大学学报(自然科学版),2003,(02):9-11.
　GAO Guo -sheng,LIU Chun -lin,LI Yi.Study on the Melt Graf ting Synthesis of Polypropylene-g -Glycidyl Methacrylate[J].Journal of Changzhou University(Natural Science Edition),2003,(02):9-11.
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甲基丙烯酸缩水甘油酯熔融接枝聚丙烯研究()
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常州大学学报(自然科学版)[ISSN:2095-0411/CN:32-1822/N]

卷:
期数:
2003年02期
页码:
9-11
栏目:
出版日期:
2003-06-25

文章信息/Info

Title:
Study on the Melt Graf ting Synthesis of Polypropylene-g -Glycidyl Methacrylate
作者:
高国生1 ;  刘春林2 ;  李　毅2
1.江苏工业学院科技处, 江苏 常州 213016;2.江苏工业学院
Author(s):
GAO Guo -sheng 1 ;  LIU Chun -lin2 ;  LI Yi2
1 .Of fice of Science and Technology , Jiang su Polytechnic University , Changzhou 213016 , China
关键词:
聚丙烯; 甲基丙烯酸缩水甘油酯; 熔融接枝
Keywords:
polypropylene ; g ly cidyl methacry late ; melt g raf ting
分类号:
T Q 325.1 +4 　
文献标志码:
A
摘要:
利用双螺杆挤出机研究甲基丙烯酸缩水甘油酯(GMA)接枝改性聚丙烯, 探讨了停留时间、单体组成、引发剂用量等因 素对接枝反应的影响。结果表明, 通过工艺条件的控制在双螺杆挤出上可制备出接枝率高、流动性、色泽度良好的接枝产物。
Abstract:
The melt grafting of glycidyl methacry late (GMA)onto polypropy lene in a co-rotating tw in screw extruder was studied .The influences of different factors such as reaction time , concent ration of monomer and initiator on graf ting reaction were explored .Grafting yields of GMA with high grafting degree and good flowing and gloss properties were obtained through the control of experimental conditions .GMA was high boiling and low toxic as monomer graft ing on polypropylene molecular , it could improve poly propy lene compatibili ty w ith polyimide polyester and so on , it could improve polypropylene coating adhere property .

参考文献/References:

[1] Sun Y J , Hu G H , Lambla M .Free Radical Graft ing of Glycidyl Methacrylate onto Polypropylene in a Co -Rotating Tw in Screw Ext ruder [J] .J Appl polym Sci , 1995 , 57 :1 043 -1 054 .
[2] 潘泳康, 阮吉敏, 周达飞.GMA 熔融接枝聚丙烯的研究[J] .华东理工大学学报, 1997 , 23 (2):204 -209 .
[3] 谢续明, 陈年欢.高极性聚丙烯的制备及应用[J] .合成树 脂与塑料, 1999 , 16 (5):35 -37 .
[4] 李敬泽, 王均, 吴永刚.高极性PP 熔融接枝物的制备及应用 [J] .现代塑料加工应用, 1999 , 11 (6):6 -9 .
[5] 刘念才, 黄华, 周持兴.甲基丙烯酸缩水甘油酯熔融接枝粉末 聚丙烯的研究[J] .高分子材料科学与工程, 1997 , 13 (1): 27 -32 .
[6] 俞强, 李锦春, 夏汉中.聚丙烯反应性挤出接枝马来酸酐的研 究[J] .江苏石油化工学院学报, 1997 , 9 (1):20 -25 .
[7] Huang H , Liu N C .Nondegradat ive Melt Functionalizat ion of Polypropylene wi th Glycidyl Methacrylate [J] .J Appl polym Sci , 1998 , 67 :1 957 -1 963 .
[8] 吕晖辉, 黄华, 刘念才.聚丙烯自由基接枝改性进展[J] . 中国塑料, 1999 , 13 (8):10 -15 .
[9] 李颖, 谢续明, 陈年欢.聚丙烯多单体熔融接枝及其共混物研 究[J] .高分子通报, 2000 , 2 :73 -77 .

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备注/Memo

备注/Memo:
作者简介:高国生(1964 -), 男, 江苏 常州 人, 研究生毕业, 主要从事高分子材料研究
更新日期/Last Update: 2003-06-25